Patents by Inventor Yasuhisa Nakashima

Yasuhisa Nakashima has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11607667
    Abstract: Provided is a water-absorbing agent that causes no or little fluctuation of feed rate when fed with use of a feeder. A water-absorbing agent containing a water-absorbing resin as a main component, the water-absorbing agent satisfying the following (a) and (b): (a) K-index is 70 or more; and (b) Moisture absorption blocking ratio, after 30 minutes of standing at a temperature of 25° C. and a relative humidity of 80% RH, is 70 weight % or less, the K-index being defined by the following equation: K-index=100?(?438+3.6×angle of repose+3.5×angle of difference+7.9×compressibility rate+290×bulk density (EDANA method)).
    Type: Grant
    Filed: November 14, 2018
    Date of Patent: March 21, 2023
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Hiroki Kawada, Taku Iwamura, Koji Tachi, Makiko Masuda, Yasuhisa Nakashima, Kazushi Torii, Yukihiro Kasano
  • Publication number: 20200398253
    Abstract: Provided is a water-absorbing agent that causes no or little fluctuation of feed rate when fed with use of a feeder. A water-absorbing agent containing a water-absorbing resin as a main component, the water-absorbing agent satisfying the following (a) and (b): (a) K-index is 70 or more; and (b) Moisture absorption blocking ratio, after 30 minutes of standing at a temperature of 25° C. and a relative humidity of 80% RH, is 70 weight % or less, the K-index being defined by the following equation: K-index=100?(?438+3.6×angle of repose+3.5×angle of difference+7.9×compressibility rate+290×bulk density (EDANA method)).
    Type: Application
    Filed: November 14, 2018
    Publication date: December 24, 2020
    Applicant: NIPPON SHOKUBAI CO., LTD.
    Inventors: Hiroki KAWADA, Taku IWAMURA, Koji TACHI, Makiko MASUDA, Yasuhisa NAKASHIMA, Kazushi TORII, Yukihiro KASANO
  • Patent number: 10363339
    Abstract: An object of the present invention is to provide (i) a water absorbent agent composition which has an excellent additional function (a deodorizing function in particular), which stably carries out the additional function even after being stored for a long term, and which is less stressful to skin when used as an absorbent article, (ii) a method for producing the water absorbent agent composition, and (iii) an absorbent core and an absorbent article. The water absorbent agent composition contains: a polycarboxylic acid (salt)-based water absorbent resin as a main component; a natural ingredient; and a temporal deterioration preventing agent. Further, a water absorbent agent composition is produced by simultaneously or separately mixing a natural ingredient and a temporal deterioration preventing agent with a water absorbent resin which is a crosslinked polymer of unsaturated monomers having carboxylic acid and/or a salt thereof.
    Type: Grant
    Filed: November 15, 2012
    Date of Patent: July 30, 2019
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Manabu Ueda, Hiroyuki Ikeuchi, Yasuhisa Nakashima, Katsuyuki Wada
  • Patent number: 10196500
    Abstract: The present invention (a) provides, at low cost, a water absorbing agent (i) that has a suppressed amount of generated dust and a suppressed amount of dust that increases over time and (ii) that also has a high absorption capacity without load, a high absorption capacity under load, a high vertical diffusion absorbency under load, and a high absorbency in a short period of time, and (b) also provides a method for evaluating, in a short period of time, an amount of dust that increases over time. A particulate water absorbing agent of the present invention includes: a surface crosslinked polyacrylic acid (salt)-based water absorbent resin as a main component; a hydrophilic polymer compound; and a stabilizing agent.
