Abstract: The present invention relates to the field of zeolite technology, and more particularly to a recyclable polymer template agent, a hierarchical gradient pore Beta zeolite, and a green preparation method thereof. By synthesizing a polymer template agent and utilizing the unique temperature sensitivity conferred by the combination of the hydrophilic quaternary amide group and the hydrophobic isopropyl group in the polyquaternary ammonium salt structure of the recyclable polymer template agent provided by the present invention, the zeolite precursor is locked inside the gel at the zeolite synthesis temperature, directing the formation of the zeolite crystal structure; after crystallization is complete, the reaction temperature is lowered to room temperature, the polymer shell opens, and the locked zeolite crystals inside are released via a diffusion mechanism, followed by centrifugation to separate the polymer from the zeolite for removal.

Abstract: A method for piercing a titanium alloy solid billet, the method including: 1) providing a Mannesmann rotary piercer including two rollers, a feed channel, a plurality of centering devices, and a mandril including a plug; fixing the mandril using the plurality of centering devices, where the Mannesmann rotary piercer has a feeding angle of 6-18°, a cross angle of 15°, and a roll speed of 30-90 rpm; 2) heating a titanium alloy solid billet to 930-990° C.; 3) transferring the titanium alloy solid billet to the feed channel of the Mannesmann rotary piercer; and 4) aligning the titanium alloy solid billet with the plug of the mandril, and driving the titanium alloy solid billet to pass through the plug of the mandril, thereby piercing the titanium alloy solid billet and yielding a titanium alloy tube.

Abstract: A method for preparing an ultrafine-grained superalloy bar, the method including: 1) designing a rolling machine including two rollers and two guide plates, where each of the two rollers includes a first roller and a second roller; the first roller includes a first curve and the second roller includes a second curve; the first curve and the second curve form a generatrix of the two rollers; 2) disposing the two guide plates with two curved surfaces thereof opposite to each other; disposing the two rollers to be between the two guide plates; where the two rollers and the two guide plates form a deformation zone of the rolling machine; and 3) driving the two rollers to rotate around their central axes, heating and introducing a superalloy blank from a gap between two first rollers to the deformation zone of the rolling machine; advancing the superalloy blank towards two second rollers.

Abstract: A tooth cleaning device includes a main body, a cleaning head extending out of the main body, and a camera unit. An upper end of the main body is provided with an inclined portion that is inclined downward and rearward. The camera unit is mounted to the inclined portion. An ultrasonic transducer is mounted to the inclined portion. The cleaning head is connected to the ultrasonic transducer. The ultrasonic transducer is rotatably connected to the main body.

Abstract: A method for piercing a titanium alloy solid billet, the method including: 1) providing a Mannesmann rotary piercer including two rollers, a feed channel, a plurality of centering devices, and a mandril including a plug; fixing the mandril using the plurality of centering devices, where the Mannesmann rotary piercer has a feeding angle of 6-18°, a cross angle of 15°, and a roll speed of 30-90 rpm; 2) heating a titanium alloy solid billet to 930-990° C.; 3) transferring the titanium alloy solid billet to the feed channel of the Mannesmann rotary piercer; and 4) aligning the titanium alloy solid billet with the plug of the mandril, and driving the titanium alloy solid billet to pass through the plug of the mandril, thereby piercing the titanium alloy solid billet and yielding a titanium alloy tube.

Abstract: A method for piercing a titanium alloy solid billet, the method including: 1) providing a Mannesmann rotary piercer including two rollers, a feed channel, a plurality of centering devices, and a mandril including a plug; fixing the mandril using the plurality of centering devices, where the Mannesmann rotary piercer has a feeding angle of 6-18°, a cross angle of 15°, and a roll speed of 30-90 rpm; 2) heating a titanium alloy solid billet to 930-990° C.; 3) transferring the titanium alloy solid billet to the feed channel of the Mannesmann rotary piercer; and 4) aligning the titanium alloy solid billet with the plug of the mandril, and driving the titanium alloy solid billet to pass through the plug of the mandril, thereby piercing the titanium alloy solid billet and yielding a titanium alloy tube.

Abstract: A method for preparing an ultrafine-grained superalloy bar, the method including: 1) designing a rolling machine including two rollers and two guide plates, where each of the two rollers includes a first roller and a second roller; the first roller includes a first curve and the second roller includes a second curve; the first curve and the second curve form a generatrix of the two rollers; 2) disposing the two guide plates with two curved surfaces thereof opposite to each other; disposing the two rollers to be between the two guide plates; where the two rollers and the two guide plates form a deformation zone of the rolling machine; and 3) driving the two rollers to rotate around their central axes, heating and introducing a superalloy blank from a gap between two first rollers to the deformation zone of the rolling machine; advancing the superalloy blank towards two second rollers.

Abstract: The present invention relates to a method of forming a particulate porous metal oxide or metalloid oxide, as well as uses of the obtained a particulate porous metal oxide or metalloid oxide. A solution of a non-ionic surfactant and either an ionic surfactant or an inorganic salt is formed in an acidic aqueous solution. A metal oxide precursor or a metalloid oxide precursor is added. The formed reaction mixture is heated under reflux upon agitation for a period sufficient to obtain a particulate porous metal oxide or metalloid oxide.

Abstract: The present invention relates to a method of forming single-walled carbon nanotubes. The method comprises contacting a gaseous carbon source with mesoporous TUD-1 silicate at suitable conditions. The mesoporous TUD-1 silicate comprises a metal of groups 3-13 of the Periodic Table of the Elements.

Abstract: The present invention relates to a method of forming single-walled carbon nanotubes. The method comprises contacting a gaseous carbon source with mesoporous TUD-1 silicate at suitable conditions. The mesoporous TUD-1 silicate comprises a metal of groups 3-13 of the Periodic Table of the Elements.

Abstract: The present invention relates to a method of forming a particulate porous metal oxide or metalloid oxide, as well as uses of the obtained a particulate porous metal oxide or metalloid oxide. A solution of a non-ionic surfactant and either an ionic surfactant or an inorganic salt is formed in an acidic aqueous solution. A metal oxide precursor or a metalloid oxide precursor is added. The formed reaction mixture is heated under reflux upon agitation for a period sufficient to obtain a particulate porous metal oxide or metalloid oxide.

Abstract: A metal-substituted mesoporous oxide framework, such as Co-MCM-41, are disclosed which includes more than one ion species with different reduction kinetics. The reducibility correlates strongly with the pore radius of curvature, with the metal ions incorporated in smaller pores more resistant to complete reduction. The metal-ion substituted oxide framework improves catalytic processes by controlling the size of the catalytic particles forming in the pores. The metal-substituted mesoporous oxide framework can be employed in selective hydrogenation of organic chemicals, in ammonia synthesis, and in automotive catalytic exhaust systems.