Patents by Inventor Yojiro Hotta
Yojiro Hotta has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 9897932Abstract: A toner comprising: a toner particle containing a toner base particle containing a binder resin and a colorant, and a resin particle fixed to a surface of the toner base particle; and an inorganic fine particle A, wherein the surface of the toner particle has protruded portions originating in the resin particle, an average length (D) of long sides of the protruded portions is 50 nm to 300 nm, an average Height (H) of the protruded portions is 25 nm to 250 nm, the average long-side length and the average height of the protruded portions satisfies a specific relationship, and an average value of a compactness of the inorganic fine particle A is 0.40 to 0.80, and the attachment rate of the inorganic fine particles A is 0.1% to 5.0% by area.Type: GrantFiled: January 31, 2017Date of Patent: February 20, 2018Assignee: CANON KABUSHIKI KAISHAInventors: Yojiro Hotta, Kazuo Terauchi, Tsuneyoshi Tominaga, Akane Masumoto, Takuya Mizuguchi, Motohide Shiozawa, Takeshi Naka, Masami Fujimoto, Shingo Ito, Kousuke Yamamoto, Yasukazu Ikami
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Patent number: 9778583Abstract: A toner having compatibility between transfer properties and cleaning properties is provided. A toner wherein a fine particle A containing a primary particle having a number average particle diameter (D1) of 80 nm or more and 400 nm or less is present on the surface of a toner particle at a coverage ratio of 5 to 40%, a fixing rate of 30 to 90% by mass, and a variation coefficient of 0.1 to 0.5 in a region of 0.5 ??m2.Type: GrantFiled: August 3, 2015Date of Patent: October 3, 2017Assignee: CANON KABUSHIKI KAISHAInventors: Kazuo Terauchi, Yojiro Hotta, Takeshi Naka, Motohide Shiozawa, Shohei Tsuda, Masami Fujimoto
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Patent number: 9772570Abstract: Provided is a toner having good endurance stability and good low-temperature fixability in high-speed printing, and having good resistance to the adhesion of printed paper. The toner is a magnetic toner having, on the surface of toner particle containing a binder resin and an ester compound as a releasing agent, inorganic fine particle “a” and organic-inorganic composite fine particle having a volumetric specific heat of from 2,900 kJ/(m3·° C.) to 4,200 kJ/(m3·° C.), in which a coverage A of the surface of the toner particle with the inorganic fine particle “a” is 45.0% or more and 70.0% or less.Type: GrantFiled: July 29, 2015Date of Patent: September 26, 2017Assignee: CANON KABUSHIKI KAISHAInventors: Shohei Tsuda, Yojiro Hotta, Koji Nishikawa, Masami Fujimoto, Katsuhisa Yamazaki
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Publication number: 20170227864Abstract: A toner comprising: a toner particle containing a toner base particle containing a binder resin and a colorant, and a resin particle fixed to a surface of the toner base particle; and an inorganic fine particle A, wherein the surface of the toner particle has protruded portions originating in the resin particle, an average length (D) of long sides of the protruded portions is 50 nm to 300 nm, an average Height (H) of the protruded portions is 25 nm to 250 nm, the average long-side length and the average height of the protruded portions satisfies a specific relationship, and an average value of a compactness of the inorganic fine particle A is 0.40 to 0.80, and the attachment rate of the inorganic fine particles A is 0.1% to 5.0% by area.Type: ApplicationFiled: January 31, 2017Publication date: August 10, 2017Inventors: Yojiro Hotta, Kazuo Terauchi, Tsuneyoshi Tominaga, Akane Masumoto, Takuya Mizuguchi, Motohide Shiozawa, Takeshi Naka, Masami Fujimoto, Shingo Ito, Kousuke Yamamoto, Yasukazu Ikami
