Abstract: A composition is disclosed having minimum halogen content, fire-retardance and/or drip-resistant characteristics. The composition comprises an effective amount of a polycarbonate, a glass fiber, a polysiloxane-polycarbonate copolymer, and a synergistic combination of an aromatic sulfone sulfonate such as potassium diphenylsulfone sulfonate with an aromatic sulfonate such as sodium salt of toluene sulfonic acid, optionally in the presence of an anti-drip agent. The polycarbonate composition is useful for manufacture of electronic and mechanical articles, among others.

Abstract: A polycarbonate composition is disclosed having zero or minimum halogen content, while also exhibiting improved fire-retardance and/or drip-resistant characteristics. The composition comprises an effective amount of a polycarbonate, an anti-dripping agent, an aromatic sulfone sulfonate, an aromatic sulfonate, a synergistic combination of an elastomer-modified graft copolymer and a polysiloxane-polycarbonate copolymer, and an optional siloxane oligomer. The polycarbonate composition is useful for manufacture of electronic and mechanical articles, among others.

Abstract: A thermoplastic composition comprises a polycarbonate, an acrylonitrile-styrene-acrylate terpolymer, and a low gloss additive, wherein the 60° gloss is measured to be less than or equal to 90 GU according to ASTM D2457. The thermoplastic composition has excellent low gloss performance and mechanical performance. A method of making the thermoplastic composition, and an article comprising the thermoplastic composition are also disclosed.

Abstract: A thermoplastic polycarbonate composition is disclosed, in various embodiments, having enhanced low-temperature ductility, UV resistance and/or fire-retardance characteristics. The composition comprises a polycarbonate, and a combination of an elastomer-modified graft copolymer and a polysiloxane-polycarbonate copolymer. The polycarbonate composition is useful for manufacture of electronic and mechanical parts, among others.

Abstract: A thermoplastic composition comprises a polycarbonate, a polysiloxane-polycarbonate, and a gel-type low gloss additive, wherein the 60° gloss is measured to be less than or equal to 90 GU according to ASTM D2457. The thermoplastic composition has excellent impact strength and color capability. A method of making the thermoplastic composition, and an article comprising the thermoplastic composition are also disclosed.

Abstract: A thermoplastic polycarbonate composition is disclosed, in various embodiments, having enhanced low-temperature ductility, UV resistance and/or fire-retardance characteristics. The composition comprises a polycarbonate, and a combination of an elastomer-modified graft copolymer and a polysiloxane-polycarbonate copolymer. The polycarbonate composition is useful for manufacture of electronic and mechanical parts, among others.

Abstract: A polycarbonate composition is disclosed having zero or minimum halogen content, while also exhibiting improved fire-retardance and/or drip-resistant characteristics. The composition comprises an effective amount of a polycarbonate, an anti-dripping agent, an aromatic sulfone sulfonate, an aromatic sulfonate, a synergistic combination of an elastomer-modified graft copolymer and a polysiloxane-polycarbonate copolymer, and an optional siloxane oligomer. The polycarbonate composition is useful for manufacture of electronic and mechanical articles, among others.

Abstract: A halogen-free polycarbonate composition is disclosed having improved fire-retardancy and/or transparency characteristics. The composition comprises a polycarbonate, and a synergic combination of an aromatic sulfone sulfonate such as potassium diphenylsulfone sulfonate, an aromatic sulfonate such as sodium salt of toluene sulfonic acid, and optionally a siloxane oligomer. The polycarbonate composition is useful for manufacture of electronic and mechanical parts, among others.

Abstract: A composition is disclosed having minimum halogen content, fire-retardance and/or drip-resistant characteristics. The composition comprises an effective amount of a polycarbonate, a glass fiber, a polysiloxane-polycarbonate copolymer, and a synergistic combination of an aromatic sulfone sulfonate such as potassium diphenylsulfone sulfonate with an aromatic sulfonate such as sodium salt of toluene sulfonic acid, optionally in the presence of an anti-drip agent. The polycarbonate composition is useful for manufacture of electronic and mechanical articles, among others.

Abstract: A thermoplastic composition comprises a polycarbonate, a polysiloxane-polycarbonate, and a gel-type low gloss additive, wherein the 60° gloss is measured to be less than or equal to 90 GU according to ASTM D2457. The thermoplastic composition has excellent impact strength and color capability. A method of making the thermoplastic composition, and an article comprising the thermoplastic composition are also disclosed.

Abstract: A thermoplastic composition comprises a polycarbonate, an acrylonitrile-styrene-acrylate terpolymer, and a low gloss additive, wherein the 60° gloss is measured to be less than or equal to 90 GU according to ASTM D2457. The thermoplastic composition has excellent low gloss performance and mechanical performance. A method of making the thermoplastic composition, and an article comprising the thermoplastic composition are also disclosed.

Abstract: A process for the production of an ionic transition metal catalyst in supported form than is highly productive under gas phase olefin polymerization conditions. In the process a an aluminum alkyl is added to a suitable solvent after which a neutral metallocene compound is added to the solution under stirring in a quantity that provides for a ratio of Al to transition metal of at least 25:1. To this metallocene-aluminum alkyl solution is next added an ionic compound the anionic portion of which is a non-coordinating anion under stirring until all materials are dissolve. The ionic compound is added in a quantity that provides for a ratio of NCA to transition metal of at least 1:1. Next the support particles are added to the solution and thereafter the solution is heated to at least 40° C. and held at this elevated temperature for at least 0.5 hour. Thereafter the solvent is removed and the supported catalyst is dried under vacuum.

