Patents by Inventor Yasuhiro Shibai

Yasuhiro Shibai has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20240010808
    Abstract: A photocatalytic film according to the present disclosure includes a base film, a hard coat layer placed on the base film, and a photocatalytic coat layer placed on the hard coat layer, and is characterized in that the hard coat layer contains an ultraviolet-curable resin, the photocatalytic coat layer contains photocatalytic particles and a binder, the photocatalytic particles are tungsten oxide particles, and the binder is composed of a tetraalkoxysilane hydrolyzed condensate.
    Type: Application
    Filed: June 29, 2023
    Publication date: January 11, 2024
    Inventors: HIDETSUGU KAWAI, YASUHIRO SHIBAI
  • Publication number: 20240010871
    Abstract: A photocatalytic coating agent of the present disclosure includes a liquid medium, photocatalyst particles, and a binder, in which the binder is a hydrolysis condensate of a tetraalkoxysilane and is a long-chain siloxane compound.
    Type: Application
    Filed: June 28, 2023
    Publication date: January 11, 2024
    Inventors: HIDETSUGU KAWAI, Masafumi IKARI, Masao MORIMOTO, YASUHIRO SHIBAI
  • Patent number: 11707911
    Abstract: The present invention provides a method for producing an optical film excellent in anti-fouling properties and scratch resistance as well as anti-reflection properties. The method includes the steps of: (1) applying a lower layer resin and an upper layer resin; (2) forming a resin layer having the uneven structure on a surface thereof by pressing a mold against the lower layer resin and the upper layer resin from the upper layer resin side in the state where the applied lower layer resin and upper layer resin are stacked; and (3) curing the resin layer, the lower layer resin containing at least one kind of first monomer that contains no fluorine atoms, the upper layer resin containing a fluorine-containing monomer and at least one kind of second monomer that contains no fluorine atoms, at least one of the first monomer and the second monomer containing a compatible monomer that is compatible with the fluorine-containing monomer and being dissolved in the lower layer resin and the upper layer resin.
    Type: Grant
    Filed: January 6, 2022
    Date of Patent: July 25, 2023
    Assignee: SHARP KABUSHIKI KAISHA
    Inventors: Hidekazu Hayashi, Tokio Taguchi, Atsushi Niinoh, Kenichiro Nakamatsu, Yasuhiro Shibai
  • Publication number: 20220195173
    Abstract: The film according to an embodiment of the present invention 1 includes a synthetic polymer membrane 3 including a surface having a plurality of protrusions 3a, and photocatalyst particles 4 supported on the surface of the synthetic polymer membrane 3. As the synthetic polymer membrane 3 is seen from a normal line direction, the two-dimensional size of the plurality of protrusions 3a is more than 20 nm to less than 500 nm. The mean particle diameter of the photocatalyst particles 4 is preferably 20 nm or more to 1000 nm or less.
    Type: Application
    Filed: December 13, 2021
    Publication date: June 23, 2022
    Inventors: YASUHIRO SHIBAI, HIDETSUGU KAWAI
  • Patent number: 11364673
    Abstract: A synthetic polymer film whose surface has a plurality of raised or recessed portions, wherein a two-dimensional size of the plurality of raised or recessed portions is in a range of not less than 0.5 ?m and not more than 3 ?m when viewed in a normal direction of the synthetic polymer film, the synthetic polymer film has a crosslink structure and contains an organic carboxylic acid, at the lapse of 5 minutes since placing a 200 ?L drop of water on the surface of the synthetic polymer film, a pH of an aqueous solution is less than 4, and an area equivalent circle diameter of the aqueous solution is not less than 20 mm, and at the lapse of 60 seconds since placing a drop of water on the surface of the synthetic polymer film, a static contact angle of the water drop with respect to the surface is less than 3°.
    Type: Grant
    Filed: February 20, 2019
    Date of Patent: June 21, 2022
    Assignee: SHARP KABUSHIKI KAISHA
    Inventors: Miho Yamada, Yasuhiro Shibai, Kiyoshi Minoura, Tokio Taguchi
  • Publication number: 20220126542
    Abstract: The present invention provides a method for producing an optical film excellent in anti-fouling properties and scratch resistance as well as anti-reflection properties. The method includes the steps of: (1) applying a lower layer resin and an upper layer resin; (2) forming a resin layer having the uneven structure on a surface thereof by pressing a mold against the lower layer resin and the upper layer resin from the upper layer resin side in the state where the applied lower layer resin and upper layer resin are stacked; and (3) curing the resin layer, the lower layer resin containing at least one kind of first monomer that contains no fluorine atoms, the upper layer resin containing a fluorine-containing monomer and at least one kind of second monomer that contains no fluorine atoms, at least one of the first monomer and the second monomer containing a compatible monomer that is compatible with the fluorine-containing monomer and being dissolved in the lower layer resin and the upper layer resin.