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Patent number: 9715188Abstract: The toner comprising a toner particle containing a binder resin and a colorant, an iron oxide particle and an organic-inorganic composite fine particle, wherein the organic-inorganic composite fine particle comprises a vinyl resin particle, and inorganic fine particles which are embedded in the vinyl resin particle, and at least a part of which is exposed at surface of the organic-inorganic composite fine particle; the organic-inorganic composite fine particle has convexes derived from the inorganic fine particles, and wherein: a coverage ratio of the surface of the organic-inorganic composite fine particle with the inorganic fine particle is 20-70%; and the content of the iron oxide particle present on a surface of the toner particle is 0.1-5.0 mass % based on the mass of the toner particle.Type: GrantFiled: July 30, 2014Date of Patent: July 25, 2017Assignee: CANON KABUSHIKI KAISHAInventors: Kazuo Terauchi, Koji Nishikawa, Shohei Tsuda, Yojiro Hotta, Katsuhisa Yamazaki, Takayuki Itakura, Takeshi Naka, Motohide Shiozawa
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Patent number: 9588450Abstract: Provided is a magnetic toner in which enhancement of initial transfer efficiency and transfer efficiency that is stable during a long-term use are achieved by simultaneously suppressing the friction force between the toner and a drum and the cohesion between toners, and further the degradation in chargeability and fluidity caused by the deterioration of the toner. The magnetic toner includes: a magnetic toner particle; a first external additive; and a second external additive. The first external additive includes an organic-inorganic composite fine particle, a plurality of convexes derived from an inorganic fine particle being present on a surface of the organic-inorganic composite fine particle, and has a number-average particle diameter of 50 nm or more and 500 nm or less. The second external additive includes a silica fine particle and has a number-average particle diameter of 5 nm or more and 30 nm or less. A shear load calculated from a rotation torque is 0.50 kPa or more and 2.Type: GrantFiled: July 30, 2014Date of Patent: March 7, 2017Assignee: CANON KABUSHIKI KAISHAInventors: Shohei Tsuda, Koji Nishikawa, Katsuhisa Yamazaki, Yojiro Hotta, Kazuo Terauchi, Motohide Shiozawa, Takeshi Naka, Takuya Mizuguchi, Takayuki Itakura
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Patent number: 9575425Abstract: A toner is provided including large particle-diameter external additives with sweep to the concaves of a toner particle suppressed, so that the large particle-diameter external additives function as spacer particles for a long period. The toner includes toner particles which contain a binder resin and magnetic material, and organic-inorganic composite fine particles having a structure including inorganic fine particles embedded in a vinyl resin particle. The presence state of the magnetic material on the toner particle surface satisfies specific conditions and the presence state of the organic-inorganic composite fine particles on the toner surface satisfies specific conditions.Type: GrantFiled: July 29, 2014Date of Patent: February 21, 2017Assignee: CANON KABUSHIKI KAISHAInventors: Takeshi Naka, Kazuo Terauchi, Motohide Shiozawa, Yojiro Hotta, Shohei Tsuda, Katsuhisa Yamazaki, Koji Nishikawa, Takayuki Itakura
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Publication number: 20160202624Abstract: Provided is a toner, including: a toner particle; and an organic-inorganic composite fine particle on a surface of the toner particle, in which the organic-inorganic composite fine particle includes: a resin fine particle; and an inorganic fine particle embedded in the resin fine particle, and part of which is exposed to a surface of the composite fine particle, and in which the composite fine particle satisfies the following relationships: (i) in viscoelasticity measurement of the composite fine particle, when the loss elastic modulus thereof at a temperature T (° C.) is represented by G?T [dN/m2], a change ratio d(Log(G?T))/dT of a common logarithm of the loss elastic modulus has a minimum in a temperature range of from 60° C. to 150° C., and the minimum is less than ?0.10; and (ii) the loss elastic modulus (G?180) thereof at a temperature of 180° C. is 1.0×104 dN/m2 or more and 1.0×107 dN/m2 or less.Type: ApplicationFiled: December 18, 2015Publication date: July 14, 2016Inventors: Koji Nishikawa, Shuhei Moribe, Daisuke Yoshiba, Shotaro Nomura, Kosuke Fukudome, Hiroki Akiyama, Yojiro Hotta, Katsuhisa Yamazaki