Abstract: A process for the production of an ionic transition metal catalyst in supported form than is highly productive under gas phase olefin polymerization conditions. In the process a an aluminum alkyl is added to a suitable solvent after which a neutral metallocene compound is added to the solution under stirring in a quantity that provides for a ratio of Al to transition metal of at least 25:1. To this metallocene-aluminum alkyl solution is next added an ionic compound the anionic portion of which is a non-coordinating anion under stirring until all materials are dissolve. The ionic compound is added in a quantity that provides for a ratio of NCA to transition metal of at least 1:1. Next the support particles are added to the solution and thereafter the solution is heated to at least 40° C. and held at this elevated temperature for at least 0.5 hour. Thereafter the solvent is removed and the supported catalyst is dried under vacuum.

Abstract: The invention provides a process for reducing the low molecular weight oligomer content of olefin polymers produced by metallocene catalysis wherein at least one organometallic compound is fed continuously into the reactor during polymerization. The organometallic compound has the formula R1nA, wherein A is a Periodic Table Group 12 or 13 element. R1 is the same or different, substituted or unsubstituted, straight or branched chain alkylradical, cyclic hydrocarbyl radical, alkyl-cyclohydrocarbyl radical, aromatic radical or alkoxide radical and n is 2 or 3, to form a polymer product having a content of said compound of at least about 50 weight ppm.

Abstract: A process for the production of an ionic transition metal catalyst in supported form than is highly productive under gas phase olefin polymerization conditions. In the process a an aluminum alkyl is added to a suitable solvent after which a neutral metallocene compound is added to the solution under stirring in a quantity that provides for a ratio of Al to transition metal of at least 25:1. To this metallocene-aluminum alkyl solution is next added an ionic compound the anionic portion of which is a non-coordinating anion under stirring until all materials are dissolve. The ionic compound is added in a quantity that provides for a ratio of NCA to transition metal of at least 1:1. Next the support particles are added to the solution and thereafter the solution is heated to at least 40° C. and held at this elevated temperature for at least 0.5 hour. Thereafter the solvent is removed and the supported catalyst is dried under vacuum.

Abstract: A process for the production of an ionic transition metal catalyst in supported form than is highly productive under gas phase olefin polymerization conditions. In the process a an aluminum alkyl is added to a suitable solvent after which a neutral metallocene compound is added to the solution under stirring in a quantity that provides for a ratio of Al to transition metal of at least 25:1. To this metallocene-aluminum alkyl solution is next added an ionic compound the anionic portion of which is a non-coordinating anion under stirring until all materials are dissolve. The ionic compound is added in a quantity that provides for a ratio of NCA to transition metal of at least 1:1. Next the support particles are added to the solution and thereafter the solution is heated to at least 40° C. and held at this elevated temperature for at least 0.5 hour. Thereafter the solvent is removed and the supported catalyst is dried under vacuum.

Abstract: The invention provides a process for reducing the low molecular weight oligomer content of olefin polymers produced by metallocene catalysis wherein at least one organometallic compound is fed continuously into the reactor during polymerization. The organometallic compound has the formula R1nA, wherein A is a Periodic Table Group 12 or 13 element. R1 is the same or different, substituted or unsubstituted, straight or branched chain alkylradical, cyclic hydrocarbyl radical, alkyl-cyclohydrocarbyl radical, aromatic radical or alkoxide radical and n is 2 or 3, to form a polymer product having a content of said compound of at least about 50 weight ppm.

Abstract: A catalyst composition is provided, which is prepared by contacting a cycloalkadienyl compound, a transition metal amide of the formula M(NMe2)mXn, an aluminoxane, and optionally a solid support at a temperature of 0 to 100° C.

Abstract: A process for the preparation of (i) polyethylene or (ii) polypropylene, which is essentially isotactic or a mixture of atactic and isotactic polypropylenes comprising contacting ethylene or propylene per se, or in admixture with one or more alpha-olefins, under polymerization conditions, with a catalyst system comprising: (a) a precatalyst comprising a mixture of racemic and meso stereoisomers of a metallocene catalyst containing two cycloalkadienyl ligands joined by a bridging linkage, said ligands complexed to a metal atom; and (b) (1) to obtain polyethylene catalyzed by the rac epimer only, a cocatalyst selected from the group consisting of tris(perfluorophenyl)borane and isobutyl alumoxane;  (2) to obtain polyethylene catalyzed by both the rac and the meso epimers, a cocatalyst selected from the group consisting of dimethylanilinium tetrakis(perfluorophenyl)borate and triphenylmethyl tetrakis(perfluorophenyl)borate;  (3) to obtain polypropylene, which is essentially isotactic, a cocatalyst

Abstract: A process for the polymerization of an olefin which employs as the catalyst composition the reaction product of a) a monocycloalkadienyl catalyst precursor; b) an activity enhancing cycloalkadiene; and c) an activating cocatalyst is disclosed.