Abstract: An anion exchange membrane includes a quaternary ammonium salt group in which two methyl groups, and one alkyl group having 3 to 8 carbon atoms are bonded to a nitrogen atom.

Abstract: By performing photograft polymerization of functional monomers such that grafted chains will be introduced from the surface of a polymer base film into its interior without deteriorating its inherent characteristics and also by creating a multiplex crosslinked structure between the grafted chains and the base film under such conditions as to cause preferential radiation-induced crosslinking reaction, there is produced a polymer electrolyte membrane having high enough oxidation resistance and proton conductivity to be suitable for use in fuel cells.

Abstract: A method of producing an electrolyte membrane for use in a fuel cell, including: performing radiation-induced graft polymerization of a vinyl monomer having a nucleophilic functional group selected from an acylvinyl ether derivative, a styrene derivative, and a methacrylic acid derivative, with a polymer substrate having a fluorine-containing polymer, an olefin-containing polymer, or an aromatic polymer; deprotecting an ester bond of a graft chain on the polymer substrate introduced by the radiation-induced graft polymerization; and introducing an alkylethersulfonic acid structure into the nucleophilic functional group of the graft chain thus deprotected, by use of an electrophilic reagent selected from cyclic sulfonic acid ester and alkylhalide sulfonate.

Abstract: An aromatic polymer film substrate, or a grafted aromatic polymer film substrate having a monomer introduced therein as graft chains is irradiated with ionizing radiation to impart a crosslinked structure. The aromatic polymer film substrate or the grafted aromatic polymer film substrate, provided with the crosslinked structure, is directly sulfonated to obtain a crosslinked aromatic polymer electrolyte membrane. The crosslinked aromatic polymer electrolyte membrane has low water uptake, high proton conductivity, low methanol permeability, high chemical stability, and excellent mechanical characteristics.

Abstract: An aromatic polymer film substrate, or a grafted aromatic polymer film substrate having a monomer introduced therein as graft chains is irradiated with ionizing radiation to impart a crosslinked structure. The aromatic polymer film substrate or the grafted aromatic polymer film substrate, provided with the crosslinked structure, is directly sulfonated to obtain a crosslinked aromatic polymer electrolyte membrane. The crosslinked aromatic polymer electrolyte membrane has low water uptake, high proton conductivity, low methanol permeability, high chemical stability, and excellent mechanical characteristics. A method for producing the crosslinked aromatic polymer electrolyte membrane is also provided.

Abstract: An object is to provide an electrolyte membrane that maintains excellent cell characteristics for a long time under high temperature and low water retention, as this is the most important point in fuel cells. A process for producing a polymer electrolyte membrane for fuel cells is provided, which process comprises in sequence: forming graft molecular chains by graft-polymerization of a vinyl silane coupling agent on a polymer film substrate that has phenyl groups capable of holding sulfonic acid groups; introducing sulfonic acid groups into phenyl groups contained in the graft molecular chains; and hydrolyzing and condensing alkoxy groups contained in the graft molecular chains so that a silane crosslinked structure is introduced between the graft molecular chains. A polymer electrolyte membrane produced by the process is also provided.

Abstract: Provision of, and a method for production of, a polymer electrolyte membrane, which is characterized by introducing a vinyl monomer into an aromatic polymer membrane substrate, typified by polyether ether ketone, polyether imide, or polysulfone, as graft chains by graft polymerization, and then chemically converting some of the graft chains or/and part of the aromatic polymer chain into sulfonic groups.

Abstract: A vinyl monomer is graft polymerized on an aromatic hydrocarbon-based polymer film substrate to introduce graft chains into the substrate and thereafter a functional monomer represented by the following formula and having sulfonic acid groups or functional groups capable of conversion to sulfonic acid groups is graft polymerized to introduce the sulfonic acid groups or the functional groups capable of conversion to sulfonic acid groups: where R is an aromatic ring or an aliphatic chain; X is (1) —OH, (2) —OLi, —ONa or —OK, (3) —F or —Cl, or (4) —OCnH2n+1 where n is an integer of 1 to 7. Since the graft chains obtained by graft polymerization of the vinyl monomer can also be utilized as scaffold polymers, the graft polymerizability of the functional monomer to the aromatic hydrocarbon-based polymer film substrate is sufficiently improved to enable the preparation of a polymer electrolyte membrane that excels not only in proton conductivity and mechanical strength but also in dimensional stability.