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Publication number: 20160202621Abstract: A toner is provided, where good cleanability is exhibited, abrasion variations of the photo conductor surface is reduced, and contamination of a charge member is reduced. The toner includes toner particles and organic-inorganic composite fine particles on the toner particle surfaces, wherein each of the organic-inorganic composite fine particles is a particle in which inorganic fine particles are exposed at the surfaces of vinyl based resin particles in such a way that convex portions derived from the inorganic fine particles are formed on the surfaces, the average circularity of the toner is 0.960 or more, and the absolute value Q of the amount of triboelectricity of the toner measured by a two-component method and the electrostatic adhesion F of the toner satisfy 0.003?F/Q2?0.040.Type: ApplicationFiled: July 30, 2014Publication date: July 14, 2016Inventors: Yojiro Hotta, Shohei Tsuda, Taiji Katsura, Masaharu Miura, Yoshinobu Baba, Takayuki Itakura
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Publication number: 20160091809Abstract: Provided is a magnetic toner in which enhancement of initial transfer efficiency and transfer efficiency that is stable during a long-term use are achieved by simultaneously suppressing the friction force between the toner and a drum and the cohesion between toners, and further the degradation in chargeability and fluidity caused by the deterioration of the toner. The magnetic toner includes: a magnetic toner particle; a first external additive; and a second external additive. The first external additive includes an organic-inorganic composite fine particle, a plurality of convexes derived from an inorganic fine particle being present on a surface of the organic-inorganic composite fine particle, and has a number-average particle diameter of 50 nm or more and 500 nm or less. The second external additive includes a silica fine particle and has a number-average particle diameter of 5 nm or more and 30 nm or less. A shear load calculated from a rotation torque is 0.50 kPa or more and 2.Type: ApplicationFiled: July 30, 2014Publication date: March 31, 2016Inventors: Shohei Tsuda, Koji Nishikawa, Katsuhisa Yamazaki, Yojiro Hotta, Kazuo Terauchi, Motohide Shiozawa, Takeshi Naka, Takuya Mizuguchi, Takayuki Itakura
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Publication number: 20160070192Abstract: The toner comprising a toner particle containing a binder resin and a colorant, an iron oxide particle and an organic-inorganic composite fine particle, wherein the organic-inorganic composite fine particle comprises a vinyl resin particle, and inorganic fine particles which are embedded in the vinyl resin particle, and at least a part of which is exposed at surface of the organic-inorganic composite fine particle; the organic-inorganic composite fine particle has convexes derived from the inorganic fine particles, and wherein: a coverage ratio of the surface of the organic-inorganic composite fine particle with the inorganic fine particle is 20-70%; and the content of the iron oxide particle present on a surface of the toner particle is 0.1-5.0 mass % based on the mass of the toner particle.Type: ApplicationFiled: July 30, 2014Publication date: March 10, 2016Inventors: Kazuo Terauchi, Koji Nishikawa, Shohei Tsuda, Yojiro Hotta, Katsuhisa Yamazaki, Takayuki Itakura, Takeshi Naka, Motohide Shiozawa
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Publication number: 20160041482Abstract: A toner having compatibility between transfer properties and cleaning properties is provided. A toner wherein a fine particle A containing a primary particle having a number average particle diameter (D1) of 80 nm or more and 400 nm or less is present on the surface of a toner particle at a coverage ratio of 5 to 40%, a fixing rate of 30 to 90% by mass, and a variation coefficient of 0.1 to 0.5 in a region of 0.5 ??m2.Type: ApplicationFiled: August 3, 2015Publication date: February 11, 2016Inventors: Kazuo Terauchi, Yojiro Hotta, Takeshi Naka, Motohide Shiozawa, Shohei Tsuda, Masami Fujimoto
