Abstract: The present disclosure relates to a treatment method of wastewater containing heterocyclic organics comprising the following steps: (1) adding a persulfate to the wastewater containing heterocyclic organics in a reaction vessel; (2) heating the reaction vessel to a reaction temperature in an inert atmosphere, then introducing an oxygen-containing gas until a reaction pressure is reached for reaction, and after the reaction is completed, cooling and filtering the reaction resultant to obtain a filtrate as a treated effluent and a filter residue; no catalyst is added to the reaction system. The treatment method provided by the present disclosure not only can significantly reduce the treatment temperature of the conventional wet oxidation, but also can control the amount of generated spherical polymer and the removal efficiency of organic pollutants by control of reaction conditions. Wastewater purification and organics recovery and reuse are achieved at the same time.

Abstract: An ozone-photocatalysis reactor, comprising: a shell layer (1); activated carbon layers (2) arranged in the shell layer (1); and at least one photoxidation unit arranged in the shell layer (1) and above the activated carbon layers (2). The photoxidation unit comprises a honeycomb activated carbon layer I (3), a light source layer and a honeycomb activated carbon bed layer II (4) sequentially from bottom to top. A gas inlet (7) and a water inlet (6) are formed in the shell layer below the activated carbon layers (2); a water outlet (9) and a gas outlet (10) are formed in the shell layer (1) above the photoxidation unit; and the activated carbon layers (2), at least one honeycomb activated carbon bed layer I (3) and at least one honeycomb activated carbon bed layer II (4) are loaded with a solid catalyst. The reactor uses ozone oxidation and ozone-photocatalysis sufficiently for sewage treatment, the treatment time is short, and the treatment efficiency is high.

Abstract: The present disclosure relates to a treatment method of wastewater containing heterocyclic organics comprising the following steps: (1) adding a persulfate to the wastewater containing heterocyclic organics in a reaction vessel; (2) heating the reaction vessel to a reaction temperature in an inert atmosphere, then introducing an oxygen-containing gas until a reaction pressure is reached for reaction, and after the reaction is completed, cooling and filtering the reaction resultant to obtain a filtrate as a treated effluent and a filter residue; no catalyst is added to the reaction system. The treatment method provided by the present disclosure not only can significantly reduce the treatment temperature of the conventional wet oxidation, but also can control the amount of generated spherical polymer and the removal efficiency of organic pollutants by control of reaction conditions. Wastewater purification and organics recovery and reuse are achieved at the same time.

Abstract: The present disclosure relates to a method for photocatalytic ozonation reaction, in which the silicon carbide material is used. By using the silicon carbide material for photocatalytic ozonation reaction, the present disclosure overcomes the problem of low photocatalytic efficiency of silicon carbide, utilizes photogenerated electrons therefrom with strong reducibility to reduce ozone molecules to efficiently produce hydroxyl radicals, so as to improve the oxidation capacity in the process. Whether visible light or ultraviolet light is coupled with ozone, the group has strong catalytic activity, moreover, the silicon carbide has low cost and good stability, which prolongs the life of catalyst for photocatalytic ozonation or device.

Abstract: An ozone-photocatalysis reactor, comprising: a shell layer (1); activated carbon layers (2) arranged in the shell layer (1); and at least one photoxidation unit arranged in the shell layer (1) and above the activated carbon layers (2). The photoxidation unit comprises a honeycomb activated carbon layer I (3), a light source layer and a honeycomb activated carbon bed layer II (4) sequentially from bottom to top. A gas inlet (7) and a water inlet (6) are formed in the shell layer below the activated carbon layers (2); a water outlet (9) and a gas outlet (10) are formed in the shell layer (1) above the photoxidation unit; and the activated carbon layers (2), at least one honeycomb activated carbon bed layer I (3) and at least one honeycomb activated carbon bed layer II (4) are loaded with a solid catalyst. The reactor uses ozone oxidation and ozone-photocatalysis sufficiently for sewage treatment, the treatment time is short, and the treatment efficiency is high.

Abstract: The present invention relates to a synthetic method of graphitic carbon nitride material. The method involves a homogenous mixing of carbon nitride precursor and ammonium salt, and calcining the mixture to obtain a porous graphitic carbon nitride material. Wherein, the ammonium salt is any one or a combination of at least two which could release gaseous NH3 during thermolysis. The present invention uses thermolabile ammonium salt as a pore former; the thermolysis of ammonium salt could release soft gas bubbles during the calcination; the later burst of bubbles leads to the formation of nanoporous structure. The proposed method is template-free and environmentally-friendly, and the resultant material exhibits high photocatalytic activity in the field of gas and water decontamination.