Abstract: The present invention relates to an alkyl acrylate compound-vinyl cyanide compound-aromatic vinyl compound graft copolymer including a seed prepared by polymerizing one or more compounds selected from the group consisting of an alkyl acrylate compound, an aromatic vinyl compound, and a vinyl cyanide compound and a multifunctional crosslinking agent; a core formed to surround the seed and prepared by polymerizing an alkyl acrylate compound and a multifunctional crosslinking agent; and a graft shell formed to surround the core and prepared by polymerizing an aromatic vinyl compound and a vinyl cyanide compound, wherein the multifunctional crosslinking agent has a weight average molecular weight of 600 to 1,400 g/mol, a method of preparing the alkyl acrylate compound-vinyl cyanide compound-aromatic vinyl compound graft copolymer, and a thermoplastic resin composition including the alkyl acrylate compound-vinyl cyanide compound-aromatic vinyl compound graft copolymer.

Abstract: The present invention provides a graft copolymer comprising (A) a seed comprising units derived from an alkyl methacrylate monomer; (B) a core formed on the seed and comprising units derived from an alkyl acrylate monomer; and (C) a shell formed on the core and comprising units derived from one or more one or more selected from the group consisting of an aromatic vinyl-based monomer, a vinyl cyanide-based monomer and an alkyl methacrylate monomer, wherein an average particle diameter of the core is 40 to 90 nm, and a graft ratio of the shell is 10 to 30%, and a thermoplastic resin composition and a thermoplastic resin molded article including the same.

Abstract: A roof rack mounted on a roof panel of a vehicle includes a main body including a rail that extends along a lengthwise direction and forms the main body and support parts provided on opposite longitudinal end portions of the rail in the lengthwise direction, a hollow profile that extends along the lengthwise direction of the rail and that is integrally formed inside the rail, and a cap mounted on at least one of opposite longitudinal end portions of the hollow profile or disposed inside the main body.

Abstract: Provided is a thermoplastic resin composition including: a first copolymer including an acrylic rubber-based graft copolymer and an emulsifier including an acid salt; a second copolymer including a unit derived from an alkyl acrylate-based monomer and a unit derived from an alkyl methacrylate-based monomer; and a third copolymer including a unit derived from an aromatic vinyl-based monomer and a unit derived from a vinyl cyan-based monomer.

Abstract: The present invention relates to a method of preparing a graft copolymer powder, which includes: preparing a seed by adding one or more selected from the group consisting of an alkyl (meth)acrylate-based monomer, an aromatic vinyl-based monomer and a vinyl cyan-based monomer to a reactor and carrying out polymerization; preparing a core in the presence of the seed by adding an alkyl (meth)acrylate-based monomer and carrying out polymerization; and preparing a graft copolymer latex in the presence of the core by adding an aromatic vinyl-based monomer and a vinyl cyan-based monomer and carrying out polymerization; adding an alkyl methacrylate-based polymer to the graft copolymer latex and carrying out coagulation, and more particularly, to a method of preparing a graft copolymer powder that is excellent in weather resistance, fluidity, mechanical properties, surface gloss and appearance quality.

Abstract: Provided is a thermoplastic resin composition which includes: a first graft copolymer including a C4 to C10 alkyl (meth)acrylate-based monomer unit, a C1 to C3 alkyl-substituted styrene-based monomer unit, and a vinyl cyan-based monomer unit; a second graft copolymer including a C4 to C10 alkyl (meth)acrylate-based monomer unit, an alkyl-unsubstituted styrene-based monomer unit, and a vinyl cyan-based monomer unit; a first styrene-based copolymer including a C1 to C3 alkyl-substituted styrene-based monomer unit and a vinyl cyan-based monomer unit; a second styrene-based copolymer including an alkyl-unsubstituted styrene-based monomer unit and a vinyl cyan-based monomer unit; and an olefin-based copolymer including a C1 to C3 alkyl (meth)acrylate-based monomer unit. The thermoplastic resin composition exhibits remarkably excellent chemical resistance and remarkably excellent appearance characteristics while maintaining basic properties.

