Abstract: A negative electrode material for a non-aqueous electrolyte secondary battery and the like with high discharge capacity relative to volume and excellent cycle characteristics are provided. The negative electrode material for a non-aqueous electrolyte secondary battery of the present invention comprises, as an active material, a carbon material mixture including a non-graphitic carbon material and a graphitic material. In this carbon material mixture, the non-graphitic carbon material has an atom ratio (H/C) of hydrogen atoms to carbon atoms determined by elemental analysis of 0.10 or less, and an average particle size (Dv50) of from 1 to 8 ?m; and the graphitic material has a true density (?Bt) determined by a pycnometer method using butanol of 2.15 g/cm3 or greater. The true density (?Bt) of the non-graphitic carbon material is preferably 1.52 g/cm3 or greater and less than 2.15 g/cm3.

Abstract: An object of the present invention is to provide a material for non-aqueous electrolyte secondary battery negative electrodes containing a graphitic material and a non-graphitizable carbonaceous material, the material having excellent resistance against deterioration due to moisture absorption and excellent charge/discharge cycle resistance; a non-aqueous electrolyte secondary battery negative electrode using the same; and a non-aqueous electrolyte secondary battery using these, that has low resistance and excellent cycle durability. The present invention comprises a carbonaceous material obtained by carbonizing a plant-derived organic material having a potassium content of 0.5% by mass or less, an average particle size Dv50 of 2 ?m to 50 ?m, an average interlayer spacing of (002) plane determined by powder X-ray diffraction of 0.365 nm to 0.400 nm, an atomic ratio (H/C) of hydrogen atoms to carbon atoms determined by elemental analysis of 0.

Abstract: The object of the present invention is to provide a manufacturing method of carbonaceous material for a negative electrode of lithium ion capacitors, wherein the carbonaceous material is obtained from plant-derived char as a source, potassium and iron are sufficiently removed, and an average particle diameter thereof is small; and a carbonaceous material for a negative electrode of lithium ion capacitors. The object can be solved by a method for manufacturing a carbonaceous material having an average diameter of 3 to 30 ?m, for a negative electrode of lithium ion capacitors comprising the steps of: (1) heating plant-derived char having an average particle diameter of 100 to 10000 ?m at 500° C. to 1250° C. under an inert gas atmosphere containing a halogen compound to demineralize in a gas-phase, (2) pulverizing a carbon precursor obtained by the demineralization in a gas-phase, (3) calcining the pulverized carbon precursor at less than 1100° C. under a non-oxidizing gas atmosphere.

Abstract: Provided is a manufacturing method of carbonaceous material for a negative electrode of non-aqueous electrolyte secondary batteries, wherein the carbonaceous material is obtained from plant-derived char as a source, potassium is sufficiently removed, and an average particle diameter thereof is small; and a carbonaceous material for a negative electrode of non-aqueous electrolyte secondary batteries. The method for manufacturing a carbonaceous material having an average particle diameter of 3 to 30 ?m, for a negative electrode of non-aqueous electrolyte secondary batteries includes the steps of: (1) heating plant-derived char having an average particle diameter of 100 to 10000 ?m at 500° C. to 1250° C. under an inert gas atmosphere containing halogen compound to demineralize in a gas-phase, (2) pulverizing a carbon precursor obtained by demineralization in a gas-phase, (3) calcining the pulverized carbon precursor at 1000° C. to 1600° C. under an non-oxidizing gas atmosphere.

Abstract: Provided is a less hygroscopic carbonaceous material that is obtained from a plant-derived carbonaceous raw material and that, when used as a negative electrode material for a nonaqueous electrolyte secondary battery, allows the battery to exhibit good battery characteristics. Provided is a carbonaceous material for negative electrodes of nonaqueous electrolyte secondary batteries. This carbonaceous material is a particulate carbonaceous material containing carbonaceous particles. The carbonaceous material has a BET specific surface area of 1 m2/g or more and less than 20 m2/g. Each of the carbonaceous particles of the carbonaceous material has a core and a skin covering the core. The core contains a calcined product of a plant-derived carbonaceous raw material. The skin is made of a material that has higher electron emission ability upon irradiation with an electron beam than a material of the core.

Abstract: The object of the present invention is to provide a manufacturing method of carbonaceous material for a negative electrode of non-aqueous electrolyte secondary batteries, wherein the carbonaceous material is obtained from plant-derived char as a source, potassium is sufficiently removed, and an average particle diameter thereof is small; and a carbonaceous material for a negative electrode of non-aqueous electrolyte secondary batteries. The object can be solved by a method for manufacturing a carbonaceous material having an average particle diameter of 3 to 30 ?m, for a negative electrode of non-aqueous electrolyte secondary batteries comprising the steps of: (1) heating plant-derived char having an average particle diameter of 100 to 10000 ?m at 500° C. to 1250° C. under an inert gas atmosphere containing halogen compound to demineralize in a gas-phase, (2) pulverizing a carbon precursor obtained by demineralization in a gas-phase, (3) calcining the pulverized carbon precursor at 1000° C. to 1600° C.

