Patents by Inventor Yoshihiro Kameda
Yoshihiro Kameda has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 12110354Abstract: An object of the present invention is to provide a method of producing a copolymer that produces an aromatic vinyl-diene copolymer having a low glass transition temperature, and a method of producing a rubber composition using the method. The subject method produces an aromatic vinyl-diene copolymer having a content of repeating units derived from an aromatic vinyl in an amount of 18 mass % or greater, and among repeating units derived from a diene, a proportion of a vinyl structure of 8 mol % or less, a proportion of a 1,4-trans structure of 60 mol % or less, and a proportion of a 1,4-cis structure from 40 to 95 mol %, the method including copolymerizing a monomer containing an aromatic vinyl and a diene using an initiator prepared with an organolithium compound, an alkylaluminum, a metal alcoholate, and at least one polar compound selected from the group consisting of water and an alcohol.Type: GrantFiled: August 22, 2019Date of Patent: October 8, 2024Assignee: The Yokohama Rubber Co., LTD.Inventors: Kazuya Uenishi, Yu Shinke, Yoshihiro Kameda, Masaki Sato, Ayaki Kazariya, Hideaki Sawa
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Publication number: 20210246246Abstract: An object of the present invention is to provide a method of producing a copolymer that produces an aromatic vinyl-diene copolymer having a low glass transition temperature, and a method of producing a rubber composition using the method. The subject method produces an aromatic vinyl-diene copolymer having a content of repeating units derived from an aromatic vinyl in an amount of 18 mass % or greater, and among repeating units derived from a diene, a proportion of a vinyl structure of 8 mol % or less, a proportion of a 1,4-trans structure of 60 mol % or less, and a proportion of a 1,4-cis structure from 40 to 95 mol %, the method including copolymerizing a monomer containing an aromatic vinyl and a diene using an initiator prepared with an organolithium compound, an alkylaluminum, a metal alcoholate, and at least one polar compound selected from the group consisting of water and an alcohol.Type: ApplicationFiled: August 22, 2019Publication date: August 12, 2021Inventors: Kazuya UENISHI, Yu SHINKE, Yoshihiro KAMEDA, Masaki SATO, Ayaki KAZARIYA, Hideaki SAWA
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Patent number: 10273352Abstract: A pneumatic tire using as a tread part, a rubber composition containing a high silica-content rubber composition having a difference F-S between an amount of filler F and an amount of a softening agent S of 60 to 90 parts by weight and having a durometer hardness measured at 20° C. of 65 to 76.Type: GrantFiled: August 2, 2007Date of Patent: April 30, 2019Assignee: THE YOKOHAMA RUBBER CO., LTD.Inventors: Naoya Amino, Yoshihiro Kameda, Kazuto Yamakawa, Akitomo Sato
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Patent number: 10072138Abstract: A rubber composition comprises a diene rubber including not less than 30% by weight of a modified conjugated diene polymer rubber and, per 100 parts by weight of the diene rubber, from 1 to 25 parts by weight of a tackifying resin, and from 25 to 80 parts by weight of a filler comprising not less than 50% by weight of silica. The modified conjugated diene polymer rubber has a terminal modified group comprising a functional group that interacts with silica. In the modified conjugated diene polymer rubber, aromatic vinyl unit content is from 38% to 48% by weight, vinyl unit content is from 20% to 35%, weight-average molecular weight is from 600,000 to 1,000,000, and glass transition temperature is from ?22 to ?32° C. A glass transition temperature of the tackifying resin is from 50 to 110° C. higher than the glass transition temperature of the modified conjugated diene polymer rubber.Type: GrantFiled: November 25, 2011Date of Patent: September 11, 2018Assignee: The Yokohama Rubber Co., LTDInventors: Ayumi Naka, Takashi Shirokawa, Makoto Ashiura, Yoshihiro Kameda, Masaki Satou