Abstract: Provided is a thermoplastic resin composition which includes: a graft copolymer including a C4 to C10 alkyl (meth)acrylate-based monomer unit, a styrene-based monomer unit, and a vinyl cyan-based monomer unit; a first styrene-based copolymer including a C1 to C3 alkyl-substituted styrene-based monomer unit and a vinyl cyan-based monomer unit; and a second styrene-based copolymer including an unsubstituted styrene-based monomer unit and a vinyl cyan-based monomer unit. The thermoplastic resin composition is remarkably excellent in heat resistance, chemical resistance, and appearance characteristics while maintaining basic properties.

Abstract: Provided is a thermoplastic resin composition which includes: a graft copolymer prepared by graft-polymerizing an aromatic vinyl-based monomer and a vinyl cyan-based monomer onto an acrylic rubber polymer; a first matrix copolymer including a C1-C3 alkyl (meth)acrylate-based monomer unit, an aromatic vinyl-based monomer unit and a vinyl cyan-based monomer unit; a second matrix copolymer including a C1-C3 alkyl (meth)acrylate-based monomer unit, an aromatic vinyl-based monomer unit and a vinyl cyan-based monomer unit; and an additive including a polymer including a C1-C3 alkyl (meth)acrylate-based monomer unit, wherein the first matrix copolymer and the second matrix copolymer have different weight-average molecular weights, specifically, a thermoplastic resin composition which allows high gloss, high hardness, high weather resistance and reduced whitening to be realized.

Abstract: Provided is a thermoplastic resin composition which includes: a base resin including a polyarylene oxide-based polymer at 100 parts by weight; and an additive including one or more selected from the group consisting of compounds represented by Chemical Formula 1-1 to Chemical Formula 1-3 at 0.1 to 5 parts by weight, and can be used for producing a thermoplastic resin molded article which exhibits an excellent coloring property and thus has an aesthetically pleasing appearance.

Abstract: The present invention provides a method of preparing a graft copolymer, which comprises: emulsion-polymerizing one or more selected from the group consisting of an aromatic vinyl-based monomer to prepare a seed, a vinylcyano-based monomer and an alkyl (meth)acrylate-based monomer; emulsion-polymerizing the seed and an alkyl (meth)acrylate-based monomer to prepare a core; and emulsion-polymerizing the core, an aromatic vinyl-based monomer and a vinylcyano-based monomer to prepare a shell, wherein one or more steps selected from the group consisting of the steps of preparing the seed, the core and the shell comprises adding an emulsifier comprising a compound represented by Formula 1 below.

Abstract: The present invention relates to a method of preparing an ASA graft copolymer, a method of preparing a thermoplastic resin composition including the ASA graft copolymer, and a method of manufacturing a molded article using the thermoplastic resin composition.

Abstract: Provided is a thermoplastic resin composition which includes: a graft copolymer prepared by graft-polymerizing an aromatic vinyl-based monomer and a vinyl cyan-based monomer onto an acrylic rubber polymer having an average particle diameter of 50.0 to 90.0 nm; a matrix copolymer including a C1-C3 alkyl (meth)acrylate-based monomer unit, an aromatic vinyl-based monomer unit and a vinyl cyan-based monomer unit; and an additive including a polymer including a C1-C3 alkyl (meth)acrylate-based monomer unit, specifically, a thermoplastic resin composition which has improved properties in terms of elongation, processability, weather resistance, colorability, hardness, chemical resistance, scratch resistance, a whitening phenomenon, surface gloss and appearance quality while having excellent basic properties.

