Abstract: A hollow fiber membrane for removal of dissolved oxygen from fluid that is made of a porous hydrophobic material and an apparatus for controlling nitrate concentration level in water comprising a membrane contactor having the membrane, the membrane comprises at least one tubular fiber comprising: an outer wall for contacting fluid external to the tubular fiber; at least three inner channel walls for contacting fluid internal of the tubular fiber, wherein each inner channel wall forms a fluid communicating channel; a plurality of pores, wherein pores proximate to surfaces of the outer wall and each inner channel wall are smaller in size than pores non-proximate to said surfaces of the outer wall and each inner channel wall, wherein a central portion of the tubular fiber has a thickness greater than thickness of the tubular fiber outside the central portion.