Abstract: The present invention provides a method for analysis and determination of the heavy metal occurrence key mineral phases in industrial solid waste, by performing N concentration gradients dissociation determination of the heavy metal solid waste to be tested under the same dissociation conditions, to give the dissociation degrees of the heavy metal elements to be tested at N different concentration gradients; the dissociated solid residues after dissociation being quantitatively analyzed for the mineral phase, to give the relative content of each mineral phase in the M mineral phases of the heavy metal solid waste to be tested; then calculating to give the occurrence distribution proportion of the heavy metal elements in the mineral phase, which are accumulated from high to low; the occurrence key mineral phase whose cumulative occurrence proportion exceeds the preset cumulative threshold value is determined to be the key mineral phase of the heavy metal elements.

Abstract: The present invention provides a method for treating a copper-containing waste etching solution, which includes: preparing basic copper chloride nanometer seed crystals and synthesizing basic copper chloride mono-crystals; making an acidic waste etching solution subjected to agglomeration reaction with an ammonium-containing solution and slurry containing the basic copper chloride mono-crystals to obtain basic copper chloride crystal particles and copper-removed waste solution; making an alkaline waste etching solution react with sulfuric acid to obtain a copper sulfate mixed solution; and then evaporating, concentrating, cooling and crystallizing the copper sulfate mixed solution obtained by the reaction of the alkaline waste etching solution and the sulfuric acid in sequence to obtain copper sulfate pentahydrate solids.

Abstract: The present invention provides a method for treating a copper-containing waste etching solution, which includes: preparing basic copper chloride nanometer seed crystals and synthesizing basic copper chloride mono-crystals; making an acidic waste etching solution subjected to agglomeration reaction with an ammonium-containing solution and slurry containing the basic copper chloride mono-crystals to obtain basic copper chloride crystal particles and copper-removed waste solution; making an alkaline waste etching solution react with sulfuric acid to obtain a copper sulfate mixed solution; and then evaporating, concentrating, cooling and crystallizing the copper sulfate mixed solution obtained by the reaction of the alkaline waste etching solution and the sulfuric acid in sequence to obtain copper sulfate pentahydrate solids.

Abstract: The present invention provides a method for analysis and determination of the heavy metal occurrence key mineral phases in industrial solid waste, by performing N concentration gradients dissociation determination of the heavy metal solid waste to be tested under the same dissociation conditions, to give the dissociation degrees of the heavy metal elements to be tested at N different concentration gradients; the dissociated solid residues after dissociation being quantitatively analyzed for the mineral phase, to give the relative content of each mineral phase in the M mineral phases of the heavy metal solid waste to be tested; then calculating to give the occurrence distribution proportion of the heavy metal elements in the mineral phase, which are accumulated from high to low; the occurrence key mineral phase whose cumulative occurrence proportion exceeds the preset cumulative threshold value is determined to be the key mineral phase of the heavy metal elements.

Abstract: The present invention discloses a method for detoxifying chromium slag by using high sulfur coal. The method includes: sieving chromium slag into coarse-grained chromium slag and fine-grained chromium slag, air-drying and crushing both the coarse-grained chromium slag and the fine-grained chromium slag; separately mixing the crushed coarse-grained chromium slag and fine-grained chromium slag with the crushed high sulfur coal uniformly; adjusting pH values of a coarse-grained slag mixture and a fine-grained slag mixture to 8.0-11.0 and moisture content thereof to 12%-18%; conducting reduction on the treated coarse-grained slag mixture and fine-grained slag mixture, where the reduction temperature of the fine-grained slag mixture is 500-700° C., the reduction time of the fine-grained slag mixture is 10-30 min, the reduction temperature of the coarse-grained slag mixture is 800-1000° C.

Abstract: The present disclosure belongs to the field of chemical synthesis, and in particular relates to an ammonium carboxylate compound, a crystalline form and an amorphous form, and a preparation method thereof. The present disclosure prepares the compound and the crystalline form I and its single crystal, amorphous form and crystalline form II thereof. The compound, the crystalline forms, the single crystal and the amorphous form can stably exist and exhibit good solid forms, suitable for medicine-making. Furthermore, these products possess high purity and less single impurity. Moreover, the preparation methods of the present disclosure are easy to implement due to the simple processes with mild reaction conditions, and could produce products of high yield and high purity without complex purification steps. Furthermore, the preparation methods may facilitate safety, environmental protection, and industrial production.

Abstract: The present invention discloses a method for detoxifying chromium slag by using high sulfur coal. The method includes: sieving chromium slag into coarse-grained chromium slag and fine-grained chromium slag, air-drying and crushing both the coarse-grained chromium slag and the fine-grained chromium slag; separately mixing the crushed coarse-grained chromium slag and fine-grained chromium slag with the crushed high sulfur coal uniformly; adjusting pH values of a coarse-grained slag mixture and a fine-grained slag mixture to 8.0-11.0 and moisture content thereof to 12%-18%; conducting reduction on the treated coarse-grained slag mixture and fine-grained slag mixture, where the reduction temperature of the fine-grained slag mixture is 500-700° C., the reduction time of the fine-grained slag mixture is 10-30 min, the reduction temperature of the coarse-grained slag mixture is 800-1000° C.