Abstract: An object of the present invention is to provide a carbonaceous material for a negative electrode for producing a nonaqueous electrolyte secondary battery capable of rapid charge and discharge and having excellent rate characteristics (output characteristics) while maintaining a large discharge capacity. The problem described above can be solved by a carbonaceous material for a nonaqueous electrolyte secondary battery negative electrode of the present invention obtained by heat-treating a non-graphitizable carbon precursor which is pulverized and contains from 13 to 80 wt. % of a volatile component. With the present invention, it is possible to provide a carbonaceous material for a nonaqueous electrolyte secondary battery negative electrode, whereby a nonaqueous electrolyte secondary battery having a large charge-discharge capacity and having excellent rate characteristics can be produced.

Abstract: The object of the present invention is to provide a manufacturing method of carbonaceous material for a negative electrode of lithium ion capacitors, wherein the carbonaceous material is obtained from plant-derived char as a source, potassium and iron are sufficiently removed, and an average particle diameter thereof is small; and a carbonaceous material for a negative electrode of lithium ion capacitors. The object can be solved by a method for manufacturing a carbonaceous material having an average diameter of 3 to 30 ?m, for a negative electrode of lithium ion capacitors comprising the steps of: (1) heating plant-derived char having an average particle diameter of 100 to 10000 ?m at 500° C. to 1250° C. under an inert gas atmosphere containing a halogen compound to demineralize in a gas-phase, (2) pulverizing a carbon precursor obtained by the demineralization in a gas-phase, (3) calcining the pulverized carbon precursor at less than 1100° C. under a non-oxidizing gas atmosphere.

Abstract: The object of the present invention is to provide a carbonaceous material which is obtainable from plant-derived char and has a decreased specific surface area. Further, the object of the present invention is to provide a non-aqueous electrolyte secondary battery having excellent dedoping capacity (discharge capacity), non-dedoping capacity (irreversible capacity), and charge-discharge efficiency. The object can be solved by a carbonaceous material for non-aqueous electrolyte secondary batteries characterized in that the carbonaceous material is obtained by heat-treating plant-derived char which is demineralized in gas-phase, and carbon precursor (i.e. non-graphitizable carbon precursor, graphitizable carbon, or mixture thereof) or volatile organic compound under a non-oxidizing gas atmosphere; and a specific surface area determined by a BET method is 10 m2/g or less.

Abstract: An object of the present invention is to provide a method of producing, stably and at high yield, a carbonaceous material for non-aqueous electrolyte secondary battery negative electrodes, whose raw material is coffee bean, that has high purity achieved by de-mineralization in which alkali metals such as potassium element and alkaline earth metal such as calcium element are sufficiently removed, and that can guarantee reliability, and an intermediate product for obtaining the same. A raw material composition for producing a carbonaceous material for non-aqueous electrolyte secondary battery negative electrodes comprises a roasted coffee bean-derived organic material having an L value of 18.0 or less. The raw material composition for producing a carbonaceous material for non-aqueous electrolyte secondary battery negative electrodes is formed from a roasted coffee bean-derived organic material having an L value of 19.0 or less.

Abstract: A porous membrane of vinylidene fluoride resin, including a 10 ?m-thick portion contiguous to one surface thereof which comprises network resin fibers having an average diameter of at most 100 nm and shows a porosity A1 of at least 60% as measured by a focused ion beam-scanning electron microscope, and showing a surface pore size of at most 0.3 ?m on said one surface thereof. The porous membrane has a treated water side surface layer showing a small surface pore size suitable for water filtration treatment and formed of extremely thin network resin fibers giving an extremely high porosity, thus showing an excellent minute particle-blocking performance and also extremely good anti-soiling resistance and regeneratability.

Abstract: A porous membrane of vinylidene fluoride resin, having two major surfaces, including a dense layer which governs filtration performance on one major surface side and a sparse layer which contributes to reinforcement on the other opposite major surface side, and having an asymmetrical gradient network texture including pore sizes which increase continuously from the one major surface to the other opposite major surface, wherein the dense layer includes a 7 ?m-thick portion contiguous to the one major surface showing a porosity A1 of at least 50%, and the one major surface shows a pore size of at most 0.30 ?m. The vinylidene-fluoride-resin porous membrane is useful as a porous membrane for separation and particularly exhibits good water-permeation-rate retentivity even in continuous filtration of cloudy water.

Abstract: The object of the present invention is to provide a carbonaceous material for an anode of a nonaqueous electrolyte secondary battery which uses a plant-derived organic material as a raw material, has high purity so that alkali metals such as the potassium element and alkali earth metals such as the calcium element are sufficiently removed by de-mineral treatment, and has excellent discharge capacity and efficiency, a novel manufacturing method capable of efficiently mass-producing the carbonaceous material, and a lithium ion secondary battery using the carbonaceous material. The problem described above can be solved by a carbonaceous material for an anode of a nonaqueous electrolyte secondary battery obtained by carbonizing a plant-derived organic material, the atom ratio (H/C) of hydrogen atoms and carbon atoms according to elemental analysis being at most 0.

