Patents by Inventor Xionghou Gao
Xionghou Gao has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11111152Abstract: A preparation method for modified molecular sieve and a modified molecular sieve-containing catalytic cracking catalyst. The preparation method comprises: mixing molecular sieve slurry, a compound solution containing ions of group IIIB metals of the periodic table of elements, organic complexing agent and/or dispersing agent and precipitating agent to obtain mixed slurry containing molecular sieve and precipitates of group IIIB elements in the periodic table of elements; and drying, and roasting or not roasting to obtain molecular sieve modified by the group IIIB elements. A weight ratio of group IIIB elements calculated based on oxides to molecular sieve dry basis is equal to (0.3-10):100, a molar ratio of organic complexing agent to ions of group IIIB metals is equal to (0.3-10):1, and a molar ratio of dispersing agent to the ions of group IIIB metals is equal to (0.2-16):1. Also related to is the catalytic cracking catalyst containing the modified molecular sieve prepared according to the method.Type: GrantFiled: August 4, 2016Date of Patent: September 7, 2021Assignee: PETROCHINA COMPANY LIMITEDInventors: Xionghou Gao, Shuhong Sun, Yunfeng Zheng, Xiaoliang Huang, Aiguo Lin, Xiaoyan Li, Lin Wang, Gengzhen Cao, Conghua Liu, Zhishuang Pan, Wei Ding, Yahong Wang, Dong Wang, Qiuxia Teng, Haitao Zhang
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Publication number: 20180222756Abstract: A preparation method for modified molecular sieve and a modified molecular sieve-containing catalytic cracking catalyst. The preparation method comprises: mixing molecular sieve slurry, a compound solution containing ions of group IIIB metals of the periodic table of elements, organic complexing agent and/or dispersing agent and precipitating agent to obtain mixed slurry containing molecular sieve and precipitates of group IIIB elements in the periodic table of elements; and drying, and roasting or not roasting to obtain molecular sieve modified by the group IIIB elements. A weight ratio of group IIIB elements calculated based on oxides to molecular sieve dry basis is equal to (0.3-10):100, a molar ratio of organic complexing agent to ions of group IIIB metals is equal to (0.3-10):1, and a molar ratio of dispersing agent to the ions of group IIIB metals is equal to (0.2-16):1. Also related to is the catalytic cracking catalyst containing the modified molecular sieve prepared according to the method.Type: ApplicationFiled: August 4, 2016Publication date: August 9, 2018Applicant: Petrochina Company LimitedInventors: Xionghou Gao, Shuhong Sun, Yunfeng Zheng, Xiaoliang Huang, Aiguo Lin, Xiaoyan Li, Lin Wang, Gengzhen Cao, Conghua Liu, Zhishuang Pan, Wei Ding, Yahong Wang, Dong Wang, Qiuxia Teng, Haitao Zhang
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Patent number: 9968918Abstract: The present invention provides a catalytic cracking catalyst for heavy oil and preparation methods thereof. The catalyst comprises 2 to 50% by weight of a phosphorus-containing ultrastable rare earth Y-type molecular sieve, 0.5 to 30% by weight of one or more other molecular sieves, 0.5 to 70% by weight of clay, 1.0 to 65% by weight of high-temperature-resistant inorganic oxides, and 0.01 to 12.5% by weight of a rare earth oxide. The phosphorus-containing ultra-stable rare earth Y-type molecular sieve uses a NaY molecular sieve as a raw material.Type: GrantFiled: July 27, 2012Date of Patent: May 15, 2018Assignee: PETROCHINA COMPANY LIMITEDInventors: Xionghou Gao, Haitao Zhang, Di Li, Zhengguo Tan, Hongchang Duan, Xueli Li, Chaowei Liu, Yunfeng Zheng, Xiaoliang Huang, Jinjun Cai, Zhishuang Pan, Xueqin Sun