    Type: Application
    Filed: January 6, 2022
    Publication date: April 28, 2022
    Applicant: Sharp Kabushiki Kaisha
    Inventors: Hidekazu HAYASHI, Tokio TAGUCHI, Atsushi NIINOH, Kenichiro NAKAMATSU, Yasuhiro SHIBAI
  • Publication number: 20210363482
    Abstract: A three-dimensional culture method includes: providing a cell suspension, the cell suspension containing a cell (12C) and a culture medium (14M); providing a solid surface (10S), the solid surface having a plurality of raised portions (10Sp) whose height is not less than 10 nm and not more than 1 mm; attaching a liquid drop (16D) of the cell suspension to the solid surface (10S); and culturing the cell (12C) in the liquid drop (16D) under such conditions that a direction of gravity exerted on the liquid drop (16D) is toward the solid surface (10S).
    Type: Application
    Filed: August 9, 2019
    Publication date: November 25, 2021
    Inventors: Tokio TAGUCHI, Yasuhiro SHIBAI, Mitsuaki SUGINE, Isao TAKEBAYASHI, Yuko SUGIMOTO
  • Publication number: 20210345860
    Abstract: An endoscope distal end cover (10) is a cover for protecting a distal end (20t) of an endoscope (20) which has an observation window at the distal end, including: a synthetic polymer film (13) which is to be located over the observation window (32) when the endoscope distal end cover is attached to the distal end of the endoscope, wherein the synthetic polymer film has a surface which includes a plurality of raised portions, when viewed in a normal direction of the synthetic polymer film, a two-dimensional size of the plurality of raised portions is in the range of more than 20 nm and less than 500 nm, and a static contact angle of water with respect to the surface is not less than 98°.
    Type: Application
    Filed: October 1, 2019
    Publication date: November 11, 2021
    Inventors: MIHO YAMADA, KIYOSHI MINOURA, TOKIO TAGUCHI, YASUHIRO SHIBAI
  • Patent number: 11142653
    Abstract: The present invention provides a method for producing an antifouling film having excellent antifouling properties and rubbing resistance. The method for producing an antifouling film of the present invention includes Process (1) of applying a resin to a surface of a substrate; Process (2) of pushing the substrate to a die with the resin in between to form an uneven structure on a surface of the resin; and Process (3) of curing the resin including the uneven structure on the surface thereof to form a polymer layer. The resin contains an antifouling agent that contains a compound containing a perfluoro(poly)ether group. The die includes a surface having undergone release treatment using a release agent containing a compound that contains a perfluoro(poly)ether group, a hydrolyzable group, and a Si atom.
    Type: Grant
    Filed: July 3, 2017
    Date of Patent: October 12, 2021
    Assignees: SHARP KABUSHIKI KAISHA, DAIKIN INDUSTRIES, LTD.
    Inventors: Hidekazu Hayashi, Tokio Taguchi, Kenichiro Nakamatsu, Yasuhiro Shibai, Ken Atsumo, Tsuneo Yamashita, Saya Nii, Eiji Sakamoto, Kakeru Hanabusa, Hisashi Mitsuhashi, Takayuki Araki
  • Patent number: 11142617
    Abstract: The present invention provides a method for producing an antifouling film capable of long-term continuous production of an antifouling film having excellent antifouling properties. The method for producing an antifouling film of the present invention includes Process (1) of applying a resin to a surface of a substrate; Process (2) of applying a second release agent to a surface of a die coated with a first release agent; Process (3) of pushing the substrate to the surface of the die coated with the second release agent with the resin in between to form an uneven structure on a surface of the resin; and Process (4) of curing the resin including the uneven structure on the surface thereof to form a polymer layer. The resin contains an antifouling agent that contains a predetermined compound. The first release agent contains a predetermined compound. The second release agent contains a predetermined compound.
    Type: Grant
    Filed: July 3, 2017
    Date of Patent: October 12, 2021
    Assignees: SHARP KABUSHIKI KAISHA, DAIKIN INDUSTRIES, LTD.
    Inventors: Hidekazu Hayashi, Tokio Taguchi, Kenichiro Nakamatsu, Yasuhiro Shibai, Ken Atsumo, Tsuneo Yamashita, Eiji Sakamoto, Saya Nii, Takayuki Araki
  • Patent number: 10996377
    Abstract: The method for producing an optical member of the present invention includes: a step (1) of applying a lower layer resin and an upper layer resin; a step (2) of pressing a die against the lower layer resin and the upper layer resin from the upper layer resin side, so as to form a resin layer including an uneven structure on a surface thereof; and a step (3) of curing the resin layer to form the polymer layer, wherein the lower layer resin contains an amide group, the lower layer resin has an amide group concentration of 1.5 mmol/g or more and less than 5 mmol/g, and the polymer layer has a minimum storage modulus E? of 1×108 Pa or higher and 1×109 Pa or lower at a bottom temperature of 110° C. or higher and 210° C. or lower.