    Type: Grant
    Filed: August 27, 2013
    Date of Patent: February 5, 2019
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Yasuhisa Nakashima, Katsuyuki Wada, Hiroyuki Ikeuchi, Manabu Ueda
  • Patent number: 9796853
    Abstract: A water-absorbent resin composition suffering exfoliation of additives from a water-absorbent resin only insignificantly and excelling in fluidity of powder after absorption of moisture and in deodorizing property and absorbent property as well is provided. The water-absorbent resin composition of this invention comprises a water-absorbent resin obtainable by polymerizing an unsaturated monomer having an acid group and/or a salt thereof; and complex oxide hydrate containing zinc and silicon, or zinc and aluminum, wherein the complex oxide hydrate contains zinc as main metal component, the mass ratio of the content of zinc and the content of silicon or aluminum is in the range of 50/50-99/1, and the absorption capacity at 60 minutes toward 0.90 mass % sodium chloride aqueous solution under the pressure of 1.9 kPa is not less than 20 g/g. Optionally, a plant component (C) can be added to the water absorbent resin composition.
    Type: Grant
    Filed: July 23, 2004
    Date of Patent: October 24, 2017
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Hiroko Ueda, Katsuyuki Wada, Yasuhisa Nakashima
  • Patent number: 9669386
    Abstract: A particulate water-absorbing agent containing a surface-crosslinked polyacrylic acid (salt)-type water-absorbing resin as a main component and at least one spacer selected from a polycation and water-insoluble fine particles. The particulate water-absorbing agent has a free swell capacity (FSC) of 55 to 65 g/g, an absorption against pressure (AAP—4.83 kPa) of 20 to 30 g/g, and a vertical diffusion absorption amount under pressure (VDAUP—4.83 kPa) of 30 to 80 g. Also disclosed is a method for producing a particulate water-absorbing agent, an absorbent core containing the particulate water-absorbing agent, and an absorbing article containing the absorbent core.
    Type: Grant
    Filed: September 30, 2011
    Date of Patent: June 6, 2017
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Katsuyuki Wada, Yasuhisa Nakashima
  • Patent number: 9180220
    Abstract: A water absorbing agent of the present invention has an internal crosslinking structure obtained by polymerization of a water-soluble unsaturated monomer. The agent satisfies conditions (a) to (d): (a) the agent contains water-insoluble inorganic particles at an amount of from 10 ppm to 1,900 ppm inclusive; (b) the agent contains 5 mass % or less particles which have such a size that they can pass through a sieve having a mesh opening size of 150 ?m; (c) the agent has an absorbency against a pressure of 4.83 kPa (AAP) of 18 g/g or more; and (d) the water-insoluble inorganic particles reside on a surface of the water absorbing resin or near the surface.
    Type: Grant
    Filed: May 9, 2012
    Date of Patent: November 10, 2015
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Kazushi Torii, Hirofumi Shibata, Kazuki Kimura, Yasuhisa Nakashima, Motohiro Imura, Hiroko Ueda, Katsuyuki Wada
  • Publication number: 20150218341
    Abstract: The present invention (a) provides, at low cost, a water absorbing agent (i) that has a suppressed amount of generated dust and a suppressed amount of dust that increases over time and (ii) that also has a high absorption capacity without load, a high absorption capacity under load, a high vertical diffusion absorbency under load, and a high absorbency in a short period of time, and (b) also provides a method for evaluating, in a short period of time, an amount of dust that increases over time. A particulate water absorbing agent of the present invention includes: a surface crosslinked polyacrylic acid (salt)-based water absorbent resin as a main component; a hydrophilic polymer compound; and a stabilizing agent.
    Type: Application
    Filed: August 27, 2013
    Publication date: August 6, 2015
    Applicant: NIPPON SHOKUBAI CO., LTD.
