Abstract: A fluidized catalytic conversion method for maximizing the production of propylene includes the steps of: 1) contacting a heavy feedstock oil with a catalytic conversion catalyst having a temperature of 650° C. or higher for reaction; 2) contacting a hydrocarbon oil feedstock having an olefin content of 50 wt % or more with the catalytic conversion catalyst after the reaction of step 1); 3) separating a first catalytic cracking distillate oil and a second catalytic cracking distillate oil from the resulting reaction products; 4) separating an olefin-rich stream from the first catalytic cracking distillate oil; and 5) recycling the olefin-rich stream. The method can effectively improve the yield of propylene and realize an effective utilization of petroleum resources.

Abstract: A fluidized catalytic conversion method for producing light olefins includes the following steps: 1) introducing an olefin-rich feedstock into a fluidized catalytic conversion reactor, and contacting with a catalyst having a temperature of 650° C. or higher for reaction; 2) separating the reaction product vapor obtained by the reaction to obtain a stream comprising C5+ olefins; and 3) recycling at least a part of the stream comprising C5+ olefins to step 1) for further reaction. The fluidized catalytic conversion method can effectively improve the yield of light olefins, improve the selectivity and improve the ethylene/propylene ratio of the product.

Abstract: A catalytic conversion process for producing gasoline and propylene includes the steps of 1) subjecting a feedstock oil to a first catalytic conversion reaction in a first catalytic conversion reaction device to obtain a first reaction product; 2) separating the first reaction product to obtain a propylene fraction, a gasoline fraction and a fraction comprising C4 olefin; 3) carrying out an oligomerization reaction on the fraction comprising C4 olefin in an oligomerization reactor to obtain an oligomerization product comprising C12 olefin, and optionally separating the oligomerization product to obtain a fraction comprising C12 olefin; 4) recycling the C12 olefin-containing oligomerization product or fraction to the first catalytic conversion reaction device, and/or sending the C12 olefin-containing oligomerization product or fraction to a second catalytic conversion reaction device for a second catalytic conversion reaction to obtain a second reaction product comprising propylene.

Abstract: A process includes: cutting a hydrocarbon-containing feedstock oil into a light distillate oil and a heavy distillate oil; introducing the light distillate oil and a first catalyst into a down-flow reactor to produce a stream; subjecting the stream to a gas-solid separation to produce a first reaction hydrocarbon product and a first spent catalyst; or, introducing the stream into a fluidized bed reactor, and then subjecting to a gas-solid separation to produce a second reaction hydrocarbon product and a second spent catalyst; introducing a continuous catalyst, the heavy distillate oil and a second catalyst into an up-flow reactor, and then subjecting to a gas-solid separation to produce a third reaction hydrocarbon product and a third spent catalyst; separating out lower carbon olefins and light aromatics from reaction hydrocarbon products, separating out a light olefin fraction, and returning the light olefin fraction to the fluidized bed reactor or the up-flow reactor.

Abstract: A catalytic conversion process for producing gasoline and propylene includes the steps of 1) subjecting a feedstock oil to a first catalytic conversion reaction in a first catalytic conversion reaction device to obtain a first reaction product; 2) separating the first reaction product to obtain a propylene fraction, a gasoline fraction and a fraction comprising C4 olefin; 3) carrying out an oligomerization reaction on the fraction comprising C4 olefin in an oligomerization reactor to obtain an oligomerization product comprising C12 olefin, and optionally separating the oligomerization product to obtain a fraction comprising C12 olefin; 4) recycling the C12 olefin-containing oligomerization product or fraction to the first catalytic conversion reaction device, and/or sending the C12 olefin-containing oligomerization product or fraction to a second catalytic conversion reaction device for a second catalytic conversion reaction to obtain a second reaction product comprising propylene.

Abstract: The present application relates to a process for treating gasoline, comprising the steps of: contacting a gasoline feedstock with a mixed catalyst and subjecting it to desulfurization and aromatization in the presence of hydrogen to obtain a desulfurization-aromatization product; optionally, splitting the resulting desulfurization-aromatization product into a light gasoline fraction and a heavy gasoline fraction; and, optionally, subjecting the resulting light gasoline fraction to etherification to obtain an etherified oil; wherein the mixed catalyst comprises an adsorption desulfurization catalyst and an aromatization catalyst. The process of the present application is capable of reducing the sulfur and olefin content of gasoline and at the same time increasing the octane number of the gasoline while maintaining a high yield of gasoline.