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Patent number: 9567451Abstract: A rubber composition for use in tire treads comprises a diene rubber including not less than 40% by weight of a modified conjugated diene polymer rubber and, per 100 parts by weight of the diene rubber, from 66 to 110 parts by weight of a filler. The filler comprises not less than 50% by weight of silica. The modified conjugated diene polymer rubber is obtained by copolymerizing a conjugated diene monomer unit and an aromatic vinyl monomer unit in a hydrocarbon solvent using an organic active metal compound as an initiator. A resulting active conjugated diene polymer chain thereof has a terminal modified group, obtained by reacting at least one type of compound having a functional group that is reactable with the active terminal of the polymer chain. Moreover, the terminal modified group has a functional group that interacts with the silica.Type: GrantFiled: November 25, 2011Date of Patent: February 14, 2017Assignee: The Yokohama Rubber Co., LTD.Inventors: Masaki Satou, Takashi Shirokawa, Makoto Ashiura, Yoshihiro Kameda, Ayumi Naka, Keisuke Maejima
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Patent number: 9534101Abstract: The present technology provides a rubber composition comprising from 30 to 100 parts by weight of a carbon black, and from 10 to 80 parts by weight of an inorganic filler per 100 parts by weight of a diene rubber, wherein the inorganic filler has from 20 to 80% particles of a particle size of at most 5 ?m; and when an aluminum content in the inorganic filler is defined as Wal wt. % and a silicon content is defined as Wsi wt. %, the aluminum content Wal is from 11 to 40 wt. %, and a ratio Wal/(Wal+Wsi)×100 of aluminum to a total of aluminum and silicon is from 15 to 38 wt. %.Type: GrantFiled: March 26, 2014Date of Patent: January 3, 2017Assignee: The Yokohama Co., LTD.Inventors: Miyuki Oka, Yoshihiro Kameda
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Patent number: 9475924Abstract: A rubber composition for tire tread contains a diene-based rubber including 30 wt % or more of a terminal modifying group-containing conjugated diene-based copolymer, silica, carbon black, and at least one of silane coupling agents represented by specified formulae. The total amount of silica and carbon black in the composition is 35 to 140 parts by weight relative to 100 parts by weight of the diene-based rubber, while the silane coupling agent content is 4 to 18 wt % on the silica content. The copolymer is produced by a specified method such that the aromatic vinyl monomer content in the copolymer is 38 to 48 wt %, the vinyl unit content in all the conjugated diene-based monomers is 20 to 35 mol %, the weight average molecular weight of the copolymer is 600,000 to 1,000,000, and the terminal modifying group in the copolymer contains a functional group which interacts with the silica.Type: GrantFiled: September 26, 2012Date of Patent: October 25, 2016Assignee: The Yokohama Rubber Co., Ltd.Inventors: Yoshihiro Kameda, Makoto Ashiura
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Patent number: 9446631Abstract: A rubber composition for a run-flat tire comprises from 20 to 100 parts by weight of a reinforcing filler per 100 parts by weight of a diene rubber containing from 10 to 80 wt. % of butadiene rubber and from 10 to 40 wt. % of natural rubber; wherein the reinforcing filler contains at least 50 wt. % of carbon black; a mode diameter Dst in a mass distribution curve of a Stokes diameter of aggregates of the carbon black is at least 145 nm; a nitrogen adsorption specific surface area N2SA is from 45 to 70 m2/g; and a ratio N2SA/IA of the nitrogen adsorption specific surface area N2SA to an iodine adsorption IA (units: mg/g) is from 1.00 to 1.40.Type: GrantFiled: October 25, 2013Date of Patent: September 20, 2016Assignee: The Yokohama Rubber Co., LTD.Inventor: Yoshihiro Kameda