Abstract: An aromatic polymer film substrate, or a grafted aromatic polymer film substrate having a monomer introduced therein as graft chains is irradiated with ionizing radiation to impart a crosslinked structure. The aromatic polymer film substrate or the grafted aromatic polymer film substrate, provided with the crosslinked structure, is directly sulfonated to obtain a crosslinked aromatic polymer electrolyte membrane. The crosslinked aromatic polymer electrolyte membrane has low water uptake, high proton conductivity, low methanol permeability, high chemical stability, and excellent mechanical characteristics. A method for producing the crosslinked aromatic polymer electrolyte membrane is also provided.

Abstract: Polymer electrolyte membranes for use in fuel cells are produced by first graft polymerizing acrylic acid derivatives or vinylketone derivatives as monomers on polymer substrates and by then performing selective conversion to a sulfonic acid group of hydrogen atoms on the carbon atom adjacent to the carbonyl in the ketone or carboxyl group on the graft chains.

Abstract: By performing photograft polymerization of functional monomers such that grafted chains will be introduced from the surface of a polymer base film into its interior without deteriorating its inherent characteristics and also by creating a multiplex crosslinked structure between the grafted chains and the base film under such conditions as to cause preferential radiation-induced crosslinking reaction, there is produced a polymer electrolyte membrane having high enough oxidation resistance and proton conductivity to be suitable for use in fuel cells.

Abstract: A reflection-type liquid crystal display device, having a pair of substrates, at least one of which is transparent, a liquid crystal layer sandwiched between the pair of substrates, a light reflector section provided between the liquid crystal layer and one of the pair of substrates, and a polymeric medium layer with fine silver particles precipitated on the surface, as formed at the light reflector section. The reflection-type liquid crystal display is produced by the steps of: applying a mixture containing monovalent silver and a photosensitive polymeric medium; exposing the mixture to light, thereby photolithographically forming a light reflector layer of desired pattern; heating the light reflector layer under a predetermined temperature condition, thereby precipitating fine silver particles on the surface of the light reflector layer; and confronting a transparent substrate with the light reflector layer-formed substrate, and sandwiching a liquid crystal layer between the substrates.

Abstract: A liquid crystal display device having a pair of substrates, a liquid crystal layer, a group of electrodes for applying to the liquid crystal layer an electric field substantially parallel to the substrate surface, and a plurality of active elements connected to the electrodes, the group of electrodes and active elements being formed on one of the pair of substrates. An alignment control film is formed between the liquid crystal layer and at least one of the pair of substrates and is made from polyamic acid obtained by reacting a diamine with an acid anhydride.

Abstract: A normally closed liquid crystal display device using an in-plane switching mode prevented from light leakage caused by spacer beads and having a high contrast ratio can be produced by making a pretilt angle between an alignment control film and liquid crystals 4° or less and controlling a light leakage centering the spacer in 4-divided shapes; or by placing a film provided with a liquid crystal alignment controlling function by irradiation with polarized light between the spacer and a liquid crystal layer, the spacer being present in a pair of substrates.

Abstract: A normally closed liquid crystal display device using an in-plane switching mode prevented from light leakage caused by spacer beads and having a high contrast ratio can be produced by making a pretilt angle between an alignment control film and liquid crystals 4° or less and controlling a light leakage centering the spacer in 4-divided shapes; or by placing a film provided with a liquid crystal alignment controlling function by irradiation with polarized light between the spacer and a liquid crystal layer, the spacer being present in a pair of substrates.

Abstract: A normally closed liquid crystal display device using an in-plane switching mode prevented from light leakage caused by spacer beads and having a high contrast ratio can be produced by making a pretilt angle between an alignment control film and liquid crystals 4° or less and controlling a light leakage centering the spacer in 4-divided shapes; or by placing a film provided with a liquid crystal alignment controlling function by irradiation with polarized light between the spacer and a liquid crystal layer, the spacer being present in a pair of substrates.

Abstract: A photosensitive composition comprising a polyimide precursor, a photosensitive material having a structure represented by the following formula wherein A1 is an atom belonging to Group VI of the periodic table, in the molecule thereof and/or a photosensitive material having a structure represented by the following formula: wherein A2 is O, S or N atom, in the molecule thereof is suitable for formation of a positive tone pattern excellent in heat resistance, and applicable to electronic devices.

Abstract: A highly reliable positive type photosensitive resin composition composed of diamine having a carboxyl group as a structural unit, which can be developed with an alkaline aqueous solution, comprising polyamic acid ester having hydrophobic group, o-quinonediazidesulfonyl amide compound, and/or o-quinonediazidesulfonyl amide sulfonic ester compound, and electronic devices using the same. A polyamide film having preferable positive type relief patterns, of which the unexposed portion is not corroded, can be obtained.