Abstract: A positive electrode material, a preparation method therefor, and an application thereof are disclosed. The cathode material is composed of secondary particles agglomerated by primary particles; wherein individual secondary particle contains an inner core structure, a middle layer, and a shell layer, in this order, along a direction from a center to a surface of the secondary particle; wherein the middle layer is distributed in a circular ring shape; and wherein the secondary particle has a structure of close packing of an inner core structure, loose and porous middle layer, and close packing of the shell layer.

Abstract: Provided is a positive electrode material for a lithium ion battery, having the following general formula I: Li1+aNixCoyMnzMcM?dO2?bAb general formula I, wherein ?0.05?a?0.3, 0.8?x?1, 0?y?0.2, 0?z?0.2, 0?c?0.01, 0?d?0.01, x+y+z+c+d=1, and 0?b?0.05; M and M? are different from each other and each independently selected from at least one of La, Cr, Mo, Ca, Fe, Ti, Zn, Y. Zr, W, Nb, V, Mg, B, Al, Sr, Ba and Ta, A is selected from at least one of F, Cl, Br, I and S, and the number of crystallite boundaries N in primary particles of the positive electrode material is from 10.5 to 14.5, wherein N is calculated according to Equation I: N=DS/DX Equation I, wherein DS is an average size of the primary particles, as measured from scanning electron microscope (SEM) image of cross section of the positive electrode material, and DX is an average size of crystallites in the primary particles of the positive electrode material, as measured by an XRD test and calculated by the Scherrer equation.

Abstract: A positive electrode material for a lithium ion battery and a preparation method therefor, and a lithium ion battery, relating to the technical field of secondary batteries. The positive electrode material comprises a high-nickel multi-element positive electrode material, the high-nickel multi-element positive electrode material is formed by agglomerating multiple primary grains, and the primary grains are distributed in a divergent shape along the diameter direction of the high-nickel multi-element positive electrode material, the aspect ratio L/R of the primary grains in the positive electrode material is greater than or equal to 3, and the radial distribution ratio of the primary grains in the positive electrode material is greater than or equal to 60%. The lithium ion battery containing the positive electrode material has high capacity and greatly improved particle strength.

Abstract: The present disclosure relates to the technical field of positive electrode materials of lithium ion batteries. Disclosed a positive electrode material having a multi-cavity structure and a preparation method therefor, and a lithium ion battery. The positive electrode material is formed by aggregation of a plurality of primary particles, and some of the primary particles grow in an oriented manner to form supporting structures, the supporting structures overlapping each other inside the positive electrode material to form a plurality of cavities. The particle strength of the positive electrode material is significantly improved, so that the positive electrode material has the advantage of a long service life. In addition, the impedance of the positive electrode material is reduced, thereby improving the power performance of the positive electrode material.

Abstract: The present disclosure provides a preparation method of a homogeneous rare earth catalyst. In the present disclosure, a depolymerizing agent is introduced into the homogeneous rare earth catalyst to promote complete depolymerization of an alkyl aluminum trimer into monomolecular alkyl aluminum. As a result, there is an increase in the number of the alkyl aluminum which serves as an effective chain transfer agent, resulting in a greatly improved chain transfer rate, such that a polymerization system has completed the chain transfer in an early stage of the reaction. Accordingly, an aluminum terminal molecular chain has an increased concentration, leading to an accelerated exchange with an active center propagating chain and a decreased influence caused by an increased viscosity of the system, maintaining living polymerization of the system.

Abstract: The present disclosure relates to the technical field of secondary battery, and discloses a positive electrode material and a preparation method and use therefor, a lithium-ion battery positive electrode poly piece, and a lithium-ion battery.

Abstract: The present disclosure relates to the technical field of secondary battery, and discloses a positive electrode material and a preparation method and use therefor, a lithium-ion battery positive electrode poly piece, and a lithium-ion battery.

