Abstract: The present application relates to the field of lithium-ion batteries and discloses a lithium-ion battery cathode material, a preparation method thereof, and a lithium-ion battery. A ratio of surface Ni3+ content of the cathode material to internal Ni3+ content of the cathode material is (0.95 to 1):1, and a content of disordering nickel in the cathode material is less than or equal to 3%. The lithium-ion battery cathode material has the similar surface Ni3+ content and internal Ni3+ content, and has a low content of disordering nickel, thereby avoiding the generation of a NiO passivation layer in the cathode material and reducing the phenomenon of loss of surface active lithium. The lithium-ion battery containing such a cathode material has improved capacity, rate capacity, and cycle performance.

Abstract: The present disclosure relates to the technical field of lithium-ion batteries, and discloses a lithium-rich manganese oxide cathode material, a preparation method and use thereof, and a positive electrode plate and use thereof. The cathode material has a chemical composition of xLi[Li1/3(Mn1-aMa)2/3]O2·(1?x)LiMn1-bM?bO2. An XRD spectrum of the cathode material has a diffraction peak P(1) in a range of a diffraction angle 2?1 satisfying [43.5(1?x)+44x]°?2?1?[44(1?x)+45x]°; and the XRD spectrum of the cathode material has a diffraction peak P(2) in a range of a diffraction angle 2?2 satisfying [17.7(1?x)+18.3x]°?2?2?[19.2(1?x)+19.8x]°, where 0.35?x?0.63. The cathode material has high first-cycle efficiency, high discharge capacity, high energy efficiency, high rate performance, and high cycle performance.

Abstract: Disclosed are an iron-based catalyst and its application catalytic diene polymerization. The iron-based catalyst provided by the present application includes iron-containing organic compounds, alkyl aluminum compounds and isocyanide-containing organic compounds, and the molar ratio between the iron element of the iron-containing organic compounds, the alkyl aluminum compounds and the isocyanide-containing organic compounds is 1:(5˜100):(0.5˜100). The iron-based catalyst system of the present application can initiate polymerization of diene with high activity at high temperature by using isocyanide-containing organic compounds as an electron donor and alkyl aluminum compounds as a co-catalyst.

Abstract: Disclosed is a method of adjusting the molecular weight of syndiotactic 1,2-polybutadiene prepared using an iron-based catalyst. In the present application, when an iron-based catalyst catalyzes the polymerization of butadiene to prepare syndiotactic 1,2-polybutadiene, alpha-olefins are added as a molecular weight regulator, and a chain transfer effect is achieved through competitive adsorption. At the same time, since alpha-olefins are stable to iron-based catalysts, cannot be initiated to polymerize, and are easy to separate from butadiene, they have a significant effect on molecular weight regulation and do not have a significant effect on activity, making it possible to prepare syndiotactic 1,2-polybutadiene thermoplastic elastomers with number average molecular weights ranging from 3,000-250,000. The syndiotactic 1,2-polybutadiene rubber prepared by the present application has better processability.

Abstract: The present disclosure relates to the technical field of secondary battery, and discloses a positive electrode material and a preparation method and use therefor, a lithium-ion battery positive electrode poly piece, and a lithium-ion battery.

Abstract: The present disclosure relates to the technical field of positive electrode materials of lithium ion batteries. Disclosed a positive electrode material having a multi-cavity structure and a preparation method therefor, and a lithium ion battery. The positive electrode material is formed by aggregation of a plurality of primary particles, and some of the primary particles grow in an oriented manner to form supporting structures, the supporting structures overlapping each other inside the positive electrode material to form a plurality of cavities. The particle strength of the positive electrode material is significantly improved, so that the positive electrode material has the advantage of a long service life. In addition, the impedance of the positive electrode material is reduced, thereby improving the power performance of the positive electrode material.

Abstract: A positive electrode material, a preparation method therefor, and an application thereof are disclosed. The cathode material is composed of secondary particles agglomerated by primary particles; wherein individual secondary particle contains an inner core structure, a middle layer, and a shell layer, in this order, along a direction from a center to a surface of the secondary particle; wherein the middle layer is distributed in a circular ring shape; and wherein the secondary particle has a structure of close packing of an inner core structure, loose and porous middle layer, and close packing of the shell layer.