Abstract: The object of the present invention is to provide a carbonaceous material for an anode of a nonaqueous electrolyte secondary battery which uses a plant-derived organic material as a raw material, has high purity so that alkali metals such as the potassium element are sufficiently removed by de-mineral, and has excellent cycle characteristics, and to provide a lithium ion secondary battery using the carbonaceous material. The carbonaceous material for an anode of a nonaqueous electrolyte secondary battery is a carbonaceous material obtained by carbonizing a plant-derived organic material, the atom ratio of hydrogen atoms and carbon atoms (H/C) according to elemental analysis being at most 0.1, the average particle size Dv50 being from 2 to 50 ?m, the average interlayer spacing of the 002 planes determined by X-ray diffraction being from 0.365 nm to 0.400 nm, the potassium element content being at most 0.5 mass %, the calcium element content being at most 0.

Abstract: An object of the present invention is to provide a material for non-aqueous electrolyte secondary battery negative electrodes containing a graphitic material and a non-graphitizable carbonaceous material, the material having excellent resistance against deterioration due to moisture absorption and excellent charge/discharge cycle resistance; a non-aqueous electrolyte secondary battery negative electrode using the same; and a non-aqueous electrolyte secondary battery using these, that has low resistance and excellent cycle durability. The present invention comprises a carbonaceous material obtained by carbonizing a plant-derived organic material having a potassium content of 0.5% by mass or less, an average particle size Dv50 of 2 ?m to 50 ?m, an average interlayer spacing of (002) plane determined by powder X-ray diffraction of 0.365 nm to 0.400 nm, an atomic ratio (H/C) of hydrogen atoms to carbon atoms determined by elemental analysis of 0.

Abstract: An object of the present invention is to provide a carbonaceous material for a non-aqueous electrolyte secondary battery having excellent output characteristics and exhibiting excellent cycle characteristics, and a negative electrode using the same. The problem described above is solved by a carbonaceous material for a non-aqueous electrolyte battery having a true density of 1.4 to 1.7 g/cm3, an atom ratio (H/C) of hydrogen atoms to carbon atoms of at most 0.1, as determined by elemental analysis, an average particle size Dv50 of 3 to 35 ?m, a ratio Dv90/Dv10 of 1.05 to 3.00, and a degree of circularity of 0.50 to 0.95.

Abstract: The object of the present invention is to provide a carbonaceous material for a negative electrode of non-aqueous electrolyte secondary batteries having a great charge-discharge capacity, high charge-discharge efficiency, and an excellent charge-discharge cycle characteristic. The object can be solved by a carbonaceous material for a negative electrode of non-aqueous electrolyte secondary batteries, characterized in that an average (002) interlayer spacing d002 determined by X-ray diffractometry is 0.365 to 0.400 nm, a specific surface area determined by a BET method is 1 to 7 m2/g, an average diameter is 5 to 25 ?m, a value of (D90?D10)/D50 is 1.05 or less, and an exothermic peak does not emerge at a temperature range of 620° C. or less in differential thermal analysis measured in an air atmosphere.

Abstract: A porous membrane of vinylidene fluoride resin, comprising a substantially single layer membrane of vinylidene fluoride resin having two major surfaces sandwiching a certain thickness, including a dense layer that has a small pore size and governs a filtration performance on one major surface side thereof, having an asymmetrical gradient network structure wherein pore sizes continuously increase from the one major surface side to the other opposite major surface side, and satisfying conditions: (a) the dense layer includes a 5 ?m-thick portion contiguous to the one major surface showing a porosity A1 of at least 60%, (b) the one major surface shows a pore size P1 of at most 0.

Abstract: A porous membrane of vinylidene fluoride resin, including a 10 ?m-thick portion contiguous to one surface thereof which comprises network resin fibers having an average diameter of at most 100 nm and shows a porosity A1 of at least 60% as measured by a focused ion beam-scanning electron microscope, and showing a surface pore size of at most 0.3 ?m on said one surface thereof. The porous membrane has a treated water side surface layer showing a small surface pore size suitable for water filtration treatment and formed of extremely thin network resin fibers giving an extremely high porosity, thus showing an excellent minute particle-blocking performance and also extremely good anti-soiling resistance and regeneratability.

Abstract: A hollow-fiber porous membrane of vinylidene fluoride resin, satisfying: a ratio Pmax/Pm of at most 2.0 between a maximum pore size Pmax and an average pore size Pm, and a Pm of 0.13 ?m-0.25 ?m, according to the half-dry/bubble point method (ASTM F316 and ASTM E1294); a coefficient of variation in outer surface pore size of at most 70%, and a porosity of 75-90%. The hollow-fiber porous membrane has a moderate average pore size, has a pore size distribution which is uniform as a whole and also on the outer surface, and has a high porosity, so that it shows not only a good pure water permeability but also retains a good water permeability even in continuous filtration of cloudy water.