Abstract: The invention relates to the field of medicinal chemistry, in particular to a substituted diaryl compound shown as a formula (I), a preparation method of the substituted diaryl compound, a medicinal preparation containing the substituted diaryl compound and medical application of the substituted diaryl compound. Pharmacological test results show that the substituted diaryl compound disclosed by the invention has a good inhibition effect on cells of human lung cancer (A549), human ovarian cancer (SKOV3), human melanoma (A375) and human colon cancer (LOVO).

Abstract: The present invention provides a SAPO-34 molecular sieve with small crystal size and a hollow structure rapidly synthesized from a waste MTO catalyst and a method for preparation thereof. The method comprises of the following steps: calcining a waste MTO catalyst fine powder; mixing it with an inorganic acid solution to obtain a mixed solution; adding an organic amine and a phosphorus source to the mixed solution, and stirring it to obtain an initial gel mixture for SAPO-34 molecular sieve; crystallizing the initial gel mixture, and then drying the resultant to obtain a raw SAPO-34 molecular sieve powder; and calcining the raw powder obtained to obtain the SAPO-34 molecular sieve with small crystal size and a hollow structure.

Abstract: The present invention provides a long-lifetime SAPO-34 catalyst prepared from waste MTO catalyst as a raw material and a preparation method thereof. The method comprises the following steps: mixing the waste MTO catalyst fine powder with water; adding a phosphoric acid and an organic amine and stirring to obtain an initial gel mixture for SAPO-34 molecular sieve; crystallizing the initial gel mixture and then at least drying it to obtain a raw SAPO-34 molecular sieve powder; calcining the raw molecular sieve powder to obtain a SAPO-34 molecular sieve powder; then mixing it with a binder and a matrix carrier in water with stirring, and then aging it; and molding and then calcining it to obtain the long-lifetime SAPO-34 catalyst. The preparation method of the present invention uses MTO waste catalyst as a raw material to synthesize SAPO-34 molecular sieve in situ within a short time, and to prepare MTO catalysts having a long life and high selectivity for light olefins.

Abstract: The invention provides a process for producing low-carbon olefins by gaseous phase catalytic cracking of heavy oil with multi-stages in milliseconds, comprising: a high-efficiency atomizing nozzle sprays the preheated heavy oil into an upper portion of the downflow modification reaction tube, the produced oil mist is mixed with a high temperature heat carrier flowing downward from a return controller for pyrolysis, and then the pyrolysis products are subject to a gas-solid separation at the bottom of the downflow modification reaction tube; then the coked heat carrier obtained by the separation enters into a lower portion of a modification regeneration reactor to conduct a regeneration reaction, the obtained regeneration gas and the high temperature heat carrier are subject to a gas-solid separation on the top of the modified regeneration reactor, then the high temperature heat carrier returns to a top of the downflow reaction tube to participate in circulation, the regeneration gas is subject to heat exchang