Abstract: Provided is a thermoplastic resin composition which includes: a graft copolymer including a C4 to C10 alkyl (meth)acrylate-based monomer unit, a styrene-based monomer unit, and a vinyl cyan-based monomer unit; a first styrene-based copolymer including a C1 to C3 alkyl-substituted styrene-based monomer unit and a vinyl cyan-based monomer unit; and a second styrene-based copolymer including an unsubstituted styrene-based monomer unit and a vinyl cyan-based monomer unit. The thermoplastic resin composition is remarkably excellent in heat resistance, chemical resistance, and appearance characteristics while maintaining basic properties.

Abstract: Provided is a thermoplastic resin composition which includes: a graft copolymer prepared by graft-polymerizing an aromatic vinyl-based monomer and a vinyl cyan-based monomer onto an acrylic rubber polymer; a first matrix copolymer including a C1-C3 alkyl (meth)acrylate-based monomer unit, an aromatic vinyl-based monomer unit and a vinyl cyan-based monomer unit; a second matrix copolymer including a C1-C3 alkyl (meth)acrylate-based monomer unit, an aromatic vinyl-based monomer unit and a vinyl cyan-based monomer unit; and an additive including a polymer including a C1-C3 alkyl (meth)acrylate-based monomer unit, wherein the first matrix copolymer and the second matrix copolymer have different weight-average molecular weights, specifically, a thermoplastic resin composition which allows high gloss, high hardness, high weather resistance and reduced whitening to be realized.

Abstract: The present invention relates to a method of preparing an ASA graft copolymer, a method of preparing a thermoplastic resin composition including the ASA graft copolymer, and a method of manufacturing a molded article using the thermoplastic resin composition.

Abstract: Provided is a thermoplastic resin composition which includes: a graft copolymer prepared by graft-polymerizing an aromatic vinyl-based monomer and a vinyl cyan-based monomer onto an acrylic rubber polymer having an average particle diameter of 50.0 to 90.0 nm; a matrix copolymer including a C1-C3 alkyl (meth)acrylate-based monomer unit, an aromatic vinyl-based monomer unit and a vinyl cyan-based monomer unit; and an additive including a polymer including a C1-C3 alkyl (meth)acrylate-based monomer unit, specifically, a thermoplastic resin composition which has improved properties in terms of elongation, processability, weather resistance, colorability, hardness, chemical resistance, scratch resistance, a whitening phenomenon, surface gloss and appearance quality while having excellent basic properties.

Abstract: The present disclosure relates to an economical method of preparing a resin composition including a polyalkylene carbonate with improved thermal stability and processability. More specifically, the method of preparing a resin composition includes the steps of polymerizing carbon dioxide and an epoxide compound in the presence of a zinc-based catalyst and a solvent, recovering monomers, removing the catalyst and recovering raw materials, solution-blending with a thermostable resin to improve the thermal stability and processability, and removing the solvent and byproducts from the reaction mixture by using an agitated flash drum and an extrusion or kneader-type devolatilizer.

Abstract: The present invention relates to a thermoplastic resin composition having excellent weather resistance, according to the present invention, the thermoplastic resin composition has excellent weather resistance, gloss, and impact resistance, and thus may be suitable for use as exterior materials for structures, such as siding and window frames.

Abstract: The present invention relates to a thermoplastic resin composition, including a first graft copolymer including an alkyl (meth)acrylate-based polymer-derived unit, an aromatic vinyl-based monomer-derived unit, and a vinyl cyanide-based monomer-derived unit; a copolymer including an aromatic vinyl-based monomer-derived unit and a vinyl cyanide-based monomer-derived unit; a polyester-based elastomer; and a phthalate-based plasticizer.

Abstract: The present invention relates to a thermoplastic resin composition, a method of preparing the same, and a molded part manufactured using the same. More specifically, the present invention provides a thermoplastic resin composition having excellent mechanical properties, such as tensile strength and impact strength, and weather resistance while having low gloss characteristics, a method of preparing the same, and a molded part manufactured using the same. According to the present invention, the thermoplastic resin composition includes an ASA graft copolymer having a core-shell structure having an average particle diameter of 0.05 to 1 ?m, an aromatic vinyl compound-vinyl cyanide compound copolymer, and an epoxy group-containing copolymer having a weight average molecular weight of 2,000 to 8,000 g/mol in specific amounts.

Abstract: A thermoplastic resin composition with low gloss and improved colorability, pencil hardness and wear resistance has (A) 5 to 35% by weight of a first graft copolymer having an average particle diameter of 50 to 150 nm and containing acrylate rubber as a core; (B) 10 to 40% by weight of a second graft copolymer having an average particle diameter of more than 150 nm and 800 nm or less and containing acrylate rubber as a core; (C) 5 to 15% by weight of an aromatic vinyl compound-vinyl cyanide compound copolymer having a weight average molecular weight of 70,000 to 130,000 g/mol; (D) 20 to 50% by weight of an aromatic vinyl compound-(meth)acrylate compound copolymer having a weight average molecular weight of 65,000 to 100,000 g/mol; and (E) 0.1 to 7% by weight of a syndiotactic polystyrene resin.

Abstract: Provided is a thermoplastic resin composition including: a first copolymer including an acrylic rubber-based graft copolymer and an emulsifier including a salt of a compound represented by Chemical Formula 1; a second copolymer including a unit derived from an alkyl acrylate-based monomer and a unit derived from an alkyl methacrylate-based monomer; and a third copolymer including a unit derived from an aromatic vinyl-based monomer and a unit derived from a vinyl cyan-based monomer.