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Patent number: 9416252Abstract: A rubber composition comprises a diene rubber including not less than 25% by weight of a modified conjugated diene polymer rubber and, per 100 parts by weight of the diene rubber, from 25 to 65 parts by weight of a filler, the filler comprising not less than 50% by weight of silica. The silica has a DBP absorption number of 190 to 250 ml/100 g, an N2SA of 194 to 225 m/g, and a CTAB of 185 to 215 m2/g. A ratio of the N2SA to the CTAB is from 0.9 to 1.4. The modified conjugated diene polymer rubber has a terminal modified group including a functional group that interacts with the silica. In the modified conjugated diene polymer rubber, aromatic vinyl unit content is from 38% to 48% by weight, vinyl unit content is from 20% to 35%, and weight-average molecular weight is from 600,000 to 1,000,000.Type: GrantFiled: November 25, 2011Date of Patent: August 16, 2016Assignee: The Yokohama Rubber Co., LTD.Inventors: Ayumi Naka, Takashi Shirokawa, Makoto Ashiura, Yoshihiro Kameda, Masaki Satou, Keisuke Maejima
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Publication number: 20160053076Abstract: The present technology provides a rubber composition comprising from 30 to 100 parts by weight of a carbon black, and from 10 to 80 parts by weight of an inorganic filler per 100 parts by weight of a diene rubber, wherein the inorganic filler has from 20 to 80% particles of a particle size of at most 5 ?m; and when an aluminum content in the inorganic filler is defined as Wal wt. % and a silicon content is defined as Wsi wt. %, the aluminum content Wal is from 11 to 40 wt. %, and a ratio Wal/(Wal+Wsi)×100 of aluminum to a total of aluminum and silicon is from 15 to 38 wt. %.Type: ApplicationFiled: March 26, 2014Publication date: February 25, 2016Applicant: The Yokohama Rubber Co., Ltd.Inventors: Miyuki OKA, Yoshihiro KAMEDA
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Publication number: 20150298511Abstract: A rubber composition for a run-flat tire comprises from 20 to 100 parts by weight of a reinforcing filler per 100 parts by weight of a diene rubber containing from 10 to 80 wt. % of butadiene rubber and from 10 to 40 wt. % of natural rubber; wherein the reinforcing filler contains at least 50 wt. % of carbon black; a mode diameter Dst in a mass distribution curve of a Stokes diameter of aggregates of the carbon black is at least 145 nm; a nitrogen adsorption specific surface area N2SA is from 45 to 70 m2/g; and a ratio N2SA/IA of the nitrogen adsorption specific surface area N2SA to an iodine adsorption IA (units: mg/g) is from 1.00 to 1.40.Type: ApplicationFiled: October 25, 2013Publication date: October 22, 2015Applicant: The Yokohama Rubber Co., LTD.Inventor: Yoshihiro KAMEDA
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Patent number: 8720507Abstract: A pneumatic tire with superior durability having a tread part comprising a cap tread layer (layer A) and an under tread layer (layer B), wherein, in the pneumatic tire, when storage elastic moduli of the rubber compositions constituting the layer A and the layer B are designated as EA and EB, the storage elastic moduli EA (60° C.) and EB (60° C.) determined at a temperature of 60° C. satisfy the following formulae (1) and (2): EA(60° C.)/EB(60° C.)?0.66??(1) 10(MPa)?EB(60° C.Type: GrantFiled: November 1, 2007Date of Patent: May 13, 2014Assignee: The Yokohoma Rubber Co., Ltd.Inventor: Yoshihiro Kameda
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Patent number: 8722781Abstract: A rubber composition for a tire containing 100 parts by weight of a rubber, 1 to 30 parts by weight of a polyether (E1) having the formula (I): R1—{(OCH2CH2CH2CH2)m(OA)n—OH}q??(I) wherein R1 is a residue of a C1 to C24 compound having 1-6 hydroxyl groups, from which at least one hydroxyl group is removed, A Ls a C2 to C24 alkylene group other than a 1,4-butylene group, q is an integer of 1 to 6, and m and n are independently integers of 1 to 600, and/or the derivative thereof (E2) and 10 to 180 parts by weight of a filler, which is excellent in processability, silica dispersability abrasion resistance and wet braking performance, etc.Type: GrantFiled: May 27, 2005Date of Patent: May 13, 2014Assignee: The Yokohama Rubber Co., Ltd.Inventors: Yoshihiro Kameda, Yasuhiro Yamada, Satoru Yamakawa, Tsuyoshi Okamoto
