Abstract: A fluororubber-metal laminate gasket material, which comprises a metallic steel sheet, a zirconium element-, phosphorus element-, and aluminum element-containing surface-treating agent layer, a silica-containing thermosetting phenol resin-based vulcanizing adhesive layer, and a fluororubber layer, as successively laid upon one another on the metallic steel sheet, where the silica-containing thermosetting phenol-based vulcanizing adhesive is a thermosetting phenol resin-based vulcanizing adhesive comprising silica and cresol novolak-type epoxy resin or phenol novolak-type epoxy resin, and further containing 11-80 parts by weight of an aliphatic amine-based compound or a mixture thereof with an imidazole-based compound as a curing accelerator on the basis of 100 parts by weight of the thermosetting phenol resin, where the aliphatic amine-based compound and the imidazol-based compound are in a proportion of the former to the latter of 100-10 wt. % to 0-90 wt. %.

Abstract: A fluororubber-metal laminate sheet, which comprises a metallic sheet and a vulcanized fluorocarbon layer, provided on the metallic sheet by applying thereto a fluororubber composition comprising (A) 100 parts by weight of a polyol-vulcanizable fluororubber, (B) 10-50 parts by weight of amorphous graphite, (C) 1-15 parts by weight of a phenol resin, (D) 1-4 parts by weight of a silane coupling agent, (E) 0.5-8 parts by weight of a polyol-based vulcanizing agent, and (F) 0.5-6 parts by weight of a vulcanizing accelerator, followed by vulcanization of the fluororubber composition to form laminate, where the metallic sheet is free from either a chromating treatment or a chromating substitute treatment, is distinguished in characteristics such as sealability, compression resistance, air-heated aging resistance, anti-freezing liquid resistance, oil resistance, sticking resistance, abrasion resistance, etc.

Abstract: A fluororubber-metal laminate sheet, which comprises a metallic sheet and a vulcanized fluorocarbon layer, provided on the metallic sheet by applying thereto a fluororubber composition comprising (A) 100 parts by weight of a polyol-vulcanizable fluororubber, (B) 10-50 parts by weight of amorphous graphite, (C) 1-15 parts by weight of a phenol resin, (D) 1-4 parts by weight of a silane coupling agent, (E) 0.5-8 parts by weight of a polyol-based vulcanizing agent, and (F) 0.5-6 parts by weight of a vulcanizing accelerator, followed by vulcanization of the fluororubber composition to form laminate, where the metallic sheet is free from either a chromating treatment or a chromating substitute treatment, is distinguished in characteristics such as sealability, compression resistance, air-heated aging resistance, anti-freezing liquid resistance, oil resistance, sticking resistance, abrasion resistance, etc.

Abstract: A fluororubber-metal laminate gasket material, which comprises a metallic steel sheet, a zirconium element-, phosphorus element-, and aluminum element-containing surface-treating agent layer, a silica-containing thermosetting phenol resin-based vulcanizing adhesive layer, and a fluororubber layer, as successively laid upon one another on the metallic steel sheet, where the silica-containing thermosetting phenol-based vulcanizing adhesive is a thermosetting phenol resin-based vulcanizing adhesive comprising silica and cresol novolak-type epoxy resin or phenol novolak-type epoxy resin, and further containing 11-80 parts by weight of an aliphatic amine-based compound or a mixture thereof with an imidazole-based compound as a curing accelerator on the basis of 100 parts by weight of the thermosetting phenol resin, where the aliphatic amine-based compound and the imidazol-based compound are in a proportion of the former to the latter of 100-10 wt. % to 0-90 wt. %.

Abstract: A vulcanizing adhesive composition comprising a copolymerization oligomer of amino group-containing alkoxysilane and vinyl group-containing alkoxysilane, a nonionic surfactant of HLB 10-16 and an acid compound is an aqueous vulcanizing adhesive composition free from an organic solvent and for use in bonding of fluororubber to a metal, which is also effectively applicable to any of polyol-vulcanizable fluororubber and peroxide-vulcanizable fluororubber, showing a good adhesiveness even to stainless steel of poor wettability toward the conventional aqueous adhesive.

Abstract: A vulcanizing adhesive composition comprising a copolymerization oligomer of amino group-containing alkoxysilane and vinyl group-containing alkoxysilane, a nonionic surfactant of HLB 10-16 and an acid compound is an aqueous vulcanizing adhesive composition free from an organic solvent and for use in bonding of fluororubber to a metal, which is also effectively applicable to any of polyol-vulcanizable fluororubber and peroxide-vulcanizable fluororubber, showing a good adhesiveness even to stainless steel of poor wettability toward the conventional aqueous adhesive.