Abstract: The invention relates to a method for preparing amorphous molybdenum oxide adsorption material and an application thereof. The invention aims to solve the technical problem of low recovery efficiency of silver ions in coexisting silver-containing wastewater in the prior art. The method of the present invention includes:1) preparation of electrolyte; and 2) subjecting to cyclic voltammetry. The amorphous molybdenum oxide adsorption material prepared by the present invention is used as an adsorbent for adsorbing and reducing silver ions in wastewater. The invention successfully prepares amorphous molybdenum oxide (MoOx) by cyclic voltammetry, which has a highly selective reduction adsorption for Ag+. Silver ions and the adsorbent MoOx could be subjected to redox reaction to remove silver ions in water. The removal efficiency of the silver ions in wastewater by the amorphous molybdenum oxide prepared by cyclic voltammetry of the invention is up to 99.85%.

Abstract: The present disclosure provides a three-dimensional alkynyl-containing porous aromatic framework polymer and a preparation method and use thereof. The polymer has a structure represented by Formula I: The preparation method includes: under a protective atmosphere, mixing tetrakis(p-bromophenyl)methane, 1,3,5-triethynyl benzene, a catalyst and an amine solvent, and subjecting to a Sonogashira-Hagihara coupling reaction to obtain the three-dimensional alkynyl-containing porous aromatic framework polymer having the structure represented by Formula I.

Abstract: A method for selective adsorption of lead ions from heavy metal wastewater by electric field enhancement relating to a method for recovering lead ions from heavy metal wastewater. The method aims to solve the technical problems that it is difficult to recover heavy metals from a complex water environment in well-targeted manner and recovery purity is poor because of poor selectivity of the existing adsorbents. The adsorption selectivity to Pb2+ is enhanced under an electric field by applying a tannic acid@graphene oxide conductive aerogel material to water heavy metal electrochemical adsorption system as a conductive adsorbent. In the method, the conductive layer of the tannic acid@graphene oxide conductive aerogel material may be optimized through electrochemical reduction, so that the material has better conductivity, and has better selectivity to lead ions under an electric field.

Abstract: Disclosed is a method for preparing an acid-resistant Zr-metal-organic framework (Zr-MOF) material with selective adsorption of hexavalent chromium, which is specifically a method for preparing a MOF material with selective adsorption of hexavalent chromium. The present invention aims to solve the technical problems that the existing MOFs have poor water stability, is unstable in an aqueous solution, and therefore may structurally collapse. In addition, the micropore characteristics of most MOFs have affected the mass transfer rate of the adsorbate, which in turn limits the industrial application thereof. The MOF of the present invention has excellent water stability and acid resistance, showing a strong adaptability and great potential in treating mostly acidic industrial wastewater.

Abstract: The present invention discloses a heavy metal separating device and a parameter determining method. The device includes a plurality of pipe sections and a plurality of adsorbents; the pipe sections each include multilayer pipes; the plurality of pipe sections are connected end to end; each of the pipe sections is coated with one adsorbent; and the adsorbent is coated onto the multilayer pipes of the pipe section. According to the present invention, the adsorbents are coated onto the pipes and supporting plates, so that heavy metals are separated in the wastewater conveying process, the area occupied by wastewater treatment facilities can be greatly reduced, and heavy metal ions in the wastewater can be efficiently separated.

Abstract: The invention relates to a method for preparing amorphous molybdenum oxide adsorption material and an application thereof. The invention aims to solve the technical problem of low recovery efficiency of silver ions in coexisting silver-containing wastewater in the prior art. The method of the present invention includes: 1) preparation of electrolyte; and 2) subjecting to cyclic voltammetry. The amorphous molybdenum oxide adsorption material prepared by the present invention is used as an adsorbent for adsorbing and reducing silver ions in wastewater. The invention successfully prepares amorphous molybdenum oxide (MoOx) by cyclic voltammetry, which has a highly selective reduction adsorption for Ag+. Silver ions and the adsorbent MoOx could be subjected to redox reaction to remove silver ions in water. The removal efficiency of the silver ions in wastewater by the amorphous molybdenum oxide prepared by cyclic voltammetry of the invention is up to 99.85%.

Abstract: A process for separate removal and recovery of heavy metals from industrial wastewater is provided. The wastewater to be treated flows through adsorbents after filtration and adjustment of a pH to about 3 to 7 to obtain the adsorbents which have adsorbed corresponding heavy-metal ions, which are then eluted from the corresponding adsorbents using an acidic solution such that eluates containing the corresponding heavy-metal ions are obtained.

Abstract: A process for separate removal and recovery of heavy metals from industrial wastewater is provided. The wastewater to be treated flows through adsorbents after filtration and adjustment of a pH to about 3 to 7 to obtain the adsorbents which have adsorbed corresponding heavy-metal ions, which are then eluted from the corresponding adsorbents using an acidic solution such that eluates containing the corresponding heavy-metal ions are obtained.