Abstract: Described herein is a method and composition comprising same for sealing the pores of a porous low dielectric constant (“low k”) layer by providing an additional thin dielectric film, referred to herein as a pore sealing layer, on at least a surface of the porous, low k layer to prevent further loss of dielectric constant of the underlying layer. In one aspect, the method comprises: contacting a porous low dielectric constant film with at least one organosilicon compound to provide an absorbed organosilicon compound and treating the absorbed organosilicon compound with ultraviolet light, plasma, or both, and repeating until a desired thickness of the pore sealing layer is formed.

Abstract: Described herein is a method and composition comprising same for sealing the pores of a porous low dielectric constant (“low k”) layer by providing an additional thin dielectric film, referred to herein as a pore sealing layer, on at least a surface of the porous, low k layer to prevent further loss of dielectric constant of the underlying layer. In one aspect, the method comprises: contacting a porous low dielectric constant film with at least one organosilicon compound to provide an absorbed organosilicon compound and treating the absorbed organosilicon compound with ultraviolet light, plasma, or both, and repeating until a desired thickness of the pore sealing layer is formed.

Abstract: A dispersion, and a film and optoelectronic devices formed from the dispersion are provided. The dispersion comprising conducting polymer containing particles having a particle size of less than 450 nm, wherein the conducting polymer comprises substituted or unsubstituted, uncharged or charged polymerized units of thieno[3,4-b]thiophene, and wherein a film drop cast from the dispersion has a conductivity from 10?1 to 10?6 S/cm measured using the four point probe method.

Abstract: A resistivity stable aqueous dispersion and a method for making an aqueous dispersion. The dispersion including polythienothiophene and at least one colloid-forming polymeric acid having a pH of from about 3 to about 10. The method includes preparing an aqueous dispersion containing polythienothiophene and adjusting the pH of the dispersion to a sufficiently high pH to provide resistivity stability. Devices utilizing layers formed of pH adjusted polythienothiophene are also disclosed.

Abstract: A resistivity stable aqueous dispersion and a method for making an aqueous dispersion. The dispersion including polythienothiophene and at least one colloid-forming polymeric acid having a pH of from about 3 to about 10. The method includes preparing an aqueous dispersion containing polythienothiophene and adjusting the pH of the dispersion to a sufficiently high pH to provide resistivity stability. Devices utilizing layers formed of pH adjusted polythienothiophene are also disclosed.

Abstract: The light-emitting device comprising an anode, a cathode, a semi-conducting layer between the anode and the cathode and a hole injection layer comprising a conducting polymer between the anode and the semi-conducting layer; where an interfacial bonding layer is formed in-situ between the hole injection layer and the semi-conducting is disclosed.

Abstract: An aqueous blend comprising water, a first conjugated polymer having a conductivity of greater than 10?7 S/cm and a second conjugated polymer having a conductivity greater than 10?7 S/cm wherein the conductivities of the first conjugated polymer and the second conjugated polymer are measured using a four point probe method prior to preparing the aqueous blend. A film is also presented comprising a first conjugated polymer having a conductivity of greater than 10?7 S/cm and a second conjugated polymer having a conductivity greater than 10?7 S/cm formed by (a) depositing the recited aqueous blend onto an article and (b) removing the water-containing solution to form the film on the article.

Abstract: Compositions are provided comprising aqueous dispersions of polythienothiophenes and colloid-forming polymeric acids. Films from invention compositions are useful as hole injection layers in organic electronic devices, including electroluminescent devices, such as, for example, organic light emitting diodes (OLED) displays, as hole extraction layers in organic optoelectronic devices, such as organic photovoltaic devices, and in combination with metal nanowires or carbon nanotubes in applications such as drain, source, or gate electrodes in thin film field effect transistor.

Abstract: Osmium complexes having the formula [Os(II) (N—N)2L—L]2+ 2A? (or A2?), or [Os(II) N—N(L—L)2]2+ 2A? (or A2?), where N—N is a bipyridine or phenanthroline ligand, L—L is a ?-acid bidentate ligand, and A is counter ion.

Abstract: A dispersion, and a film and optoelectronic devices formed from the dispersion are provided. The dispersion comprising conducting polymer containing particles having a particle size of less than 450 nm, wherein the conducting polymer comprises substituted or unsubstituted, uncharged or charged polymerized units of thieno[3,4-b]thiophene, and wherein a film drop cast from the dispersion has a conductivity from 10?1 to 10?6 S/cm measured using the four point probe method.

Abstract: A photovoltaic device having an anode, a cathode, and at least one photoactive layer between the anode and the cathode, wherein the at least one photoactive layer includes a composition containing a polymer having a glass transition temperature of at least 125° C.; and a photoactive material, wherein: (a) the photoactive material is a hole transporting organic material, an electron transporting organic material, and/or a light harvesting organic material, (b) the polymer and the photoactive material are in a single phase (c) the photoactive material constitutes at least 20% by weight of the composition, and (d) the at least one photoactive layer is in electrical communication with the anode and the cathode, the anode and the cathode are configured to conduct an electric charge from the at least one photoactive layer produced by the at least one photoactive layer absorbing light.