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Patent number: 9968915Abstract: Provided is a phosphorus-containing ultrastable Y-type rare earth (RE) molecular sieve and the preparation method thereof. The method is: based on NaY molecular sieve as a raw material, obtaining “one-exchange one-roast” RE-Na Y-type molecular sieve through the steps of exchanging with RE, pre-exchanging with dispersing, and the first calcination; and then performing ammonium salt exchange, phosphorus modification, and the second calcination on the “one-exchange one-roast” RE-Na Y-type molecular sieve, wherein the sequence of the RE exchange and the pre-exchange with dispersing is unlimited, and the sequence of the ammonium salt exchange and the phosphorus modification is unlimited as well. The obtained molecular sieve contains RE oxide 1-20 wt %, phosphorus 0.1-5 wt %, and sodium oxide no more than 1.2 wt %, and has a crystallization degree of 51-69% and a lattice parameter of 2.449-2.469 nm.Type: GrantFiled: July 27, 2012Date of Patent: May 15, 2018Assignee: PETROCHINA COMPANY LIMITEDInventors: Xionghou Gao, Haitao Zhang, Di Li, Xueli Li, Hongchang Duan, Zhengguo Tan, Chaowei Liu, Yunfeng Zheng, Xiaoliang Huang, Jinjun Cai, Chenxi Zhang, Zhishuang Pan, Gengzhen Cao
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Patent number: 9895686Abstract: A method for producing double-component modified molecular sieve comprises adding molecular sieve to an aqueous solution containing phosphorus to form a mixture, allowing the mixture to react at pH of 1-10, temperature of 70-200° C. and pressure of 0.2-1.2 MPa for 10-200 min, and then filtering, drying and baking the resultant to obtain phosphorus-modified molecular sieve, and then adding the phosphorus-modified molecular sieve to an aqueous solution containing silver ions, allowing the phosphorus-modified molecular sieve to react with silver ions at 0-100° C. in dark condition for 30-150 min, and then filtering, drying and baking. The obtained double-component modified molecular sieve contains 88-99 wt % molecular sieve with a ratio of silica to alumina between 15 and 60, 0.5-10 wt % phosphorus (based on oxides) and 0.01-2 wt % silver (based on oxides), all based on dry matter. A catalyst produced from the double-component modified molecular sieve has improved hydrothermal stability and microactivity.Type: GrantFiled: December 1, 2009Date of Patent: February 20, 2018Assignee: PetroChina Company LimitedInventors: Xionghou Gao, Dong Ji, Haitao Zhang, Hongchang Duan, Di Li, ZhengGuo Tan, Yi Su, Zhicheng Tang, Yi Wang, Yanqing Ma, Yanbo Sun
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Patent number: 9889439Abstract: The present invention relates to a heavy oil catalytic cracking catalyst having a high yield of light oil and preparation methods thereof. The catalyst comprises 2 to 50% by weight of a magnesium-modified ultra-stable rare earth type Y molecular sieve, 0.5 to 30% by weight of one or more other molecular sieves, 0.5 to 70% by weight of clay, 1.0 to 65% by weight of high-temperature-resistant inorganic oxides, and 0.01 to 12.5% by weight of rare earth oxide. The magnesium-modified ultra-stable rare earth type Y molecular sieve is obtained by the following manner: the raw material, a NaY molecular sieve, is subjected to a rare earth exchange, a dispersing pre-exchange, a magnesium salt exchange modification, an ammonium salt exchange for sodium reduction, a second exchange and a second calcination. The catalyst provided in the present invention is characteristic in its high conversion capacity of heavy oil and a high yield of light oil.Type: GrantFiled: April 13, 2012Date of Patent: February 13, 2018Assignee: PetroChina Company LimitedInventors: Xionghou Gao, Haitao Zhang, Hongchang Duan, Di Li, Xueli Li, Zhengguo Tan, Xiaoliang Huang, Jinjun Cai, Yunfeng Zheng, Chenxi Zhang, Gengzhen Cao
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Patent number: 9844772Abstract: The present invention relates to a heavy oil catalytic cracking catalyst and preparation method thereof. The catalyst comprises 2 to 50% by weight of an ultra-stable rare earth type Y molecular sieve, 0.5 to 30% by weight of one or more other molecular sieves, 0.5 to 70% by weight of clay, 1.0 to 65% by weight of high-temperature-resistant inorganic oxides, and 0.01 to 12.5% by weight of rare earth oxide. The ultra-stable rare earth type Y molecular sieve is obtained as follows: the raw material, NaY molecular sieve, is subjected to a rare earth exchange and a