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Publication number: 20140011909Abstract: A rubber composition for use in tire treads comprises a diene rubber including not less than 40% by weight of a modified conjugated diene polymer rubber and, per 100 parts by weight of the diene rubber, from 66 to 110 parts by weight of a filler. The filler comprises not less than 50% by weight of silica. The modified conjugated diene polymer rubber is obtained by copolymerizing a conjugated diene monomer unit and an aromatic vinyl monomer unit in a hydrocarbon solvent using an organic active metal compound as an initiator. A resulting active conjugated diene polymer chain thereof has a terminal modified group, obtained by reacting at least one type of compound having a functional group that is reactable with the active terminal of the polymer chain. Moreover, the terminal modified group has a functional group that interacts with the silica.Type: ApplicationFiled: November 25, 2011Publication date: January 9, 2014Applicant: The Yokohama Rubber Co., Ltd.Inventors: Masaki Satou, Takashi Shirokawa, Makoto Ashiura, Yoshihiro Kameda, Ayumi Naka, Keisuke Maejima
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Publication number: 20130338255Abstract: A rubber composition comprises a diene rubber including not less than 25% by weight of a modified conjugated diene polymer rubber and, per 100 parts by weight of the diene rubber, from 25 to 65 parts by weight of a filler, the filler comprising not less than 50% by weight of silica. The silica has a DBP absorption number of 190 to 250 ml/100 g, an N2SA of 194 to 225 m/g, and a CTAB of 185 to 215 m2/g. A ratio of the N2SA to the CTAB is from 0.9 to 1.4. The modified conjugated diene polymer rubber has a terminal modified group including a functional group that interacts with the silica. In the modified conjugated diene polymer rubber, aromatic vinyl unit content is from 38% to 48% by weight, vinyl unit content is from 20% to 35%, and weight-average molecular weight is from 600,000 to 1,000,000.Type: ApplicationFiled: November 25, 2011Publication date: December 19, 2013Applicant: The Yokohama Rubber Co., LTD.Inventors: Ayumi Naka, Takashi Shirokawa, Makoto Ashiura, Yoshihiro Kameda, Masaki Satou, Keisuke Maejima
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Publication number: 20130324638Abstract: A rubber composition comprises a diene rubber including not less than 30% by weight of a modified conjugated diene polymer rubber and, per 100 parts by weight of the diene rubber, from 1 to 25 parts by weight of a tackifying resin, and from 25 to 80 parts by weight of a filler comprising not less than 50% by weight of silica. The modified conjugated diene polymer rubber has a terminal modified group comprising a functional group that interacts with silica. In the modified conjugated diene polymer rubber, aromatic vinyl unit content is from 38% to 48% by weight, vinyl unit content is from 20% to 35%, weight-average molecular weight is from 600,000 to 1,000,000, and glass transition temperature is from ?22 to ?32° C. A glass transition temperature of the tackifying resin is from 50 to 110° C. higher than the glass transition temperature of the modified conjugated diene polymer rubber.Type: ApplicationFiled: November 25, 2011Publication date: December 5, 2013Applicant: THE YOKOHAMA RUBBER CO., LTD.Inventors: Ayumi Naka, Takashi Shirokawa, Makoto Ashiura, Yoshihiro Kameda, Masaki Satou