Abstract: The present application relates to a process for treating gasoline, comprising the steps of: contacting a gasoline feedstock with a mixed catalyst and subjecting it to desulfurization and aromatization in the presence of hydrogen to obtain a desulfurization-aromatization product; optionally, splitting the resulting desulfurization-aromatization product into a light gasoline fraction and a heavy gasoline fraction; and, optionally, subjecting the resulting light gasoline fraction to etherification to obtain an etherified oil; wherein the mixed catalyst comprises an adsorption desulfurization catalyst and an aromatization catalyst. The process of the present application is capable of reducing the sulfur and olefin content of gasoline and at the same time increasing the octane number of the gasoline while maintaining a high yield of gasoline.

Abstract: A process for producing light olefins and aromatics, which comprises reacting a feedstock by contacting with a catalytic cracking catalyst in at least two reaction zones, wherein the reaction temperature of at least one reaction zone among the reaction zones downstream of the first reaction zone is higher than that of the first reaction zone and its weight hourly space velocity is lower than that of the first reaction zone, separating the spent catalyst from the reaction product vapor, regenerating the separated spent catalyst and returning the regenerated catalyst to the reactor, and separating the reaction product vapor to obtain the desired products, light olefins and aromatics. This process produces maximum light olefins such as propylene, ethylene, etc from heavy feedstocks, wherein the yield of propylene exceeds 20% by weight, and produces aromatics such as toluene, xylene, etc at the same time.

Abstract: A process for producing light olefins and aromatics, which comprises reacting a feedstock by contacting with a catalytic cracking catalyst in at least two reaction zones, wherein the reaction temperature of at least one reaction zone among the reaction zones downstream of the first reaction zone is higher than that of the first reaction zone and its weight hourly space velocity is lower than that of the first reaction zone, separating the spent catalyst from the reaction product vapor, regenerating the separated spent catalyst and returning the regenerated catalyst to the reactor, and separating the reaction product vapor to obtain the desired products, light olefins and aromatics. This process produces maximum light olefins such as propylene, ethylene, etc from heavy feedstocks, wherein the yield of propylene exceeds 20% by weight, and produces aromatics such as toluene, xylene, etc at the same time.

Abstract: A process for producing light olefins and aromatics, which comprises reacting a feedstock with a catalytic cracking catalyst in at least two reaction zones, wherein the reaction temperature of at least one reaction zone downstream of the first reaction zone is higher than that of the first reaction zone and its weight hourly space velocity is lower than that of the first reaction zone. The spent catalyst is separated, from the reaction product vapor, regenerated, and then returned to the reactor. The reaction product vapor is separated to obtain the desired products, light olefins and aromatics. This process efficiently produces light olefins such as propylene, ethylene, etc from heavy feedstocks, wherein the yield of propylene exceeds 20% by weight, and produces aromatics such as toluene, xylene, etc at the same time.

Abstract: A noble metal-containing titanosilicate material, characterized in that said material is represented with the oxide form of xTiO2.100SiO2.yEOm.zE, wherein x ranges from 0.001 to 50.0; (y+z) ranges from 0.0001 to 20.0 and y/z<5; E represents one or more noble metals selected from the group consisting of Ru, Rh, Pd, Re, Os, Ir, Pt, Ag and Au; m is a number satisfying the oxidation state of E. The crystal grains of said material contain a hollow structure, or a sagging structure. In said material, the synergistic effect between the noble metal and the titanosilicate are enhanced. As compared with the prior art, the selectivity, catalytic activity and stability of the reaction product are obviously increased in the oxidation reaction, e.g. the reaction for preparing propylene oxide by epoxidation of propylene.

Abstract: A noble metal-containing titanosilicate material, characterized in that said material is represented with the oxide form of xTiO2.100SiO2.yEOm.zE, wherein x ranges from 0.001 to 50.0; (y+z) ranges from 0.0001 to 20.0 and y/z<5; E represents one or more noble metals selected from the group consisting of Ru, Rh, Pd, Re, Os, Ir, Pt, Ag and Au; m is a number satisfying the oxidation state of E. The crystal grains of said material contain a hollow structure, or a sagging structure. In said material, the synergistic effect between the noble metal and the titanosilicate are enhanced. As compared with the prior art, the selectivity, catalytic activity and stability of the reaction product are obviously increased in the oxidation reaction, e.g. the reaction for preparing propylene oxide by epoxidation of propylene.

Abstract: A process for producing light olefins and aromatics, which comprises reacting a feedstock with a catalytic cracking catalyst in at least two reaction zones, wherein the reaction temperature of at least one reaction zone downstream of the first reaction zone is higher than that of the first reaction zone and its weight hourly space velocity is lower than that of the first reaction zone. The spent catalyst is separated from the reaction product vapor, regenerated and then returned to the reactor. The reaction product vapor is separated to obtain the desired products, light olefins and aromatics. This process efficiently produces light olefins such as propylene, ethylene, etc. from heavy feedstocks, wherein the yield of propylene exceeds 20% by weight, and produces aromatics such as toluene, xylene, etc. at the same time.