    Type: Grant
    Filed: February 15, 2017
    Date of Patent: May 4, 2021
    Assignee: SHARP KABUSHIKI KAISHA
    Inventors: Yasuhiro Shibai, Ken Atsumo, Hidekazu Hayashi
  • Patent number: 10976475
    Abstract: The antifouling film includes a substrate, and a polymer layer disposed on a surface of the substrate and including on a surface thereof an uneven structure provided with multiple projections at a pitch not longer than a wavelength of visible light. The polymer layer is a cured product of a polymerizable composition, the polymerizable composition containing, in terms of active constituents, 15 to 40 wt % of an urethane acrylate containing six or more functional groups, 35 to 60 wt % of a multifunctional acrylate containing four or more functional groups and 3 to 15 ethylene oxide groups for each functional group, 15 to 30 wt % of a monofunctional acrylate with no ethylene oxide group, 0.5 to 10 wt % of a fluorine release agent containing a perfluoropolyether group and having a fluorine atom concentration of 50 wt % or lower, and 0.5 to 5 wt % of a polymerization initiator.
    Type: Grant
    Filed: June 28, 2017
    Date of Patent: April 13, 2021
    Assignee: SHARP KABUSHIKI KAISHA
    Inventors: Yasuhiro Shibai, Ken Atsumo, Kenichiro Nakamatsu
  • Patent number: 10968292
    Abstract: A synthetic polymer film is a synthetic polymer film whose surface has a plurality of raised or recessed portions. The synthetic polymer film has a crosslink structure, and the crosslink structure does not contain any nitrogen element that is a constituent of a urethane bond. The synthetic polymer film contains an organic carboxylic acid, and an amount of water required for dissolving 1 g of the organic carboxylic acid is equal to or greater than 10 mL and less than 10000 mL. At the lapse of 5 minutes since placing a 200 ?L drop of water on the surface of the synthetic polymer film, a pH of an aqueous solution is not more than 5, and an area equivalent circle diameter of the aqueous solution is not less than 20 mm. A synthetic polymer film whose surface has a microbicidal activity can be produced using a photocurable resin composition which contains an organic carboxylic acid or a photoacid generator which generates the organic carboxylic acid.
    Type: Grant
    Filed: September 25, 2018
    Date of Patent: April 6, 2021
    Assignee: SHARP KABUSHIKI KAISHA
    Inventors: Yasuhiro Shibai, Miho Yamada, Ken Atsumo, Kiyoshi Minoura
  • Publication number: 20210096282
    Abstract: The antifouling film includes a substrate, and a polymer layer disposed on a surface of the substrate and including on a surface thereof an uneven structure provided with multiple projections at a pitch not longer than a wavelength of visible light. The polymer layer is a cured product of a polymerizable composition, the polymerizable composition containing, in terms of active constituents, 15 to 40 wt % of an urethane acrylate containing six or more functional groups, 35 to 60 wt % of a multifunctional acrylate containing four or more functional groups and 3 to 15 ethylene oxide groups for each functional group, 15 to 30 wt % of a monofunctional acrylate with no ethylene oxide group, 0.5 to 10 wt % of a fluorine release agent containing a perfluoropolyether group and having a fluorine atom concentration of 50 wt % or lower, and 0.5 to 5 wt % of a polymerization initiator.
    Type: Application
    Filed: June 28, 2017
    Publication date: April 1, 2021
    Inventors: YASUHIRO SHIBAI, KEN ATSUMO, KENICHIRO NAKAMATSU
  • Patent number: 10947411
    Abstract: The optical member of the present invention includes a substrate and a polymer layer that is in direct contact with the substrate and includes on a surface thereof an uneven structure provided with multiple projections at a pitch not longer than a wavelength of visible light, the polymer layer containing an amide group, the polymer layer having an amide group concentration of 2 mmol/g or higher and lower than 5 mmol/g, the polymer layer having a minimum storage modulus E? of 1×108 Pa or higher and 1×109 Pa or lower at a bottom temperature of 110° C. or higher and 210° C. or lower in a dynamic viscoelasticity measurement with a measurement temperature range of ?50° C. to 250° C., a temperature rise rate of 5° C./min, and a frequency of 10 Hz.