dispersing pre-exchange, and the molecular sieve slurry is filtered, washed and subjected to a first calcination to produce a “one-exchange one-calcination” rare earth sodium Y molecular sieve, wherein the order of the rare earth exchange and the dispersing pre-exchange is not limited; and the “one-exchange one-calcination” rare earth sodium Y molecular sieve is further subjected to ammonium salt exchange for sodium reduction and a second calcination.Type: GrantFiled: April 13, 2012Date of Patent: December 19, 2017Assignee: PetroChina Company LimitedInventors: Xionghou Gao, Haitao Zhang, Zhengguo Tan, Di Li, Dong Ji, Hongchang Duan, Chenxi Zhang
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Patent number: 9840422Abstract: The present invention provides a magnesium-modified ultra-stable rare earth type Y molecular sieve and the preparation method thereof, which method is carried out by subjecting a NaY molecular sieve as the raw material to a rare earth exchange and a dispersing pre-exchange, then to an ultra-stabilization calcination treatment, and finally to a magnesium modification. The molecular sieve comprises 0.2 to 5% by weight of magnesium oxide, 1 to 20% by weight of rare earth oxide, and not more than 1.2% by weight of sodium oxide, and has a crystallinity of 46 to 63%, and a lattice parameter of 2.454 nm to 2.471 nm. In contrast to the prior art, in the molecular sieve prepared by this method, rare earth ions are located in sodalite cages, which is demonstrated by the fact that no rare earth ion is lost during the reverse exchange process. Moreover, the molecular sieve prepared by such a method has a molecular particle size D(v,0.5) of not more than 3.0 ?m and a D(v,0.9) of not more than 20 ?m.Type: GrantFiled: April 13, 2012Date of Patent: December 12, 2017Assignee: PetroChina Company LimitedInventors: Xionghou Gao, Haitao Zhang, Hongchang Duan, Chaowei Liu, Di Li, Xueli Li, Zhengguo Tan, Yunfeng Zheng, Xiaoliang Huang, Jinjun Cai, Chenxi Zhang
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Patent number: 9789475Abstract: The present invention provides an ultra-stable rare earth type Y molecular sieve and the preparation method thereof, which method is carried out by subjecting a NaY molecular sieve as the raw material to a rare earth exchange and a dispersing pre-exchange, then to an ultra-stabilization calcination treatment. The molecular sieve comprises 1 to 20% by weight of rare earth oxide, not more than 1.2% by weight of sodium oxide, has a crystallinity of 51 to 69%, and a lattice parameter of 2.451 nm to 2.469 nm. In contrast to the prior art, in the molecular sieve prepared by this method, rare earth ions are located in sodalite cages, which is demonstrated by the fact that no rare earth ion is lost during the reverse exchange process. Moreover, the molecular sieve prepared by such a method has a molecular particle size D(v,0.5) of not more than 3.0 ?m and a D(v,0.9) of not more than 20 ?m.Type: GrantFiled: April 13, 2012Date of Patent: October 17, 2017Assignee: Petrochina Company LimitedInventors: Xionghou Gao, Haitao Zhang, Zhengguo Tan, Di Li, Dong Ji, Hongchang Duan, Chenxi Zhang
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Publication number: 20150209767Abstract: Provided is a phosphorus-containing ultrastable Y-type rare earth (RE) molecular sieve and the preparation method thereof. The method is: based on Na Y molecular sieve as a raw material, obtaining “one-exchange one-roast” RE-Na Y-type molecular sieve through the steps of exchanging with RE, pre-exchanging with dispersing, and the first calcination; and then performing ammonium salt exchange, phosphorus modification, and the second calcination on the “one-exchange one-roast” RE-Na Y-type molecular sieve, wherein the sequence of the RE exchange and the pre-exchange with dispersing is unlimited, and the sequence of the ammonium salt exchange and the phosphorus modification is unlimited as well. The obtained molecular sieve contains RE oxide 1-20 wt %, phosphorus 0.1-5 wt %, and sodium oxide no more than 1.2 wt %, and has a crystallization degree of 51-69% and a lattice parameter of 2.449-2.469 nm.Type: ApplicationFiled: July 27, 2012Publication date: July 30, 2015Applicant: PetroChina Company LimitedInventors: Xionghou Gao, Haitao Zhang, Di Li, Xueli Li, Hongchang Duan, Zhengguo Tan, Chaowei Liu, Yunfeng Zheng, Xiaoliang Huang, Jinjun Cai, Chenxi Zhang, Zhishuang Pan, Gengzhen Cao