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Publication number: 20160041484Abstract: Provided is a toner having good endurance stability and good low-temperature fixability in high-speed printing, and having good resistance to the adhesion of printed paper. The toner is a magnetic toner having, on the surface of toner particle containing a binder resin and an ester compound as a releasing agent, inorganic fine particle “a” and organic-inorganic composite fine particle having a volumetric specific heat of from 2,900 kJ/(m3·° C.) to 4,200 kJ/(m3·° C.), in which a coverage A of the surface of the toner particle with the inorganic fine particle “a” is 45.0% or more and 70.0% or less.Type: ApplicationFiled: July 29, 2015Publication date: February 11, 2016Inventors: Shohei Tsuda, Yojiro Hotta, Koji Nishikawa, Masami Fujimoto, Katsuhisa Yamazaki
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Patent number: 9141012Abstract: The toner includes toner particles containing a polyester resin A, a polyester resin B and a colorant, the polyester resin A has a polyester portion including a segment capable of forming a crystal structure and a crystal nucleating agent segment, which is bonded to an end of the polyester portion, and the polyester resin B is a resin which is free of any segments capable of forming a crystal structure, the polyester resin B has a weight average molecular weight Mwb by GPC of a THF soluble matter of 3000 or more and 100000 or less, and an SP value Sa ((cal/cm3)1/2) of the polyester portion of the polyester resin A and an SP value Sb ((cal/cm3)1/2) of the polyester resin B satisfy the following relationships: 9.00?Sa?10.50 ?0.40?Sb?Sa?0.80.Type: GrantFiled: December 12, 2013Date of Patent: September 22, 2015Assignee: CANON KABUSHIKI KAISHAInventors: Shuhei Moribe, Kosuke Fukudome, Satoshi Mita, Kazuo Terauchi, Yojiro Hotta, Tetsuya Ida
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Patent number: 9134637Abstract: The toner of the present invention includes toner particles containing polyester resins A and B and a colorant, the A has a polyester portion including a portion capable of forming a crystal structure and a crystal nucleating agent portion, which is bonded to an end of the polyester portion, the B is free from any portions capable of forming a crystal structure, in a chart obtained as a result of GPC of a THF-soluble matter of the B, a ratio of a component having a molecular weight of 1500 or less in the B is 5.0 to 15.0% by area, and when an SP value of the polyester portion of the A is represented by Sa ((cal/cm3)1/2) and an SP value of the B is represented by Sb ((cal/cm3)1/2), the SP values Sa and Sb satisfy the following relationships: 9.50?Sa?11.00 ?0.65?Sb?Sa?0.70.Type: GrantFiled: December 11, 2013Date of Patent: September 15, 2015Assignee: CANON KABUSHIKI KAISHAInventors: Yojiro Hotta, Shuhei Moribe, Kosuke Fukudome, Satoshi Mita, Kazuo Terauchi, Tetsuya Ida
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Patent number: 9116448Abstract: Provided is a toner exhibiting satisfactory fixability even in high-speed fixing process involving a double-sided printing mechanism, keeping stable toner image even after a conveyance step, and doesn't cause curling to a fixing roller even in thin paper. In a toner including toner particles, each of which contains polyester resins A and B, a coloring agent, and a resin composition C, the resin A includes a crystal nucleating agent bonded to a polyester molecular chain including a moiety capable of forming a crystalline structure. The resin B doesn't include a moiety capable of forming a crystalline structure. The composition C is obtained by copolymerizing a vinyl-based resin component with a polyolefin resin component. SP values the resin A, the resin B, the agent, the polyolefin component, and the vinyl-based component satisfy the particular relationships.Type: GrantFiled: June 19, 2013Date of Patent: August 25, 2015Assignee: CANON KABUSHIKI KAISHAInventors: Kazuo Terauchi, Shuhei Moribe, Kosuke Fukudome, Satoshi Mita, Yojiro Hotta, Tetsuya Ida
