Abstract: A closed-loop large-scale preparation method of fluoride nanomaterial is disclosed, comprising the following steps: dissolving initial raw material into water-soluble salt by using volatile acid; evaporating the remaining acid under reduced pressure and recovering; then, adding oily organic matter with high boiling point to continue to evaporate the combined volatile acid under reduced pressure; adding an oil-soluble fluorine source to the generated oil-soluble salt; increasing the reaction temperature to increase the crystallinity of the fluoride; after cooling, separating and recovering the product and the oily organic matter; and repeating the process to realize large-scale preparation. The method uses the closed-loop process flow, does not discharge waste, and has high device yield per unit volume, low production cost and low specified asset investment. The product has the characteristics of uniform particle size and good dispersibility.

Abstract: The present invention relates to a polysulfide upconversion phosphor, and belongs to the field of new optical function materials. The phosphor uses polysulfide as a substrate and rare earth ions as activators, and has a general formula of composition: mA2S·nBS·kC2-xS3:Dx. The upconversion phosphor provided by the present invention can emit ultraviolet, blue, blue-green, green, red and near-infrared light when excited by near infrared light at 750-1650 nm. Because the upconversion phosphor provided by the present invention uses polysulfide with low phonon energy and symmetry as a substrate material, and optimizes rare earth ions to be doped into the matrix material as luminescence centers, the upconversion phosphor has higher upconversion luminescence efficiency and safety and wider application range compared with industrial NaYF4:Yb, Er material.

Abstract: A closed-loop large-scale preparation method of fluoride nanomaterial is disclosed, comprising the following steps: dissolving initial raw material into water-soluble salt by using volatile acid; evaporating the remaining acid under reduced pressure and recovering; then, adding oily organic matter with high boiling point to continue to evaporate the combined volatile acid under reduced pressure; adding an oil-soluble fluorine source to the generated oil-soluble salt; increasing the reaction temperature to increase the crystallinity of the fluoride; after cooling, separating and recovering the product and the oily organic matter; and repeating the process to realize large-scale preparation. The method uses the closed-loop process flow, does not discharge waste, and has high device yield per unit volume, low production cost and low specified asset investment. The product has the characteristics of uniform particle size and good dispersibility.

Abstract: A long afterglow luminescent material of the formula aMO.bM? (S?Se1-?).cAl2O3.d B2O3.eP2O5: xEu.yLn, wherein M is/are selected from Sr, Ca, Ba, and Mg, and any combinations thereof; M? is/are selected from Sr, Ca, and Ba, and any combinations thereof; Ln is/are selected from Nd, Dy, Ho, Tm, La, Ce, Er, Pr, Bi, and Sm, and any combinations thereof; a, b, c, d, e, x and y are mole ratios, wherein 0.5<a<6.0, 0.0001?b?2.0, 0.5?c?9.0, 0?d?1.0, 0?e?1.0, 0.00001?x?0.25, 0.00001?y?0.3, 0???1.0, 0.5<(a+b)?6.0, 0<(d+e)?1.0. The preparation process thereof is a high temperature solid-state reaction comprising an oxidation stage and a subsequent reduction stage.

Abstract: A light-storage self-luminescent glass is disclosed, comprising from 0.01 to 40% of a light-storage self-luminescent material activated by multiple ions and from 99.99 to 60% of a matrix glass; wherein the light-storage self-luminescent material has a particle size from 10 ?m to 20 mm, and the matrix glass can be a low melting point glass or a common silicate glass. A process for producing the glass is also disclosed, comprising doping a light-storage self-luminescent material during the forming process of a common silicate glass, or thoroughly mixing low melting point glass powder with a light-storage self-luminescent material, and then heat treating the system at 700-1100° C. to obtain the light-storage self-luminescent glass. The process is simple and the cost is low.

Abstract: A long afterglow luminescent material of the formula aMO.bM? (S?Se1-?).cAl2O3.d B2O3.eP2O5: XEu.yLn, wherein M is/are selected from Sr, Ca, Ba, and Mg, and any combinations thereof; M? is/are selected from Sr, Ca, and Ba, and any combinations thereof; Ln is/are selected from Nd, Dy, Ho, Tm, La, Ce, Er, Pr, Bi, and Sm, and any combinations thereof; a, b, c, d, e, x and y are mole ratios, wherein 0.5<a<6.0, 0.0001?b?2.0, 0.5?c?9.0, 0?d?1.0, 0?e?1.0, 0.00001?x?0.25, 0.00001?y?0.3, 0?P?1.0, 0.5<(a+b)?6.0, 0<(d+e)?1.0. The preparation process thereof is a high temperature solid-state reaction comprising an oxidation stage and a subsequent reduction stage.

Abstract: A light-storage self-luminescent glass is disclosed, comprising from 0.01 to 40% of a light-storage self-luminescent material activated by multiple ions and from 99.99 to 60% of a matrix glass; wherein the light-storage self-luminescent material has a particle size from 10 ?m to 20 mm, and the matrix glass can be a low melting point glass or a common silicate glass. A process for producing the glass is also disclosed, comprising doping a light-storage self-luminescent material during the forming process of a common silicate glass, or thoroughly mixing low melting point glass powder with a light-storage self-luminescent material, and then heat treating the system at 700-1100° C. to obtain the light-storage self-luminescent glass. The process is simple and the cost is low.