Abstract: A dispersion, and a film and optoelectronic devices formed from the dispersion are provided. The dispersion comprising conducting polymer containing particles having a particle size of less than 450 nm, wherein the conducting polymer comprises substituted or unsubstituted, uncharged or charged polymerized units of thieno[3,4-b]thiophene, and wherein a film drop cast from the dispersion has a conductivity from 10?1 to 10?6 S/cm measured using the four point probe method.

Abstract: The electrical conductivity of thin films of transparent conducting polymers such as poly(3,4-ethylenedioxythiophene)/polystyrene sulfonic acid (PEDOT/PSS) can be increased greatly by exposure to certain polar organic solvents, aqueous/organic solutions, and aqueous/organic or organic solutions containing additives such as oxidative dopants, monomers, organic compounds, or combinations thereof. The transparency of the film in the visible region of the spectrum is maintained after treatment to enhance conductivity. The conductivity of films of transparent conducting polymers based on poly(thienothiophenes) such as poly(thieno[3,4-b]thiophene)/PSS (PTT/PSS) and poly(thieno[3,4-b]thiophene)/fluoropolymeric acid is altered to much less of a degree by analogous solvent treatment, or by direct solvent addition into PTT dispersions.

Abstract: A light emitting device includes: (a) a light emitting layer including an electroluminescent organic material dispersed in a matrix, wherein the matrix contains a non-electroluminescent organic polymer having a Tg of at least 170° C., and each of the organic polymer and the electroluminescent organic material constitutes at least 20 percent by weight of the light emitting layer; and (b) electrodes in electrical communication with the light emitting layer and configured to conduct an electric charge through the light emitting layer such that the light emitting layer emits light. A method for manufacturing a flexible organic light emitting device, includes providing the light emitting layer and providing electrodes above and below the light emitting layer, wherein the electrodes are in electrical communication with the light emitting layer.

Abstract: An aqueous blend comprising water, a first conjugated polymer having a conductivity of greater than 10?7 S/cm and a second conjugated polymer having a conductivity greater than 10?7 S/cm wherein the conductivities of the first conjugated polymer and the second conjugated polymer are measured using a four point probe method prior to preparing the aqueous blend. A film is also presented comprising a first conjugated polymer having a conductivity of greater than 10?7 S/cm and a second conjugated polymer having a conductivity greater than 10?7 S/cm formed by (a) depositing the recited aqueous blend onto an article and (b) removing the water-containing solution to form the film on the article.

Abstract: Compositions are provided comprising aqueous dispersions of polythienothiophenes and colloid-forming polymeric acids. Films from invention compositions are useful as hole injection layers in organic electronic devices, including electroluminescent devices, such as, for example, organic light emitting diodes (OLED) displays, as hole extraction layers in organic optoelectronic devices, such as organic photovoltaic devices, and in combination with metal nanowires or carbon nanotubes in applications such as drain, source, or gate electrodes in thin film field effect transistors.

Abstract: An aqueous blend comprising water, a first conjugated polymer having a conductivity of greater than 10?7 S/cm and a second conjugated polymer having a conductivity greater than 10?7 S/cm wherein the conductivities of the first conjugated polymer and the second conjugated polymer are measured using a four point probe method prior to preparing the aqueous blend. A film is also presented comprising a first conjugated polymer having a conductivity of greater than 10?7 S/cm and a second conjugated polymer having a conductivity greater than 10?7 S/cm formed by (a) depositing the recited aqueous blend onto an article and (b) removing the water-containing solution to form the film on the article.

Abstract: A dispersion, and a film and optoelectronic devices formed from the dispersion are provided. The dispersion comprising conducting polymer containing particles having a particle size of less than 450 nm, wherein the conducting polymer comprises substituted or unsubstituted, uncharged or charged polymerized units of thieno[3,4-b]thiophene, and wherein a film drop cast from the dispersion has a conductivity from 10?1 to 10?6 S/cm measured using the four point probe method.

Abstract: A light emitting device includes: (a) a light emitting layer including an electroluminescent organic material dispersed in a matrix, wherein the matrix contains a non-electroluminescent organic polymer having a Tg of at least 170° C., and each of the organic polymer and the electroluminescent organic material constitutes at least 20 percent by weight of the light emitting layer; and (b) electrodes in electrical communication with the light emitting layer and configured to conduct an electric charge through the light emitting layer such that the light emitting layer emits light. A method for manufacturing a flexible organic light emitting device, includes providing the light emitting layer and providing electrodes above and below the light emitting layer, wherein the electrodes are in electrical communication with the light emitting layer.

Abstract: A photovoltaic device having an anode, a cathode, and at least one photoactive layer between the anode and the cathode, wherein the at least one photoactive layer includes a composition containing a polymer having a glass transition temperature of at least 125° C.; and a photoactive material, wherein: (a) the photoactive material is a hole transporting organic material, an electron transporting organic material, and/or a light harvesting organic material, (b) the polymer and the photoactive material are in a single phase (c) the photoactive material constitutes at least 20% by weight of the composition, and (d) the at least one photoactive layer is in electrical communication with the anode and the cathode, the anode and the cathode are configured to conduct an electric charge from the at least one photoactive layer produced by the at least one photoactive layer absorbing light.