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Publication number: 20150175432Abstract: The present invention provides a magnesium-modified ultra-stable rare earth type Y molecular sieve and the preparation method thereof, which method is carried out by subjecting a NaY molecular sieve as the raw material to a rare earth exchange and a dispersing pre-exchange, then to an ultra-stabilization calcination treatment, and finally to a magnesium modification. The molecular sieve comprises 0.2 to 5% by weight of magnesium oxide, 1 to 20% by weight of rare earth oxide, and not more than 1.2% by weight of sodium oxide, and has a crystallinity of 46 to 63%, and a lattice parameter of 2.454 nm to 2.471 nm. In contrast to the prior art, in the molecular sieve prepared by this method, rare earth ions are located in sodalite cages, which is demonstrated by the fact that no rare earth ion is lost during the reverse exchange process. Moreover, the molecular sieve prepared by such a method has a molecular particle size D(v,0.5) of not more than 3.0 ?m and a D(v,0.9) of not more than 20 ?m.Type: ApplicationFiled: April 13, 2012Publication date: June 25, 2015Applicant: PetroChina Company LimitedInventors: Xionghou Gao, Haitao Zhang, Hongchang Duan, Chaowei Liu, Di Li, Xueli Li, Zhengguo Tan, Yunfeng Zheng, Xiaoliang Huang, Jinjun Cai, Chenxi Zhang
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Patent number: 9062261Abstract: The invention relates to a catalytic cracking process for reducing sulfur content in gasoline and the device thereof, which includes a fluidized bed reactor in addition of a heavy oil catalytic cracking riser, characterized in enhancing contact time of oil-gas with the catalyst, further desulfurizing and reducing olefin content and increasing octane number in gasoline; regenerating all recycling catalysts, quality of products being stable and easily operated, reducing sulfur of gasoline to a maximum limit; adding a cooling device so as to avoid coking when the catalyst contacts with oil-gas in high temperature and decrease of yield of light oil resulted by excessively high reaction temperature of gasoline upgrading, improving products distribution, being flexible to change catalyst-oil ratio and reaction temperature of catalytic cracking reaction.Type: GrantFiled: June 10, 2010Date of Patent: June 23, 2015Assignee: PETROCHINA COMPANY LIMITEDInventors: Xionghou Gao, Shuhong Sun, Lin Wang, Xinmei Pang, Zhifeng Wang, Yongfu Gao, Zhaoyong Liu, Conghua Liu, Jinsen Gao, Gang Wang, Yanhui Zhang, Tao Liu, Juanjuan Liu
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Publication number: 20150165428Abstract: The present invention provides a catalytic cracking catalyst for heavy oil and preparation methods thereof. The catalyst comprises 2 to 50% by weight of a phosphorus-containing ultrastable rare earth Y-type molecular sieve, 0.5 to 30% by weight of one or more other molecular sieves, 0.5 to 70% by weight of clay, 1.0 to 65% by weight of high-temperature-resistant inorganic oxides, and 0.01 to 12.5% by weight of a rare earth oxide. The phosphorus-containing ultra-stable rare earth Y-type molecular sieve uses a NaY molecular sieve as a raw material.Type: ApplicationFiled: July 27, 2012Publication date: June 18, 2015Applicant: PetroChina Company LimitedInventors: Xionghou Gao, Haitao Zhang, Di Li, Zhengguo Tan, Hongchang Duan, Xueli Li, Chaowei Liu, Yunfeng Zheng, Xiaoliang Huang, Jinjun Cai, Zhishuang Pan, Xueqin Sun
