Abstract: A porous composite material capable of generating an arc in a microwave field includes an inorganic porous framework and a carbon material loaded on the inorganic porous framework. The average pore size of the inorganic porous framework is 0.2-1000 ?m. The porous composite material has an excellent mechanical performance, can generate an arc in a microwave field to quickly generate a high temperature, and thus can be used in fields such as microwave high-temperature heating, biomass pyrolysis, vegetable oil treatment, waste polymer material pyrolysis, petrochemical pyrolysis, carbon-fiber composite material recovery, waste treatment, VOC waste gas treatment, COD wastewater treatment, high-temperature catalysis, waste circuit board full-component recycling, and hydrogen preparation.