Patent number: 7829044
Abstract: The invention provides a process by which rare earth metal ions can be efficiently extracted by easy operation, and effective extracting reagents for the process. Specifically, phosphonamides represented by the general formula [1]; a process for producing the same; reagents for extracting rare earth metal ions, containing the phosphonamides; and a process for extraction of rare earth metal ions with the phosphonamides: [1] wherein R1 is alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, aryl, aralkyl, or a heterocyclic group, with the proviso that each group may be substituted; R2 is hydrogen, alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl, aralkyl, or a heterocyclic group, with the proviso that each group may be substituted; R3 is hydrogen, alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl, aralkyl, or a heterocyclic group, with the proviso that each group may be substituted, or the two R3s may be united to form alkylene, cycloalkylene, or arylene.
Type:
Grant
Filed:
March 3, 2003
Date of Patent:
November 9, 2010
Assignee:
Japan Science and Technology Agency
Inventors:
Yoshikazu Makioka, Teruyuki Hayashi, Masato Tanaka, Li-Biao Han
Publication number: 20090137771
Abstract: The present invention provides a resin composition which can be cured by visible light and whose cured product is not colored or little colored, said composition comprising a phosphine oxide compound represented by the following general formula (1) (wherein R1 represents alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, substituted or unsubstituted aryl, substituted or unsubstituted heteroaryl, substituted or unsubstituted aralkyl, or substituted or unsubstituted aralkenyl; and R2, R3, R4, R5, R6, R7, R8 and R9, which may be the same or different, each represent a hydrogen atom, a halogen atom, alkyl, alkenyl, substituted or unsubstituted aralkyl, or substituted or unsubstituted aralkenyl, and two adjacent groups among R2, R3, R4, R5, R6, R7, R8 and R9 may form a hydrocarbon ring together with the two carbon atoms adjacent thereto) and an unsaturated compound.
Type:
Application
Filed:
August 11, 2006
Publication date:
May 28, 2009
Inventors:
Satoshi Moriyama, Iwao Hotta, Masato Tanaka, Yoshikazu Makioka
Publication number: 20050107599
Abstract: The invention provides a process by which rare earth metal ions can be efficiently extracted by easy operation, and effective extracting reagents for the process. Specifically, phosphonamides represented by the general formula [1]; a process for producing the same; reagents for extracting rare earth metal ions, containing the phosphonamides; and a process for extraction of rare earth metal ions with the phosphonamides: [1] wherein R1 is alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, aryl, aralkyl, or a heterocyclic group, with the proviso that each group may be substituted; R2 is hydrogen, alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl, aralkyl, or a heterocyclic group, with the proviso that each group may be substituted; R3 is hydrogen, alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl, aralkyl, or a heterocyclic group, with the proviso that each group may be substituted, or the two R3s may be united to form alkylene, cycloalkylene, or arylene.
Type:
Application
Filed:
March 3, 2003
Publication date:
May 19, 2005
Inventors:
Yoshikazu Makioka, Teruyuki Hayashi, Masato Tanaka, Li-Biao Han