    Inventors: Yasuhisa Nakashima, Katsuyuki Wada, Hiroyuki Ikeuchi, Manabu Ueda
  • Patent number: 9044525
    Abstract: Provided is a water absorbent resin having excellent liquid permeability, water absorbent speed, anti-impact stability, and weather resistance. Provided is a polyacrylic acid (salt)-based water absorbent resin powder in which the water absorption capacity without load (CRC) is 30 to 45 [g/g], the water absorption capacity under load (AAP 0.3) is 20 to 35 [g/g], the water absorption capacity under load (AAP 0.7) is 10 to 28 [g/g], and the weight average particle diameter (D50) is 300 to 500 ?m, characterized by including p-methoxyphenol; having a degradable soluble component (0.05% L-A (saline) for 2 hours/60° C., one hour extraction rinse/room temperature) of 40% by weight or less; and having a internal gas bubbles ratio of 0.1 to 2.5%, as specified by the following equation.
    Type: Grant
    Filed: June 29, 2012
    Date of Patent: June 2, 2015
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Kazushi Torii, Reiko Nakatsuru, Yasuhisa Nakashima, Katsuyuki Wada, Kunihiko Ishizaki
  • Publication number: 20140299815
    Abstract: An object of the present invention is to provide (i) a water absorbent agent composition which has an excellent additional function (a deodorizing function in particular), which stably carries out the additional function even after being stored for a long term, and which is less stressful to skin when used as an absorbent article, (ii) a method for producing the water absorbent agent composition, and (iii) an absorbent core and an absorbent article. The water absorbent agent composition contains: a polycarboxylic acid (salt)-based water absorbent resin as a main component; a natural ingredient; and a temporal deterioration preventing agent. Further, a water absorbent agent composition is produced by simultaneously or separately mixing a natural ingredient and a temporal deterioration preventing agent with a water absorbent resin which is a crosslinked polymer of unsaturated monomers having carboxylic acid and/or a salt thereof.
    Type: Application
    Filed: November 15, 2012
    Publication date: October 9, 2014
    Inventors: Manabu Ueda, Hiroyuki Ikeuchi, Yasuhisa Nakashima, Katsuyuki Wada
  • Publication number: 20140193641
    Abstract: Provided is a water absorbent resin having excellent liquid permeability, water absorbent speed, anti-impact stability, and weather resistance. Provided is a polyacrylic acid (salt)-based water absorbent resin powder in which the water absorption capacity without load (CRC) is 30 to 45 [g/g], the water absorption capacity under load (AAP 0.3) is 20 to 35 [g/g], the water absorption capacity under load (AAP 0.7) is 10 to 28 [g/g], and the weight average particle diameter (D50) is 300 to 500 ?m, characterized by including p-methoxyphenol; having a degradable soluble component (0.05% L-A (saline) for 2 hours/60° C., one hour extraction rinse/room temperature) of 40% by weight or less; and having a internal gas bubbles ratio of 0.1 to 2.5%, as specified by the following equation.
    Type: Application
    Filed: June 29, 2012
    Publication date: July 10, 2014
    Applicant: NIPPON SHOKUBAI CO., LTD.
    Inventors: Kazushi Torii, Reiko Nakatsuru, Yasuhisa Nakashima, Katsuyuki Wada, Kunihiko Ishizaki
  • Publication number: 20130175473
    Abstract: Provided is a water-absorbing agent having enhanced performance in both the centrifuge retention capacity and the absorption against pressure (particularly, the vertical diffusion absorption amount) of a water-absorbing resin, and also, a water-absorbing agent which can provide an absorbent core having a large absorption amount in a diaper, having improved diffusibility and liquid permeability, and having a smaller re-wet amount, is provided at low cost. Disclosed is a particulate water-absorbing agent containing a surface-crosslinked polyacrylic acid (salt)-type water-absorbing resin as a main component, and containing at least one spacer selected from a polycation and water-insoluble fine particles, the particulate water-absorbing agent satisfying an free swell capacity (FSC) of 55 to 65 [g/g], an absorption against pressure (AAP—4.83 kPa) of 20 to 30 [g/g], and a vertical diffusion absorption amount under pressure (VDAUP—4.83 kPa) of 30 to 80 g.