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Publication number: 20130267646Abstract: A rubber composition for tire tread contains a diene-based rubber including 30 wt % or more of a terminal modifying group-containing conjugated diene-based copolymer, silica, carbon black, and at least one of silane coupling agents represented by specified formulae. The total amount of silica and carbon black in the composition is 35 to 140 parts by weight relative to 100 parts by weight of the diene-based rubber, while the silane coupling agent content is 4 to 18 wt % on the silica content. The copolymer is produced by a specified method such that the aromatic vinyl monomer content in the copolymer is 38 to 48 wt %, the vinyl unit content in all the conjugated diene-based monomers is 20 to 35 mol %, the weight average molecular weight of the copolymer is 600,000 to 1,000,000, and the terminal modifying group in the copolymer contains a functional group which interacts with the silica.Type: ApplicationFiled: September 26, 2012Publication date: October 10, 2013Inventors: Yoshihiro KAMEDA, Makoto ASHIURA
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Patent number: 8148473Abstract: Disclosed is a sulfur-containing conjugated diolefin copolymer rubber composed of a conjugated diolefin and an aromatic vinyl compound, wherein (1) the content of sulfur bound to the rubber is 0.01 mmol % or more, (2) the content of the aromatic vinyl compound polymerization unit is not less than 5 wt % and less than 45 wt % relative to the amount of the copolymer rubber, and (3) the content of a vinyl bond (a 1,2-bond) in the conjugated diolefin polymerization unit is 30 mol % or more relative to the amount of the conjugated diolefin polymerization unit. In the copolymerization between the conjugated diolefin and the aromatic vinyl compound, a sulfur-containing polymerization terminator is used to terminate the reaction of the copolymerization.Type: GrantFiled: June 11, 2008Date of Patent: April 3, 2012Assignee: The Yokohama Rubber Co., Ltd.Inventors: Yoshihiro Kameda, Makoto Ashiura
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Patent number: 7922843Abstract: A strip-shaped polarizing film has a protective film strip conformably adhered to one surface thereof and a releasable liner conformably adhered to the other surface thereof and delivered from a film delivering station 1. After an appearance inspection, a lamination of the protective film strip and the polarizing film strip F is half-cut using a laser unit 11 to form an array of laminations each consisting of a protective film and a polarizing film F, with the releasable liner being left intact. Then, the polarizing films F are fed to a peeling mechanism 4. The peeling mechanism 4 feeds a forwardmost one the polarizing films F to a laminating mechanism 5 while peeling off the releasable liner therefrom by a knife-edged member. The forwardmost polarizing film F is laminated to a liquid-crystal panel W conveyed to the laminating mechanism by a panel transport apparatus 18 in synchronization of the feeding of the forwardmost polarizing film F.Type: GrantFiled: April 13, 2009Date of Patent: April 12, 2011Assignee: Nitto Denko CorporationInventors: Kazuo Kitada, Yoshihiro Kameda, Kanji Nishida, Tomokazu Yura, Takaichi Amano, Hiromichi Ohashi, Atsushi Hino, Naoyuki Matsuo
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Patent number: 7913734Abstract: A strip-shaped polarizing film has a protective film strip conformably adhered to one surface thereof and a releasable liner conformably adhered to the other surface thereof and delivered from a film delivering station 1. After an appearance inspection, a lamination of the protective film strip and the polarizing film strip F is half-cut using a laser unit 11 to form an array of laminations each consisting of a protective film and a polarizing film F, with the releasable liner being left intact. Then, the polarizing films F are fed to a peeling mechanism 4. The peeling mechanism 4 feeds a forwardmost one the polarizing films F to a laminating mechanism 5 while peeling off the releasable liner therefrom by a knife-edged member. The forwardmost polarizing film F is laminated to a liquid-crystal panel W conveyed to the laminating mechanism by a panel transport apparatus 18 in synchronization of the feeding of the forwardmost polarizing film F.Type: GrantFiled: July 26, 2010Date of Patent: March 29, 2011Assignee: Nitto Denko CorporationInventors: Kazuo Kitada, Yoshihiro Kameda, Kanji Nishida, Tomokazu Yura, Takaichi Amano, Hiromichi Ohashi, Atsushi Hino, Naoyuki Matsuo