    Type: Grant
    Filed: December 8, 2016
    Date of Patent: March 16, 2021
    Assignee: SHARP KABUSHIKI KAISHA
    Inventors: Yasuhiro Shibai, Ken Atsumo, Hidekazu Hayashi, Nobuaki Yamada
  • Patent number: 10934405
    Abstract: A synthetic polymer film has a surface which has a plurality of raised or recessed portions, wherein the synthetic polymer film has a cross-linked structure, and the synthetic polymer film contains an antimicrobial additive which is permitted by law for addition to food and which has an antimicrobial effect.
    Type: Grant
    Filed: March 14, 2019
    Date of Patent: March 2, 2021
    Assignee: SHARP KABUSHIKI KAISHA
    Inventors: Yasuhiro Shibai, Miho Yamada
  • Patent number: 10926510
    Abstract: The present invention provides an antifouling film that is excellent in antifouling properties, adhesion, rubbing resistance, and reliability, and reduces fingerprint emergence at high humidity. The antifouling film includes a substrate; and a polymer layer disposed on a surface of the substrate and including on a surface thereof an uneven structure provided with projections at a pitch not longer than a wavelength of visible light, the polymer layer being a cured product of a polymerizable composition, the polymerizable composition containing, in terms of active components, 20 to 90 wt % of a polyfunctional acrylate containing an ethylene oxide group, 5 to 25 wt % of a monofunctional amide monomer, and 0.5 to 10 wt % of a fluorine-based release agent, the polymerizable composition containing, in terms of active components, a total of 40 to 65 wt % of the ethylene oxide group in the polyfunctional acrylate and the monofunctional amide monomer.
    Type: Grant
    Filed: January 11, 2018
    Date of Patent: February 23, 2021
    Assignee: SHARP KABUSHIKI KAISHA
    Inventors: Yasuhiro Shibai, Ken Atsumo, Kenichiro Nakamatsu
  • Patent number: 10913862
    Abstract: The present invention provides an antifouling film that is excellent in antifouling properties, rubbing resistance, and adhesion. The antifouling film includes: a substrate; and a polymer layer disposed on a surface of the substrate and including on a surface thereof an uneven structure provided with projections at a pitch not longer than a wavelength of visible light, the polymer layer being a cured product of a polymerizable composition, the polymerizable composition containing, in terms of active components, 30 to 80 wt % of a polyfunctional acrylate, 10 to 30 wt % of a monofunctional amide monomer, 0.5 to 10 wt % of a fluorine-based release agent, and 5 to 30 wt % of a vinyl-based polymer containing a repeat unit represented by a predetermined formula.
    Type: Grant
    Filed: January 23, 2018
    Date of Patent: February 9, 2021
    Assignee: SHARP KABUSHIKI KAISHA
    Inventors: Yasuhiro Shibai, Ken Atsumo, Kenichiro Nakamatsu
  • Publication number: 20210015345
    Abstract: An endoscope distal end cover (10) is a cover for protecting a distal end (20t) of an endoscope (20) which has an observation window at the distal end, including: a synthetic polymer film (13) which is to be located over the observation window (32) when the endoscope distal end cover is attached to the distal end of the endoscope, wherein the synthetic polymer film has a surface which includes a plurality of raised portions, when viewed in a normal direction of the synthetic polymer film, a two-dimensional size of the plurality of raised portions is in the range of more than 20 nm and less than 500 nm, and a static contact angle of water with respect to the surface is not less than 150°, and a static contact angle of hexadecane with respect to the surface is not less than 60°.
    Type: Application
    Filed: March 20, 2019
    Publication date: January 21, 2021
    Inventors: MIHO YAMADA, KIYOSHI MINOURA, TOKIO TAGUCHI, YASUHIRO SHIBAI
  • Patent number: 10800868
    Abstract: An antifouling film includes: a substrate; and a polymer layer disposed on a surface of the substrate and including on a surface thereof an uneven structure provided with projections at a pitch not longer than a wavelength of visible light. The polymer layer is a cured product of a polymerizable composition. The polymerizable composition contains, in terms of active components, 75 to 95 wt % of a polymerizable monomer, 2.5 to 12.5 wt % of a urethane acrylate containing fluorine and an ester, and 2.5 to 9 wt % of a perfluoroalkyl-based monomer containing one (meth)acryloyl group for each molecule. The polymerizable monomer contains a bifunctional acrylate that contains an ethylene oxide group and a multifunctional acrylate that contains no ethylene oxide group. The perfluoroalkyl-based monomer has a fluorine atom concentration of 50 to 60 wt %. The polymerizable composition has an ethylene oxide group concentration of 20 to 50 wt %.
    Type: Grant
    Filed: November 21, 2019
    Date of Patent: October 13, 2020
    Assignee: SHARP KABUSHIKI KAISHA
    Inventors: Yasuhiro Shibai, Tokio Taguchi, Kenichiro Nakamatsu