Abstract: The present invention relates to a method for preparing a graft copolymer and a graft copolymer. The method for preparing a graft copolymer includes the steps of: 1) preparing a seed by adding one or more selected from the group consisting of an alkyl (meth)acrylate-based monomer, an aromatic vinyl-based monomer, and a vinyl cyan-based monomer and carrying out polymerization; 2) preparing a core in the presence of the seed by adding an alkyl (meth)acrylate-based monomer and carrying out polymerization; and 3) preparing a shell in the presence of the core by adding an aromatic vinyl-based monomer and a vinyl cyan-based monomer and carrying out polymerization, wherein an activator including a compound represented by Chemical Formula 1 is added in the step 3), and wherein the core has an average particle diameter of 320 nm to 520 nm.

Abstract: Provided are a method of preparing a graft copolymer, a graft copolymer, and a thermoplastic resin molded article including the graft copolymer, the method including: 1) preparing a seed by adding one or more selected from the group consisting of an alkyl (meth)acrylate-based monomer, an aromatic vinyl-based monomer, and a vinyl cyan-based monomer and performing polymerization; 2) in the presence of the seed, preparing a core by adding an alkyl (meth)acrylate-based monomer and performing polymerization; and 3) in the presence of the core, preparing a shell by adding an aromatic vinyl-based monomer and a vinyl cyan-based monomer and performing polymerization, wherein the method further includes adding an alkyl acrylate-based polymer. When the alkyl acrylate-based polymer is included in a graft copolymer, a graft copolymer and a thermoplastic resin molded article excellent in weather resistance, fluidity, mechanical properties, and appearance quality can be provided.

Abstract: A roof rack mounted on a roof panel of a vehicle includes a main body including a rail that extends along a lengthwise direction and forms the main body and support parts provided on opposite longitudinal end portions of the rail in the lengthwise direction, a hollow profile that extends along the lengthwise direction of the rail and that is integrally formed inside the rail, and a cap mounted on at least one of opposite longitudinal end portions of the hollow profile or disposed inside the main body.

Abstract: The present invention relates to a non-halogen flame retardant resin composition. More particularly, the present invention provides a non-halogen flame retardant resin composition capable of simultaneously exhibiting superior flame retardancy, whiteness, and gloss by addressing problems of a flame retardant resin such as difficulties in realizing V-1 grade or higher flame retardancy when a non-halogen flame retardant is used and poor colorability due to low gloss and whiteness.

Abstract: The present invention relates to a thermoplastic resin composition having excellent weather resistance, according to the present invention, the thermoplastic resin composition has excellent weather resistance, gloss, and impact resistance, and thus may be suitable for use as exterior materials for structures, such as siding and window frames.

Abstract: Disclosed herein is a display apparatus including a display and a supporter. The supporter being mounted on the display and configured to support the display and rotate the display module between a first position and a second position. The supporter including a drive motor, a first gear, and a detection sensor. The drive motor configured to supply a driving force to rotate the display. The first gear configured to rotate together with the display by receiving the driving force from the drive motor. The detection sensor configured to detect a rotation amount of a second gear configured to rotate in with the first gear.

Abstract: The present invention relates to a thermoplastic resin composition, including a first graft copolymer including an alkyl (meth)acrylate-based polymer-derived unit, an aromatic vinyl-based monomer-derived unit, and a vinyl cyanide-based monomer-derived unit; a copolymer including an aromatic vinyl-based monomer-derived unit and a vinyl cyanide-based monomer-derived unit; a polyester-based elastomer; and a phthalate-based plasticizer.

Abstract: The present invention relates to a thermoplastic resin composition, a method of preparing the same, and a molded part manufactured using the same. More specifically, the present invention provides a thermoplastic resin composition having excellent mechanical properties, such as tensile strength and impact strength, and weather resistance while having low gloss characteristics, a method of preparing the same, and a molded part manufactured using the same. According to the present invention, the thermoplastic resin composition includes an ASA graft copolymer having a core-shell structure having an average particle diameter of 0.05 to 1 ?m, an aromatic vinyl compound-vinyl cyanide compound copolymer, and an epoxy group-containing copolymer having a weight average molecular weight of 2,000 to 8,000 g/mol in specific amounts.