Abstract: An inflatable membrane apparatus (10) comprising (a) a fluid accumulator (11) having an upper and a lower face and a fluid entrance (12), said lower face being partly formed by an inflatable membrane (14), and (b) a trunconical part (15) projecting outwardly from the lower face of the accumulator whose greater base is closed by at least part of the inflatable membrane (14) and smaller base forms a circular opening, whereby, when pressurized fluid is introduced into the accumulator (11), deformation of the inflatable membrane (14) is guided by the trunconical part.

Abstract: A transparent, non elastomeric, high refractive index, impact resistant poly(thio)urethane/urea material comprising the reaction product of: a) at least one (?, ?)-diiso(thio)cyanate cycloaliphatic or aromatic polysulfide prepolymer, and b) at least one aromatic primary diamine, in an equivalent molar ratio amine function/iso(thio)cyanate function ranging from 0.5 to 2, wherein, said prepolymer and diamine are free from disulfide (—S—S—) linkage and wherein the (?, ?)-diiso(thio)cyanate polysulfide prepolymer is the reaction product of at least one cycloaliphatic or aromatic diiso(thio)cyanate and at least one (?, ?)-diol prepolymer.

Abstract: A transparent, non elastomeric, high refractive index, impact resistant poly(thio)urethane/urea material comprising the reaction product of: a) at least one (?, ?)-diiso(thio)cyanate cycloaliphatic or aromatic polysulfide prepolymer, and b) at least one aromatic primary diamine, in an equivalent molar ratio amine function/iso(thio)cyanate function ranging from 0.5 to 2, wherein, said prepolymer and diamine are free from disulfide (—S—S—) linkage and wherein the (?, ?)-diiso(thio)cyanate polysulfide prepolymer is the reaction product of at least one cycloaliphatic or aromatic diiso(thio)cyanate and at least one (?, ?)-diol prepolymer.

Abstract: A transparent, non elastomeric, high index, impact resistant polythiourethane/urea material comprising the reaction product of: a) at least one (?, ?)-diiso(thio)cyanate cycloaliphatic or aromatic prepolymer having a number average molecular weight ranging from 100 to 3000 gmol?1, and b) at least one primary diamine, in an equivalent molar ratio amine function/iso(thio)cyanate function from 0.5 to 2, preferably from 0.90 to 1.10, wherein, said prepolymer and diamine are free from disulfide (—S—S—) linkage and at least one of the prepolymer or the diamine contains one or more S atoms in its chain.

Abstract: An inflatable membrane apparatus (10) comprising (a) a fluid accumulator (11) having an upper and a lower face and a fluid entrance (12), said lower face being partly formed by an inflatable membrane (14), and (b) a trunconical part (15) projecting outwardly from the lower face of the accumulator whose greater base is closed by at least part of the inflatable membrane (14) and smaller base forms a circular opening, whereby, when pressurized fluid is introduced into the accumulator (11), deformation of the inflatable membrane (14) is guided by the trunconical part.

Abstract: A process for transferring a coating onto at least one optical surface of a lens blank which comprises: providing a lens blank having at least one geometrically defined surface; providing a support having an internal surface bearing a coating and an external surface; depositing on said geometrically defined surface of said lens blank or said coating a pre-measured amount of a curable glue; moving relatively to each other the lens blank and the support to either bring the coating into contact with the curable glue or bring the curable glue into contact with the geometrically defined surface of the lens blank; applying a sufficient pressure onto the external surface of the support so that the thickness of a final glue layer after curing is less than 100 micrometers; curing the glue; and withdrawing the mold part to recover the lens blank with the coating adhered onto its geometrically defined surface.

Abstract: Disclosed is a thiosphosphine compound of formula: wherein X represents with R1 being H or —CH3, R and R? represent, independently from each other, an alkyl radical, an alkoxy radical, an aryl radical or a phenyl radical which may be substituted with one or more alkyl and/or alkoxy groups, n is an integer from 0 to 4, n? is an integer from 0 to 5, x is an integer from 0 to 2, y is an integer from 1 to 5 with the proviso that y+n is an integer from 1 to 5. The compounds can be used to make optically transparent articles such as ophthalmic lenses.