Abstract: The present invention relates to a production method of polyalkylene carbonate particles capable of precipitating and separating resin particles from a polyalkylene carbonate suspension obtained through polymerization of an epoxide and carbon dioxide. According to the present invention, the production method is capable of obtaining a polyalkylene carbonate resin having excellent workability with a high yield and a low energy cost while reducing a scale of a facility, a processing time, and a wastewater amount, as compared to conventional methods such as a flash separation method.

Abstract: A thermoplastic resin composition with low gloss and improved colorability, pencil hardness and wear resistance has (A) 5 to 35% by weight of a first graft copolymer having an average particle diameter of 50 to 150 nm and containing acrylate rubber as a core; (B) 10 to 40% by weight of a second graft copolymer having an average particle diameter of more than 150 nm and 800 nm or less and containing acrylate rubber as a core; (C) 5 to 15% by weight of an aromatic vinyl compound-vinyl cyanide compound copolymer having a weight average molecular weight of 70,000 to 130,000 g/mol; (D) 20 to 50% by weight of an aromatic vinyl compound-(meth)acrylate compound copolymer having a weight average molecular weight of 65,000 to 100,000 g/mol; and (E) 0.1 to 7% by weight of a syndiotactic polystyrene resin.

Abstract: The present invention relates to a method of preparing an ASA graft copolymer, a method of preparing a thermoplastic ASA resin composition including the same, and a method of preparing an ASA molded part, and more particularly, to a method of preparing a multilayered ASA graft copolymer including a step of preparing seeds, cores, and shells. According to the method, since a multifunctional carboxylic acid having 20 or more carbon atoms or a salt thereof is introduced as an emulsifier, the content of the emulsifier remaining in a resin may be reduced, thereby providing an ASA resin having excellent thermal stability and appearance characteristics while the inherent physical properties thereof, such as impact resistance and weather resistance, are maintained.

Abstract: A method of preparing a polyalkylene carbonate resin is provided. More particularly, a method of preparing a polyalkylene carbonate resin capable of preventing polymer degradation and improving physical properties and quality of a final resin product, in which, after polymerization of polyalkylene carbonate, by-products are removed by using a large amount of water to purify a reaction mixture, and in a subsequence process of removing a catalyst residue, a primary purification method is conducted by using a filter so that a content of the catalyst in the reaction mixture is less than 1% by weight, is provided.

Abstract: The present invention relates to a thermoplastic resin composition having excellent weather resistance, according to the present invention, the thermoplastic resin composition has excellent weather resistance, gloss, and impact resistance, and thus may be suitable for use as exterior materials for structures, such as siding and window frames.

Abstract: The present invention relates to a thermoplastic resin composition, a method of preparing the same, and a molded part manufactured using the same. More specifically, the present invention provides a thermoplastic resin composition having excellent mechanical properties, such as tensile strength and impact strength, and weather resistance while having low gloss characteristics, a method of preparing the same, and a molded part manufactured using the same. According to the present invention, the thermoplastic resin composition includes an ASA graft copolymer having a core-shell structure having an average particle diameter of 0.05 to 1 ?m, an aromatic vinyl compound-vinyl cyanide compound copolymer, and an epoxy group-containing copolymer having a weight average molecular weight of 2,000 to 8,000 g/mol in specific amounts.

Abstract: The present invention relates to a method of preparing an ASA graft copolymer, a method of preparing a thermoplastic ASA resin composition including the same, and a method of preparing an ASA molded part, and more particularly, to a method of preparing a multilayered ASA graft copolymer including a step of preparing seeds, cores, and shells. According to the method, since a multifunctional carboxylic acid having 20 or more carbon atoms or a salt thereof is introduced as an emulsifier, the content of the emulsifier remaining in a resin may be reduced, thereby providing an ASA resin having excellent thermal stability and appearance characteristics while the inherent physical properties thereof, such as impact resistance and weather resistance, are maintained.

Abstract: The present disclosure relates to an economical method of preparing a resin composition including a polyalkylene carbonate with improved thermal stability and processability. More specifically, the method of preparing a resin composition includes the steps of polymerizing carbon dioxide and an epoxide compound in the presence of a zinc-based catalyst and a solvent, recovering monomers, removing the catalyst and recovering raw materials, solution-blending with a thermostable resin to improve the thermal stability and processability, and removing the solvent and byproducts from the reaction mixture by using an agitated flash drum and an extrusion or kneader-type devolatilizer.

Abstract: The present invention relates to a production method of polyalkylene carbonate particles capable of precipitating and separating resin particles from a polyalkylene carbonate suspension obtained through polymerization of an epoxide and carbon dioxide. According to the present invention, the production method is capable of obtaining a polyalkylene carbonate resin having excellent workability with a high yield and a low energy cost while reducing a scale of a facility, a processing time, and a wastewater amount, as compared to conventional methods such as a flash separation method.

Abstract: A method of preparing a polyalkylene carbonate resin is provided. More particularly, a method of preparing a polyalkylene carbonate resin capable of preventing polymer degradation and improving physical properties and quality of a final resin product, in which, after polymerization of polyalkylene carbonate, by-products are removed by using a large amount of water to purify a reaction mixture, and in a subsequence process of removing a catalyst residue, a primary purification method is conducted by using a filter so that a content of the catalyst in the reaction mixture is less than 1% by weight, is provided.