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Patent number: 9046800Abstract: Provided is the following magnetic carrier. The magnetic carrier maintains high developing performance even when the number of sheets to be output is large. Its charge-providing performance hardly reduces even when toner or an external additive is spent on the magnetic carrier. In addition, the magnetic carrier is strong in resistance against standing. The magnetic carrier includes a magnetic carrier core and a resinous coating layer formed on a surface of the magnetic carrier core, in which the resinous coating layer contains a resin composition and silica-alumina composite particles.Type: GrantFiled: April 25, 2012Date of Patent: June 2, 2015Assignee: CANON KABUSHIKI KAISHAInventors: Yojiro Hotta, Naoki Okamoto, Kazuo Terauchi, Ryuichiro Matsuo, Tetsuya Ida
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Patent number: 9040216Abstract: Provided is a toner satisfying low-temperature fixing performance and long-term storage stability of fixed images. Further, provided is a toner capable of obtaining toner images excellent in long-term storage stability irrespective of use environments even in the case where images are formed by a high-speed fixing system having low internal pressure of a fixing nip of a fixing device and a high printing speed. The toner includes toner particles containing a binder resin having a resin A and B, and a coloring agent, in which the resin A includes a resin including a moiety capable of forming a crystalline structure; the resin B includes a resin free of a moiety capable of forming a crystalline structure; and ?Hhigh and ?Hlow satisfy the expressions: 2??Hhigh?45 3[%]?{(?Hlow??Hhigh)/?Hlow}×100?70[%] where ?Hhigh and ?Hlow represent a heat of melting derived from the binder resin measured at a temperature increase speed of 100° C./min and 10° C./min, respectively.Type: GrantFiled: December 3, 2013Date of Patent: May 26, 2015Assignee: CANON KABUSHIKI KAISHAInventors: Kosuke Fukudome, Shuhei Moribe, Satoshi Mita, Kazuo Terauchi, Yojiro Hotta, Tetsuya Ida
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Publication number: 20150125790Abstract: A magnetic toner having a toner particle containing a binder resin and a magnetic member, a first inorganic fine particle and an organic-inorganic composite particle on the surface of the toner particle, wherein the organic-inorganic composite particle i) has a structure in which a second inorganic fine particle is embedded in a resin particle, and ii) is contained in an amount of 0.5 mass % or more and 3.0 mass % or less based on the mass of the toner; the first inorganic fine particle contains an inorganic oxide fine particle selected from the group consisting of a silica fine particle, a titanium oxide fine particle and an alumina fine particle; has a number average particle diameter (D1) of 5 nm or more and 25 nm or less, and contains the silica fine particle in an amount of 85 mass % or more based on the inorganic oxide fine particle.Type: ApplicationFiled: January 13, 2015Publication date: May 7, 2015Inventors: Yojiro Hotta, Koji Nishikawa, Shohei Tsuda, Motohide Shiozawa, Takeshi Naka, Kazuo Terauchi, Katsuhisa Yamazaki, Takayuki Itakura
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Publication number: 20150037719Abstract: A toner is provided including large particle-diameter external additives with sweep to the concaves of a toner particle suppressed, so that the large particle-diameter external additives function as spacer particles for a long period. The toner includes toner particles which contain a binder resin and magnetic material, and organic-inorganic composite fine particles having a structure including inorganic fine particles embedded in a vinyl resin particle. The presence state of the magnetic material on the toner particle surface satisfies specific conditions and the presence state of the organic-inorganic composite fine particles on the toner surface satisfies specific conditions.Type: ApplicationFiled: July 29, 2014Publication date: February 5, 2015Inventors: Takeshi Naka, Kazuo Terauchi, Motohide Shiozawa, Yojiro Hotta, Shohei Tsuda, Katsuhisa Yamazaki, Koji Nishikawa, Takayuki Itakura