Abstract: The present disclosure relates to the technical field of preparation of syndiotactic 1,2-polybutadiene (s-PB), in particular to a catalytic system and use thereof, and a preparation method of s-PB. In the present disclosure, the catalytic system includes an iron-containing organic compound, an azodicyano compound, an organoaluminum compound, and a free radical scavenger; where an iron element in the iron-containing organic compound, the azodicyano compound, the organoaluminum compound, and the free radical scavenger have a molar ratio of 1:(0.5-10):(5-100):(1-1000); and the free radical scavenger is selected from the group consisting of a sterically hindered phenol, a sterically hindered amine, and a phosphorus-containing antioxidant. The catalytic system can prepare the s-PB with a high activity at a high temperature, and the s-PB has a melting point of 60° C. to 130° C. with an extremely low gel content or even no gelation.

Abstract: A positive electrode material for a lithium ion battery and a preparation method therefor, and a lithium ion battery, relating to the technical field of secondary batteries. The positive electrode material comprises a high-nickel multi-element positive electrode material, the high-nickel multi-element positive electrode material is formed by agglomerating multiple primary grains, and the primary grains are distributed in a divergent shape along the diameter direction of the high-nickel multi-element positive electrode material, the aspect ratio L/R of the primary grains in the positive electrode material is greater than or equal to 3, and the radial distribution ratio of the primary grains in the positive electrode material is greater than or equal to 60%. The lithium ion battery containing the positive electrode material has high capacity and greatly improved particle strength.

Abstract: The present invention relates to the field of polymer materials. Disclosed are a random-syndiotactic block polybutadiene and preparation method thereof, the provided random-syndiotactic block polybutadiene having a structure of formula (I), and comprising a random polybutadiene structure and a syndiotactic 1, 2-polybutadiene structure, being useful as a compatibilizing agent to improve the compatibility of the syndiotactic 1, 2-polybutadiene/polybutadiene rubber blend.

Abstract: The invention provides a method for producing soluble neodymium chloride complex using neodymium chloride aqueous solution as raw material, thereby avoiding the use of anhydrous neodymium chloride, simplifying the synthesis process and reducing the cost for synthesizing neodymium chloride complex. The neodymium chloride complex produced by this method is soluble not only in polar solvent, but also in nonpolar solvent. Such neodymium chloride complex also has good dissolvability in aliphatic hydrocarbon solvent which has relatively weaker solution power, and even in aliphatic hydrocarbon solvent with 6 or less carbon atoms which has even lower solution power. Since neodymium chloride complex is soluble in aliphatic hydrocarbon solvent, its transportation may be conducted, which is convenient for industrial application and contributes to improve the utilization efficiency of rare earth.

Abstract: The invention provides a method for producing soluble neodymium chloride complex using neodymium chloride aqueous solution as raw material, thereby avoiding the use of anhydrous neodymium chloride, simplifying the synthesis process and reducing the cost for synthesizing neodymium chloride complex. The neodymium chloride complex produced by this method is soluble not only in polar solvent, but also in nonpolar solvent. Such neodymium chloride complex also has good dissolvability in aliphatic hydrocarbon solvent which has relatively weaker solution power, and even in aliphatic hydrocarbon solvent with 6 or less carbon atoms which has even lower solution power. Since neodymium chloride complex is soluble in aliphatic hydrocarbon solvent, its transportation may be conducted, which is convenient for industrial application and contributes to improve the utilization efficiency of rare earth.

Abstract: The present invention relates to a catalyst for synthesizing a polypropylene with a wide molecular weight distribution and use of the same. The catalyst comprises magnesium halide, titanium-containing compound, and an organic phosphate type electron donor compound. By the catalyst according to the present invention, a propylene polymer with a wide molecular weight distribution, easily controllable isotacticity and good processing properties can be synthesized.