Abstract: The present disclosure relates to a positive electrode material and the preparation method therefor. The positive electrode material in accordance with the present disclosure is in a form of secondary particles having a core and a shell, wherein the core has a porosity greater than that of the shell. By forming larger particle voids in the cores of secondary particles, the present invention may reduce the stress concentration due to the volume deformation during the lithium ion intercalation/deintercalation, and improve the stability, rate performance, safety and cycle life of the material, which makes the material particularly suitable for lithium-ion batteries of high energy density.

Abstract: The present disclosure relates to a positive electrode material for a lithium ion battery and its preparation. The positive electrode material in accordance with the present disclosure has an intrinsic specific surface area of 5-13 m2/g. The positive electrode material in accordance with the present disclosure has an intrinsic specific surface area and an intrinsic pore size within the required ranges. In this regard, the positive electrode material in accordance with the present disclosure has excellent particle strength, excellent Li ion transference ability, and good resistance to electrolyte erosion. When used in lithium batteries, it may impart the batteries with excellent rate performance and cycle performance. The present disclosure also relates to a method for preparing the positive electrode material.

Abstract: The present disclosure relates to the technical field of preparation of syndiotactic 1,2-polybutadiene (s-PB), in particular to a catalytic system and use thereof, and a preparation method of s-PB. In the present disclosure, the catalytic system includes an iron-containing organic compound, an azodicyano compound, an organoaluminum compound, and a free radical scavenger; where an iron element in the iron-containing organic compound, the azodicyano compound, the organoaluminum compound, and the free radical scavenger have a molar ratio of 1:(0.5-10):(5-100):(1-1000); and the free radical scavenger is selected from the group consisting of a sterically hindered phenol, a sterically hindered amine, and a phosphorus-containing antioxidant. The catalytic system can prepare the s-PB with a high activity at a high temperature, and the s-PB has a melting point of 60° C. to 130° C. with an extremely low gel content or even no gelation.

Abstract: Provided is a positive electrode material for a lithium ion battery, having the following general formula I: Li1+aNixCoyMnzMcM?dO2?bAb general formula I, wherein ?0.05?a?0.3, 0.8?x?1, 0?y?0.2, 0?z?0.2, 0?c?0.01, 0?d?0.01, x+y+z+c+d=1, and 0?b?0.05; M and M? are different from each other and each independently selected from at least one of La, Cr, Mo, Ca, Fe, Ti, Zn, Y, Zr, W, Nb, V, Mg, B, Al, Sr, Ba and Ta, A is selected from at least one of F, Cl, Br, I and S, and the number of crystallite boundaries N in primary particles of the positive electrode material is from 10.5 to 14.5, wherein N is calculated according to Equation I: N=DS/DX Equation I, wherein DS is an average size of the primary particles, as measured from scanning electron microscope (SEM) image of cross section of the positive electrode material, and DX is an average size of crystallites in the primary particles of the positive electrode material, as measured by an XRD test and calculated by the Scherrer equation.

Abstract: A positive electrode material, a preparation method therefor, and an application thereof are disclosed. The cathode material is composed of secondary particles agglomerated by primary particles; wherein individual secondary particle contains an inner core structure, a middle layer, and a shell layer, in this order, along a direction from a center to a surface of the secondary particle; wherein the middle layer is distributed in a circular ring shape; and wherein the secondary particle has a structure of close packing of an inner core structure, loose and porous middle layer, and close packing of the shell layer.

Abstract: Provided is a positive electrode material for a lithium ion battery, having the following general formula I: Li1+aNixCoyMnzMcM?dO2?bAb general formula I, wherein ?0.05?a?0.3, 0.8?x?1, 0?y?0.2, 0?z?0.2, 0?c?0.01, 0?d?0.01, x+y+z+c+d=1, and 0?b?0.05; M and M? are different from each other and each independently selected from at least one of La, Cr, Mo, Ca, Fe, Ti, Zn, Y. Zr, W, Nb, V, Mg, B, Al, Sr, Ba and Ta, A is selected from at least one of F, Cl, Br, I and S, and the number of crystallite boundaries N in primary particles of the positive electrode material is from 10.5 to 14.5, wherein N is calculated according to Equation I: N=DS/DX Equation I, wherein DS is an average size of the primary particles, as measured from scanning electron microscope (SEM) image of cross section of the positive electrode material, and DX is an average size of crystallites in the primary particles of the positive electrode material, as measured by an XRD test and calculated by the Scherrer equation.