Abstract: A method for extracting and recycling chromium from hexavalent chromium-containing residues includes the following steps: 1) adding water to the hexavalent chromium-containing residues and mixing uniformly; 2) adding sodium sulfate, sodium chlorate and sulfuric acid to a solution obtained in step 1) and stirring sufficiently to obtain a mixed liquid; 3) treating the mixed liquid by a hydrothermal method or direct heating; 4) after the heating treatment, naturally cooling a solid-liquid mixture to room temperature for holding; 5) separating solid residues and a chromium-containing supernatant, and washing filtered residues with water and then drying; 6) precipitating the supernatant and the water used for washing the filtered residues with a precipitant CaCl2, then centrifugally washing, dewatering and drying the precipitates; and 7) recycling a chromium-containing solution for returning to a work section, or for a treatment of recycling chromium.

Abstract: A treatment method for resource recycling of hexavalent chromium-containing residues is provided. This method comprises steps as follows: 1) adding water to the hexavalent chromium-containing residues and mixing uniformly; 2) adding mineralizers to a solution obtained in step 1) and stirring sufficiently to obtain a mixed liquid; and the mineralizers are sodium chlorate, sodium perchlorate and hydrochloric acid; 3) treating the mixed liquid by a hydrothermal method or direct heating; 4) after the heating treatment, naturally cooling a solid-liquid mixture to room temperature for holding; 5) separating solid residues and a chromium-containing supernatant, and washing filtered residues with water and then drying; and 6) recycling a chromium-containing solution for returning to a work section, or for a treatment of recycling chromium.

Abstract: The present disclosure belongs to the field of chemical synthesis, and in particular relates to an ammonium carboxylate compound, a crystalline form and an amorphous form, and a preparation method thereof. The present disclosure prepares the compound and the crystalline form I and its single crystal, amorphous form and crystalline form II thereof. The compound, the crystalline forms, the single crystal and the amorphous form can stably exist and exhibit good solid forms, suitable for medicine-making. Furthermore, these products possess high purity and less single impurity. Moreover, the preparation methods of the present disclosure are easy to implement due to the simple processes with mild reaction conditions, and could produce products of high yield and high purity without complex purification steps. Furthermore, the preparation methods may facilitate safety, environmental protection, and industrial production.

Abstract: The present invention discloses a treatment method for resource recycling of hexavalent chromium-containing residues, belonging to a field of a clean treatment and resource recycling of chromium-containing residues. This method comprises steps as follows: 1) adding water to the hexavalent chromium-containing residues and mixing uniformly; 2) adding mineralizers to a solution obtained in step 1) and stirring sufficiently to obtain a mixed liquid; and the mineralizers are sodium chlorate, sodium perchlorate and hydrochloric acid; 3) treating the mixed liquid by a hydrothermal method or direct heating; 4) after the heating treatment, naturally cooling a solid-liquid mixture to room temperature for holding; 5) separating solid residues and a chromium-containing supernatant, and washing filtered residues with water and then drying; and 6) recycling a chromium-containing solution for returning to a work section, or for a treatment of recycling chromium.

Abstract: The present invention discloses a detoxification treatment method for extracting and recycling chromium from hexavalent chromium-containing residues, comprising steps as follows: 1) adding water to the hexavalent chromium-containing residues and mixing uniformly; 2) adding sodium sulfate, sodium chlorate and sulfuric acid to a solution obtained in step 1) and stirring, sufficiently to obtain a mixed liquid; 3) treating the mixed liquid by a hydrothermal method or direct heating; 4) after the heating treatment, naturally cooling a solid-liquid mixture to room temperature for holding; 5) separating solid residues and a chromium-containing supernatant, and washing filtered residues with water and then drying; 6) precipitating the supernatant and the water used for washing the filtered residues with a precipitant CaCl2, then centrifugally washing, dewatering and drying the precipitates; and 7) recycling a chromium-containing solution for returning to a work section, or for a treatment of recycling chromium.

Abstract: A method for identifying gambiered Guangdong silk includes the steps of: detecting the surface state of fiber by microscope; detecting the pyrolysis fragments of fabrics by pyrolysis gas chromatography; determining the crude protein content in the fiber by Kjeldahl determination; and detecting the dye component of the fabrics by high performance liquid chromatography. The method of the present invention can accurately identify the true and fake, good and bad of the gambiered Guangdong silk, and then make an accurate evaluation on the gambiered Guangdong silk; and the present invention is simple, useful, environmental and has low cost.

Abstract: A method for identifying gambiered Guangdong silk includes the steps of: detecting the surface state of fiber by microscope; detecting the pyrolysis fragments of fabrics by pyrolysis gas chromatography; determining the crude protein content in the fiber by Kjeldahl determination; and detecting the dye component of the fabrics by high performance liquid chromatography. The method of the present invention can accurately identify the true and fake, good and bad of the gambiered Guangdong silk, and then make an accurate evaluation on the gambiered Guangdong silk; and the present invention is simple, useful, environmental and has low cost.