Abstract: The present invention relates to a catalyst for synthesizing a polypropylene with a wide molecular weight distribution and use of the same. The catalyst comprises magnesium halide, titanium-containing compound, and an organic phosphate type electron donor compound. By the catalyst according to the present invention, a propylene polymer with a wide molecular weight distribution, easily controllable isotacticity and good processing properties can be synthesized.

Abstract: Disclosed herein are a method for preparing a cis-1,4-polybutadiene with a controlled molecular weight distribution, comprising polymerizing butadiene monomers using a rare-earth catalyst system comprising: (a) at least one aliphatic hydrocarbon-soluble organometallic compound comprising at least one metal element chosen from the elements of atomic numbers 51-71 in the periodic table; (b) at least one organoaluminum compound of the formula: AlR1R22, (c) at least one aliphatic hydrocarbon-soluble halogen-containing compound; (d) optionally at least one alkylaluminum alkoxide; and (e) at least one conjugated double bond-containing organic compound, and methods of preparing the rare-earth catalyst system.

Abstract: This invention relates to A process for manufacturing a vinyl-rich polybutadiene rubber, comprising polymerizing butadiene in a solvent using a catalyst system comprising an iron-based catalyst as catalyst and a phosphite as ligand, said catalyst system comprising: (A) an organoiron compound; (B) an organoaluminum compound; and (C) a phosphite selected from a group consisting of dialkyl phosphite, trialkyl phosphite, diaryl phosphite, triaryl phosphite and mixtures thereof; wherein, the mole ratio of component B to component A is 5:100; and that of component C to component A is 0.5:10; and 80 wt % of macromolecules of the rubber have a vinyl group.

Abstract: The present invention provides a supported catalyst comprising (A) a polymer (B) a supporter, (C) a transition metal compound, and optionally (D) (a) a compound which can form an ionic complex by the reaction with the transition metal compound or (b) a specific oxygen-containing compound, and (E) an alkylaluminum compound. The supported catalyst according to present invention, which has a high activity, can be used for preparing a styrenic polymer with a high syndiotacticity. The supported catalyst can be used in combination with a cocatalyst, preferably an alkyl aluminoxane.

Abstract: Disclosed herein are a method for preparing a cis-1,4-polybutadiene with a controlled molecular weight distribution, comprising polymerizing butadine monomers using a rare-earth catalyst system comprising (a). at least one aliphatic hydrocarbon-soluble organometallic compound comprising at least one metal element chosen from the elements of atomic numbers 51-71 in the periodic table; (b). at least one organoaluminum compound of the formula: AlR1R22, (c). at least one aliphatic hydrocarbon-soluble halogen-containing compound; (d). optionally at least one alkylaluminum alkoxide; and (e). at least one conjugated double bond-containing organic compound, and methods of preparing the rare-earth catalyst system.

Abstract: The syndiotactic polystyrene nanocomposite according to the present invention has nano silicate materials dispersed individually in a styrene polymer matrix by intercalation and exfoliation during polymerization. Besides, the syndiotactic polystyrene nanocomposite according to the present invention is prepared by using a catalytic system composed of a phyllosilicate-supported Group IVB transition metal catalyst and alkylaluminoxane, wherein the phyllosilicate-supported Group IVB transition metal catalyst comprises: a) a polymer, b) a phyllosilicate and c) a Group IVB transition metal compound, and the polymer (a) is used as an insulating material or media of the phyllosilicate (b) and the Group IVB transition metal compound (c).

Abstract: The syndiotactic polystirene resin composition according to the present invention is superior in compatibility between a syndiotactic polystyrene and a rubber component and mechanical properties such as impact strength, in which a syndiotactic polystyrene-maleic anhydride (sPS-MA) and a hydrogenated styrene/butadiene/styrene-maleic anhydride (SEBS-MA) are employed as compatibilizers and a diamine compound is added as a coupling agent. The compatibilizers and coupling agents improve polarity of both the syndiotactic polystyrene and the rubber component and impact strength of the syndiotactic polystyrene composition.