Abstract: Disclosed is a process for making a thiophosphine compound of formula (I): wherein X represents SH or with R1 being H or —CH3, R and R? represent, independently from each other, an alkyl radical, an alkoxy radical, an aryl radical or a phenyl radical which may be substituted with one or more alkyl and/or alkoxy groups, n is an integer from 0 to 4, n? is an integer from 0 to 5, x is an integer from 0 to 2, y is an integer from 1 to 5 with the proviso that y+n is an integer from 1 to 5, wherein y =1, X is in para position with regard to phosphorus and represents SH.

Abstract: Thiophosphine compounds (also named phosphine sulfide compounds) and their use for making polymerizable compositions which after polymerization give optically transparent articles, such as ophthalmic lenses, having improved mechanical and optical properties and in particular having an improved UV cut.

Abstract: The present invention relates to an improved process or method for transferring a coating onto at least one surface of a lens blank which can be implemented in a short period of time without any risk of deformation of the lens blank.

Abstract: The present invention relates to room temperature or thermally polymerizable/curable episulfide based compositions for making polymerized/cured episulfide based resins, and in particular episulfide based compositions which can be fastly polymerized/cured, as well as to a room temperature or thermal polymerization process for making such episulfide based resins.

Abstract: A method of fast curing polythiourethane transparent casted substrate, usable for making optical articles such as ophthalmic lenses, which comprises the steps of: 1) Providing a first component A comprising a polythiourethane prepolymer having isocyanate or isothiocyanate end groups and a viscosity at 25° C. ranging from 0.02 to 0.4 Pa.s; 2) Providing a second component B comprising a polythiourethane prepolymer having thiol (SH) end groups and a viscosity at 25° C. ranging from 0.2 to 2.0 Pa.s; 3) Mixing together first and second components A and B and filling a moulding cavity of a casting mould assembly with the resulting mixture; 4) Curing said mixture to obtain a transparent solid substrate, said curing step comprising: a) a first step for polymerizing said mixture to obtain a gel within 1 to 10 minutes; and b) a second step of post-curing the gel to obtain the transparent solid substrate; and 5) Recovering the transparent solid substrate from the mould.

Abstract: A process for transferring a coating onto at least one optical surface of a lens blank which comprises:

Abstract: The present invention relates to an improved process or method for transferring a coating onto at least one surface of a lens blank which can be implemented in a short period of time without any risk of deformation of the lens blank.

Abstract: A transparent, non elastomeric, high index, impact resistant polythiourethane/urea material comprising the reaction product of:

Abstract: A process for polymerizing episulfide monomers comprising the steps of: (c) mixing to an episulfide monomer or a mixture of episulfide monomers an effective amount of at least one photopolymerization catalyst selected from the group consisting of (cyclopentadienyl) ruthenium and osmium complexes and an effective amount of at least a co-catalyst selected from phosphonium salts, phosphines and amines; and (d) irradiating the mixture of (a) with an ultra-violet radiation to polymerize the mixture.

Abstract: A method of fast curing polythiourethane transparent casted substrate, usable for making optical articles such as ophthalmic lenses, which comprises the steps of:

Abstract: A method for molding a plastic ophthalmic lens which comprises introducing a liquid polymerizable composition in a molding cavity of a two-piece mold through a filling nozzle in flow communication with the upper half of the molding cavity and spaced apart from the central vertical axis of the molding cavity up to the time the lower half of the molding cavity is filled. Then, tilting the mold to bring the filling in register with the central axis of the molding cavity and achieving full filling of the molding cavity. Thereafter, polymerizing the composition and recovering the lens.

Abstract: The present invention relates to room temperature or thermally polymerizable/curable episulfide based compositions for making polymerized/cured episulfide based resins, and in particular episulfide based compositions which can be fastly polymerized/cured, as well as to a room temperature or thermal polymerization process for making such episulfide based resins.

Abstract: The present invention relates to an improved process or method for transferring a coating onto at least one surface of a lens blank which can be implemented in a short period of time without any risk of deformation of the lens blank.