Abstract: A positive electrode material for a lithium ion battery and a preparation method therefor, and a lithium ion battery, relating to the technical field of secondary batteries. The positive electrode material comprises a high-nickel multi-element positive electrode material, the high-nickel multi-element positive electrode material is formed by agglomerating multiple primary grains, and the primary grains are distributed in a divergent shape along the diameter direction of the high-nickel multi-element positive electrode material, the aspect ratio L/R of the primary grains in the positive electrode material is greater than or equal to 3, and the radial distribution ratio of the primary grains in the positive electrode material is greater than or equal to 60%. The lithium ion battery containing the positive electrode material has high capacity and greatly improved particle strength.

Abstract: The present disclosure relates to the technical field of positive electrode materials of lithium ion batteries. Disclosed a positive electrode material having a multi-cavity structure and a preparation method therefor, and a lithium ion battery. The positive electrode material is formed by aggregation of a plurality of primary particles, and some of the primary particles grow in an oriented manner to form supporting structures, the supporting structures overlapping each other inside the positive electrode material to form a plurality of cavities. The particle strength of the positive electrode material is significantly improved, so that the positive electrode material has the advantage of a long service life. In addition, the impedance of the positive electrode material is reduced, thereby improving the power performance of the positive electrode material.

Abstract: The present disclosure provides a preparation method of a homogeneous rare earth catalyst. In the present disclosure, a depolymerizing agent is introduced into the homogeneous rare earth catalyst to promote complete depolymerization of an alkyl aluminum trimer into monomolecular alkyl aluminum. As a result, there is an increase in the number of the alkyl aluminum which serves as an effective chain transfer agent, resulting in a greatly improved chain transfer rate, such that a polymerization system has completed the chain transfer in an early stage of the reaction. Accordingly, an aluminum terminal molecular chain has an increased concentration, leading to an accelerated exchange with an active center propagating chain and a decreased influence caused by an increased viscosity of the system, maintaining living polymerization of the system.

Abstract: The present disclosure relates to the technical field of secondary battery, and discloses a positive electrode material and a preparation method and use therefor, a lithium-ion battery positive electrode poly piece, and a lithium-ion battery.

Abstract: The present disclosure relates to the technical field of secondary battery, and discloses a positive electrode material and a preparation method and use therefor, a lithium-ion battery positive electrode poly piece, and a lithium-ion battery.

Abstract: The present disclosure relates to the technical field of preparation of syndiotactic 1,2-polybutadiene (s-PB), in particular to a catalytic system and use thereof, and a preparation method of s-PB. In the present disclosure, the catalytic system includes an iron-containing organic compound, an azodicyano compound, an organoaluminum compound, and a free radical scavenger; where an iron element in the iron-containing organic compound, the azodicyano compound, the organoaluminum compound, and the free radical scavenger have a molar ratio of 1:(0.5-10):(5-100):(1-1000); and the free radical scavenger is selected from the group consisting of a sterically hindered phenol, a sterically hindered amine, and a phosphorus-containing antioxidant. The catalytic system can prepare the s-PB with a high activity at a high temperature, and the s-PB has a melting point of 60° C. to 130° C. with an extremely low gel content or even no gelation.

Abstract: A positive electrode material for a lithium ion battery and a preparation method therefor, and a lithium ion battery, relating to the technical field of secondary batteries. The positive electrode material comprises a high-nickel multi-element positive electrode material, the high-nickel multi-element positive electrode material is formed by agglomerating multiple primary grains, and the primary grains are distributed in a divergent shape along the diameter direction of the high-nickel multi-element positive electrode material, the aspect ratio L/R of the primary grains in the positive electrode material is greater than or equal to 3, and the radial distribution ratio of the primary grains in the positive electrode material is greater than or equal to 60%. The lithium ion battery containing the positive electrode material has high capacity and greatly improved particle strength.