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Publication number: 20150151284Abstract: The present invention provides an ultra-stable rare earth type Y molecular sieve and the preparation method thereof, which method is carried out by subjecting a NaY molecular sieve as the raw material to a rare earth exchange and a dispersing pre-exchange, then to an ultra-stabilization calcination treatment. The molecular sieve comprises 1 to 20% by weight of rare earth oxide, not more than 1.2% by weight of sodium oxide, has a crystallinity of 51 to 69%, and a lattice parameter of 2.451 nm to 2.469 nm. In contrast to the prior art, in the molecular sieve prepared by this method, rare earth ions are located in sodalite cages, which is demonstrated by the fact that no rare earth ion is lost during the reverse exchange process. Moreover, the molecular sieve prepared by such a method has a molecular particle size D(v,0.5) of not more than 3.0 ?m and a D(v,0.9) of not more than 20 ?m.Type: ApplicationFiled: April 13, 2012Publication date: June 4, 2015Inventors: Xionghou Gao, Haitao Zhang, Zhengguo Tan, Di Li, Dong JI, Hongchang Duan, Chenxi Zhang
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Publication number: 20150080209Abstract: The present invention relates to a heavy oil catalytic cracking catalyst and preparation method thereof. The catalyst comprises 2 to 50% by weight of an ultra-stable rare earth type Y molecular sieve, 0.5 to 30% by weight of one or more other molecular sieves, 0.5 to 70% by weight of clay, 1.0 to 65% by weight of high-temperature-resistant inorganic oxides, and 0.01 to 12.5% by weight of rare earth oxide. The ultra-stable rare earth type Y molecular sieve is obtained as follows: the raw material, NaY molecular sieve, is subjected to a rare earth exchange and a dispersing pre-exchange, and the molecular sieve slurry is filtered, washed and subjected to a first calcination to produce a “one-exchange one-calcination” rare earth sodium Y molecular sieve, wherein the order of the rare earth exchange and the dispersing pre-exchange is not limited; and the “one-exchange one-calcination” rare earth sodium Y molecular sieve is further subjected to ammonium salt exchange for sodium reduction and a second calcination.Type: ApplicationFiled: April 13, 2012Publication date: March 19, 2015Applicant: PetroChina Company LimitedInventors: Xionghou Gao, Haitao Zhang, Zhengguo Tan, Di Li, Dong Ji, Hongchang Duan, Chenxi Zhang
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Publication number: 20150011378Abstract: The present invention relates to a heavy oil catalytic cracking catalyst having a high yield of light oil and preparation methods thereof. The catalyst comprises 2 to 50% by weight of a magnesium-modified ultra-stable rare earth type Y molecular sieve, 0.5 to 30% by weight of one or more other molecular sieves, 0.5 to 70% by weight of clay, 1.0 to 65% by weight of high-temperature-resistant inorganic oxides, and 0.01 to 12.5% by weight of rare earth oxide. The magnesium-modified ultra-stable rare earth type Y molecular sieve is obtained by the following manner: the raw material, a NaY molecular sieve, is subjected to a rare earth exchange, a dispersing pre-exchange, a magnesium salt exchange modification, an ammonium salt exchange for sodium reduction, a second exchange and a second calcination. The catalyst provided in the present invention is characteristic in its high conversion capacity of heavy oil and a high yield of light oil.Type: ApplicationFiled: April 13, 2012Publication date: January 8, 2015Applicant: PetroChina Company LimitedInventors: Xionghou Gao, Haitao Zhang, Hongchang Duan, Di Li, Xueli Li, Zhengguo Tan, Xiaoliang Huang, Jinjun Cai, Yunfeng Zheng, Chenxi Zhang, Gengzhen Cao
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Patent number: 8545803Abstract: Modified molecular sieve characterized by improved sodium-resisting contamination activity and preparation method thereof are provided. The method comprises: adding molecular sieve in phosphorus-containing organic solution, and reacting for 10-200 minutes at temperature of 70-200° C. and pressure of 0.2-1.2 MPa, and then filtering, drying and calcining. The said modified molecular sieve contains 90-99 wt. % molecular sieve as dry basis and 1-10 wt. % phosphorus as oxide. The said method can improve the capability of sodium-resisting contamination effectively, and its technology is simple and fits the existing catalyst production apparatus and process. The said modified molecular sieve has high sodium-resisting contamination activity, and the model catalyst by sodium contamination has high activity retention.Type: GrantFiled: December 1, 2009Date of Patent: October 1, 2013Assignee: PetroChina Company LimitedInventors: Xionghou Gao, Dong Ji, Haitao Zhang, Hongchang Duan, Di Li, ZhengGuo Tan, Yi Su, Chenxi Zhang, Yi Wang, Yanqing Ma, Yanbo Sun