    Type: Application
    Filed: September 30, 2011
    Publication date: July 11, 2013
    Applicant: Nippon Shokubai Co., Ltd
    Inventors: Katsuyuki Wada, Yasuhisa Nakashima
  • Publication number: 20120305842
    Abstract: A water absorbing agent of the present invention has an internal crosslinking structure obtained by polymerization of a water-soluble unsaturated monomer. The agent satisfies conditions (a) to (d): (a) the agent contains water-insoluble inorganic particles at an amount of from 10 ppm to 1,900 ppm inclusive; (b) the agent contains 5 mass % or less particles which have such a size that they can pass through a sieve having a mesh opening size of 150 ?m; (c) the agent has an absorbency against a pressure of 4.83 kPa (AAP) of 18 g/g or more; and (d) the water-insoluble inorganic particles reside on a surface of the water absorbing resin or near the surface.
    Type: Application
    Filed: May 9, 2012
    Publication date: December 6, 2012
    Applicant: NIPPON SHOKUBAI CO., LTD.
    Inventors: Kazushi Torii, Hirofumi Shibata, Kazuki Kimura, Yasuhisa Nakashima, Motohiro Imura, Hiroko Ueda, Katsuyuki Wada
  • Patent number: 8198209
    Abstract: A water absorbing agent of the present invention has an internal crosslinking structure obtained by polymerization of a water-soluble unsaturated monomer. The agent satisfies conditions (a) to (d): (a) the agent contains water-insoluble inorganic particles at an amount of from 10 ppm to 1,900 ppm inclusive; (b) the agent contains 5 mass % or less particles which have such a size that they can pass through a sieve having a mesh opening size of 150 ?m; (c) the agent has an absorbency against a pressure of 4.83 kPa (AAP) of 18 g/g or more; and (d) the water-insoluble inorganic particles reside on a surface of the water absorbing resin or near the surface.
    Type: Grant
    Filed: March 20, 2007
    Date of Patent: June 12, 2012
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Kazushi Torii, Hirofumi Shibata, Kazuki Kimura, Yasuhisa Nakashima, Motohiro Imura, Hiroko Ueda, Katsuyuki Wada
  • Patent number: 8026294
    Abstract: An object is to provide a water absorbent resin composition containing a water absorbent resin as a main component, with excellent deodorant property and antimicrobial property without impairing appearance and absorption characteristics of the water absorbent resin. The water absorbent resin composition according to the first aspect includes a water absorbent resin containing a polyacrylic acid (salt)-based water absorbent resin as a main component, and an extract of bamboo and an extract of tea. The water absorbent resin composition according to the second aspect includes a water absorbent resin containing a polyacrylic acid (salt)-based water absorbent resin as a main component, and at least two kinds of compounds selected from a group consisting of hexanoic acid (salt), ethyl butyrate, and 3-methyl-2-cyclopenten-1-one.
    Type: Grant
    Filed: October 10, 2008
    Date of Patent: September 27, 2011
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Katsuyuki Wada, Yasuhisa Nakashima
  • Patent number: 7825169
    Abstract: A water-absorbent composition includes: a specific plant extract; a water-absorbent resin whose surface portion and/or periphery thereof is treated; and/or a water-absorbent resin having a specific property. Specifically, it is preferable to use a water-absorbent resin having three characteristics: (1) a specific neutralization rate, (2) a specific particle diameter, and (3) a specific plant extract. The water-absorbent composition has a superior deodorant performance and an absorbent characteristic when the water-absorbent composition is used (provided) in an absorbing product such as a paper diaper, thereby providing a superior deodorant performance and a superior absorbent characteristic to the foregoing absorbing product.
    Type: Grant
    Filed: May 30, 2003
    Date of Patent: November 2, 2010
    Assignee: Nippon Shokubai Co. Ltd.
