Abstract: A nozzle structure including a spray pipe, including an outlet end provided with a spray head formed with a spray outlet. The spray head is provided with a spray cavity and a flow channel, the spray cavity is connected with the spray outlet, the flow channel guides water inside the spray pipe to the spray cavity, the flow channel is connected with the spray cavity through a connecting flow channel, and the connecting flow channel extends along a tangential direction of the spray cavity. A method for delivering additives to a washing machine is further provided, wherein after inlet water flow is mixed with delivered additives in a water supply path, a mixture is directly sprayed into a rotating washing drum.