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Publication number: 20120275994Abstract: A method for producing double-component modified molecular sieve comprises adding molecular sieve to an aqueous solution containing phosphorus to form a mixture, allowing the mixture to react at pH of 1-10, temperature of 70-200° C. and pressure of 0.2-1.2 MPa for 10-200 min, and then filtering, drying and baking the resultant to obtain phosphorus-modified molecular sieve, and then adding the phosphorus-modified molecular sieve to an aqueous solution containing silver ions, allowing the phosphorus-modified molecular sieve to react with silver ions at 0-100° C. in dark condition for 30-150 min, and then filtering, drying and baking. The obtained double-component modified molecular sieve contains 88-99 wt % molecular sieve with a ratio of silica to alumina between 15 and 60, 0.5-10 wt % phosphorus (based on oxides) and 0.01-2 wt % silver (based on oxides), all based on dry matter. A catalyst produced from the double-component modified molecular sieve has improved hydrothermal stability and microactivity.Type: ApplicationFiled: December 1, 2009Publication date: November 1, 2012Applicant: PetroChina Company LimitedInventors: Xionghou Gao, Dong Ji, Haitao Zhang, Hongchang Duan, Di Li, ZhengGuo Tan, Yi Su, Zhicheng Tang, Yi Wang, Yanqing Ma, Yanbo Sun
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Publication number: 20120213695Abstract: Modified molecular sieve characterized by improved sodium-resisting contamination activity and preparation method thereof are provided. The method comprises: adding molecular sieve in phosphorus-containing organic solution, and reacting for 10-200 minutes at temperature of 70-200° C. and pressure of 0.2-1.2 MPa, and then filtering, drying and calcining. The said modified molecular sieve contains 90-99 wt. % molecular sieve as dry basis and 1-10 wt. % phosphorus as oxide. The said method can improve the capability of sodium-resisting contamination effectively, and its technology is simple and fits the existing catalyst production apparatus and process. The said modified molecular sieve has high sodium-resisting contamination activity, and the model catalyst by sodium contamination has high activity retention.Type: ApplicationFiled: December 1, 2009Publication date: August 23, 2012Applicant: PetroChina Company LimitedInventors: Xionghou Gao, Dong Ji, Haitao Zhang, Hongchang Duan, Di Li, ZhengGuo Tan, Yi Su, Chenxi Zhang, Yi Wang, Yanqing Ma, Yanbo Sun
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Publication number: 20100314289Abstract: The invention relates to a catalytic cracking process for reducing sulfur content in gasoline and the device thereof, which includes a fluidized bed reactor in addition of a heavy oil catalytic cracking riser, characterized in enhancing contact time of oil-gas with the catalyst, further desulfurizing and reducing olefin content and increasing octane number in gasoline; regenerating all recycling catalysts, quality of products being stable and easily operated, reducing sulfur of gasoline to a maximum limit; adding a cooling device so as to avoid coking when the catalyst contacts with oil-gas in high temperature and decrease of yield of light oil resulted by excessively high reaction temperature of gasoline upgrading, improving products distribution, being flexible to change catalyst-oil ratio and reaction temperature of catalytic cracking reaction.Type: ApplicationFiled: June 10, 2010Publication date: December 16, 2010Applicant: PETROCHINA COMPANY LIMITEDInventors: Xionghou GAO, Shuhong SUN, Lin WANG, Xinmei PANG, Zhifeng WANG, Yongfu GAO, Zhaoyong LIU, Conghua LIU, Jinsen GAO, Gang WANG, Yanhui ZHANG, Tao LIU, Juanjuan LIU