Abstract: A catalytic conversion process for producing light olefins with a high yield from petroleum hydrocarbons, which comprises the steps of contacting a pre-heated petroleum hydrocarbons feedstock with a catalyst which comprises phosphorus and transition metal modified silica rich zeolite having a structure of pentasil in a riser or a fluidized bed reactor, and converting under the catalytic conversion conditions to produce reaction effluent and a spent catalyst, separating the resulted reaction effluent and spent catalyst, further separating said reaction effluent into liquid products and gaseous products comprising ethylene and propylene; stripping the spent catalyst by steam; regenerating the stripped catalyst by contacting the spent catalyst with oxygen-containing gas and burning off coke; and recycling the regenerated catalyst to reactor for reuse.

Abstract: A stripper and a stripping process for removing the flue gas carried by regenerated catalyst. A cylindrical stripper mainly comprises a degassing pipe at the longitudinal axis, a horizontal pipe connected with the lower end of the degassing pipe, several sets of inner annular baffles and outer annular baffles arranged in alternative arrangement along the vertical direction. Inner annular baffles are fixed on the degassing pipe, outer annular baffles are fixed on the inner wall of the cylinder. The degassing pipe has holes below each set of the inner annular baffles. The regenerated catalyst enters the stripper from the upper part, comes into a countercurrent and crosscurrent contact with steam from the annular steam conduit, and the stripped regenerated catalyst leaves the stripper from the bottom.

Abstract: A catalytic conversion process for producing light olefins with a high yield from petroleum hydrocarbons, which comprises the steps of contacting a pre-heated petroleum hydrocarbons feedstock with a catalyst which comprises phosphorus and transition metal modified silica rich zeolite having a structure of pentasil in a riser or a fluidized bed reactor, and converting under the catalytic conversion conditions to produce reaction effluent and a spent catalyst, separating the resulted reaction effluent and spent catalyst, further separating said reaction effluent into liquid products and gaseous products comprising ethylene and propylene; stripping the spent catalyst by steam; regenerating the stripped catalyst by contacting the spent catalyst with oxygen-containing gas and burning off coke; and recycling the regenerated catalyst to reactor for reuse.

Abstract: A stripper and a stripping process for removing the flue gas carried by regenerated catalyst. A cylindrical stripper mainly comprises a degassing pipe at the longitudinal axis, a horizontal pipe connected with the lower end of the degassing pipe, several sets of inner annular baffles and outer annular baffles arranged in alternative arrangement along the vertical direction. Inner annular baffles are fixed on the degassing pipe, outer annular baffles are fixed on the inner wall of the cylinder. The degassing pipe has holes below each set of the inner annular baffles. The regenerated catalyst enters the stripper from the upper part, comes into a countercurrent and crosscurrent contact with steam from the annular steam conduit, and the stripped regenerated catalyst leaves the stripper from the bottom.

Abstract: A stripper and a stripping process for removing the flue gas carried by regenerated catalyst. A cylindrical stripper mainly comprises a degassing pipe at the longitudinal axis, a horizontal pipe connected with the lower end of the degassing pipe, several sets of inner annular baffles and outer annular baffles arranged in alternative arrangement along the vertical direction. Inner annular baffles are fixed on the degassing pipe, outer annular baffles are fixed on the inner wall of the cylinder. The degassing pipe has holes below each set of the inner annular baffles. The regenerated catalyst enters the stripper from the upper part, comes into a countercurrent and crosscurrent contact with steam from the annular steam conduit, and the stripped regenerated catalyst leaves the stripper from the bottom.

Abstract: A process for catalytic conversion of hydrocarbon feedstock to produce isobutane and isoparaffin-enriched gasoline which comprises two different reactions, the preheated feedstock is contacted with hot regenerated catalyst in the lower part of a reactor with the result that catalytic cracking reaction takes place, and the mixture of vapors and the coke deposited catalyst are up-flowed and enter into a suitable reaction environment with the result that isomerization and hydrogen transfer reaction take place. The produced LPG has an isobutane content of about 20 wt % to about 40 wt % and the produced gasoline contains isoparaffin content of about 30 wt % to about 45 wt % and olefin content of less than 30 wt %. RON and MON of the gasoline are 90˜93 and 80˜84 respectively.

Abstract: The present invention relates to a titanium-silicalite (TS-1) molecular sieve and the method for preparation of the same, wherein each crystallite of said titanium-silicalite molecular sieve has a hollow cavity with a radial length of 5-300 nm. The benzene adsorption capacity of the molecular sieve determined at 25° C. and P/P0=0.10 for 1 hour is at least 70 mg/g; and the method for preparation of said molecular sieve comprises an acid-treatment and then an organic-base treatment of the synthesized TS-1 molecular sieve, or only an organic-base treatment. The TS-1 molecular sieve of the present invention has a relatively high reactivity and activity stability in the catalytic oxidation.