    Inventors: Katsuyuki Wada, Hiroko Ueda, Kunihiko Ishizaki, Yoshio Irie, Yasuhisa Nakashima
  • Publication number: 20100240808
    Abstract: An object is to provide a water absorbent resin composition containing a water absorbent resin as a main component, with excellent deodorant property and antimicrobial property without impairing appearance and absorption characteristics of the water absorbent resin. The water absorbent resin composition according to the first aspect includes a water absorbent resin containing a polyacrylic acid (salt)-based water absorbent resin as a main component, and an extract of bamboo and an extract of tea. The water absorbent resin composition according to the second aspect includes a water absorbent resin containing a polyacrylic acid (salt)-based water absorbent resin as a main component, and at least two kinds of compounds selected from a group consisting of hexanoic acid (salt), ethyl butyrate, and 3-methyl-2-cyclopenten-1-one.
    Type: Application
    Filed: October 10, 2008
    Publication date: September 23, 2010
    Applicant: Nippon Shokubai Co., Ltd.
    Inventors: Katsuyuki Wada, Yasuhisa Nakashima
  • Patent number: 7745537
    Abstract: The present invention provides a particulate water absorbing agent for absorbent cores which is excellent in powder conveying property, and achieves sufficient absorption performances for use in absorbent cores in particulate water absorbing agents including a water absorbing resin as a principal component, and which further is suitable for practical applications. In the present invention, characteristics that had not been known conventionally at all, i.e., “permeability potential under pressure (PPUP)” and “frictional charge being a positive charge” of the particulate water absorbing agent are regulated at a time, and furthermore, regulation of the “moisture content of 2 to 10% by weight” is perfected. Also, the particulate water absorbing agent including (A) a water-swelling crosslinked polymer having a constitutional unit derived from an unsaturated monomer containing an acid group and/or a salt thereof; and (B) water fulfills certain requirements.
    Type: Grant
    Filed: April 6, 2006
    Date of Patent: June 29, 2010
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Yasuhisa Nakashima, Toshihiro Takaai, Katsuyuki Wada
  • Publication number: 20090298685
    Abstract: A water absorbing agent of the present invention has an internal crosslinking structure obtained by polymerization of a water-soluble unsaturated monomer. The agent satisfies conditions (a) to (d): (a) the agent contains water-insoluble inorganic particles at an amount of from 10 ppm to 1,900 ppm inclusive; (b) the agent contains 5 mass % or less particles which have such a size that they can pass through a sieve having a mesh opening size of 150 ?m; (c) the agent has an absorbency against a pressure of 4.83 kPa (AAP) of 18 g/g or more; and (d) the water-insoluble inorganic particles reside on a surface of the water absorbing resin or near the surface.
    Type: Application
    Filed: March 20, 2007
    Publication date: December 3, 2009
    Applicant: NIPPON SHOKUBAI CO., LTD.
    Inventors: Kazushi Torii, Hirofumi Shibata, Kazuki Kimura, Yasuhisa Nakashima, Motohiro Imura, Hiroko Ueda, Katsuyuki Wada
  • Publication number: 20090008604
    Abstract: The present invention provides a particulate water absorbing agent for absorbent cores which is excellent in powder conveying property, and achieves sufficient absorption performances for use in absorbent cores in particulate water absorbing agents including a water absorbing resin as a principal component, and which further is suitable for practical applications. In the present invention, characteristics that had not been known conventionally at all, i.e., “permeability potential under pressure (PPUP)” and “frictional charge being a positive charge” of the particulate water absorbing agent are regulated at a time, and furthermore, regulation of the “moisture content of 2 to 10% by weight” is perfected. Also, the particulate water absorbing agent including (A) a water-swelling crosslinked polymer having a constitutional unit derived from an unsaturated monomer containing an acid group and/or a salt thereof; and (B) water fulfills certain requirements.
    Type: Application
    Filed: April 6, 2006
    Publication date: January 8, 2009
    Applicant: NIPPON SHOKUBAI CO., LTD.
    Inventors: Yasuhisa Nakashima, Toshihiro Takaai, Katsuyuki Wada