Patents by Inventor Yoshiko Hiraoka

Yoshiko Hiraoka has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11908970
    Abstract: A process for manufacturing a multilayered thin film, includes: forming a photovoltaic conversion layer, comprising Cu2O as a main component, on a first transparent electrode; and placing, under a first atmosphere at an oxygen level of from 5.0×10?8 [g/L] to 5.0×10?5 [g/L] for 1 h to 1600 h, a member having the photovoltaic conversion layer formed on the first transparent electrode.
    Type: Grant
    Filed: August 30, 2021
    Date of Patent: February 20, 2024
    Assignees: KABUSHIKI KAISHA TOSHIBA, TOSHIBA ENERGY SYSTEMS & SOLUTIONS CORPORATION
    Inventors: Yuya Honishi, Soichiro Shibasaki, Naoyuki Nakagawa, Mutsuki Yamazaki, Yoshiko Hiraoka, Kazushige Yamamoto
  • Patent number: 11888076
    Abstract: A solar cell of an embodiment includes: a transparent substrate; a p-electrode on the substrate, the p-electrode including a first p-electrode containing an Sn-based metal oxide, a second p-electrode having an opening and consisting of a wiring containing a metal or graphene, and a third p-electrode containing an In-based metal oxide; a p-type light absorbing layer in direct contact with a surface of the first p-electrode on a side opposite to the second p-electrode side; an n-type layer provided on the p-type light absorbing layer; and an n-electrode provided on the n-type layer. The third p-electrode is provided to be present between the first p-electrode and the second p-electrode and to be in direct contact with an upper surface of the second p-electrode. An entire side surface of the second p-electrode is in direct contact with the first p-electrode.
    Type: Grant
    Filed: September 9, 2021
    Date of Patent: January 30, 2024
    Assignees: KABUSHIKI KAISHA TOSHIBA, TOSHIBA ENERGY SYSTEMS & SOLUTIONS CORPORATION
    Inventors: Kazushige Yamamoto, Soichiro Shibasaki, Yuya Honishi, Naoyuki Nakagawa, Mutsuki Yamazaki, Yoshiko Hiraoka
  • Patent number: 11817520
    Abstract: A method for manufacturing a stacked thin film, includes forming a photoelectric conversion layer on a first transparent electrode by sputtering using a target mainly composed of copper in an oxygen containing atmosphere. An oxygen partial pressure of the sputtering is in a range of 0.01 [Pa] or more and 4.8 [Pa] or less, and 0.24×d [Pa] or more and 2.4×d [Pa] or less when a deposition rate is d [?m/min], in formation of the photoelectric conversion layer. A sputtering temperature is 300° C. or more and 600° C. or less, in formation of the photoelectric conversion layer.
    Type: Grant
    Filed: September 9, 2020
    Date of Patent: November 14, 2023
    Assignees: KABUSHIKI KAISHA TOSHIBA, TOSHIBA ENERGY SYSTEMS & SOLUTIONS CORPORATION
    Inventors: Soichiro Shibasaki, Yuya Honishi, Mutsuki Yamazaki, Naoyuki Nakagawa, Sara Yoshio, Yoshiko Hiraoka, Kazushige Yamamoto
  • Publication number: 20230125003
    Abstract: A solar cell of an embodiment includes a p-electrode; an n-electrode; a p-type light-absorbing layer located between the p-electrode and the n-electrode and mainly containing a cuprous oxide; and an n-type layer located between the first n-type layer and the n-electrode, the n-type layer including a first n-type layer and a second n-type layer or a first n-type region and a second n-type region; wherein the first n-type layer and the first n-type region is located on the p-type light-absorbing layer side, the second n-type layer and the second n-type region is located on the n-electrode side, the first n-type layer and the first n-type region mainly contain a compound represented by Gax1M1x2Ox3, the M1 is one or more selected from the group consisting of Hf, Zr, In, Zn, Ti, Al, B, Sn, Si, and Ge, the x1, the x2, and the x3 are more than 0, and the x3 when a sum of the x1 and the x2 is 2 is 3.0 or more and 3.
    Type: Application
    Filed: August 30, 2022
    Publication date: April 20, 2023
    Inventors: Naoyuki Nakagawa, Yukitami Mizuno, Soichiro Shibasaki, Yuya Honishi, Mutsuki Yamazaki, Yoshiko Hiraoka, Kazushige Yamamoto
  • Patent number: 11626528
    Abstract: The photoelectric conversion layer of an embodiment is based on Cu2O, contains at least one p-type dopant selected from the group consisting of Ge, Ta, and In, and has a band gap of equal to or more than 2.10 eV and equal to or less than 2.30 eV.
    Type: Grant
    Filed: February 26, 2021
    Date of Patent: April 11, 2023
    Assignees: KABUSHIKI KAISHA TOSHIBA, TOSHIBA ENERGY SYSTEMS & SOLUTIONS CORPORATION
    Inventors: Kazushige Yamamoto, Mutsuki Yamazaki, Soichiro Shibasaki, Yuya Honishi, Naoyuki Nakagawa, Yoshiko Hiraoka
  • Patent number: 11581444
    Abstract: The solar cell of embodiments includes a transparent first electrode, a photoelectric conversion layer mainly containing cuprous oxide on the first electrode, an n-type layer on the photoelectric conversion layer, and a transparent second electrode on the n-type layer. A mixed region or/and a mixed layer are present on the n-type layer side of the photoelectric conversion layer, and the mixed region and the mixed layer contain elements belonging to a first group, a second group, and a third group. The first group is one or more elements selected from the group consisting of Zn and Sn, the second group is one or more elements selected from the group consisting of Y, Sc, V, Cr, Mn, Fe, Ni, Zr, B, Al, Ga, Nb, Mo, Ti, F, Cl, Br, and I, and the third group is one or more elements selected from the group consisting of Ge and Si.
    Type: Grant
    Filed: November 15, 2021
    Date of Patent: February 14, 2023
    Assignees: KABUSHIKI KAISHA TOSHIBA, TOSHIBA ENERGY SYSTEMS & SOLUTIONS CORPORATION
    Inventors: Kazushige Yamamoto, Soichiro Shibasaki, Mutsuki Yamazaki, Naoyuki Nakagawa, Yuya Honishi, Sara Yoshio, Yoshiko Hiraoka
  • Publication number: 20230017543
    Abstract: A solar cell of an embodiment includes a p-electrode, an n-electrode, a p-type light-absorbing layer located between the p-electrode and the n-electrode and mainly containing a cuprous oxide, and an n-type layer includes a first n-type layer which is located between the p-type light-absorbing layer and the n-electrode and mainly contains a compound represented by Gax1M1x2M2x3M3x4Ox5, the M1 being Al and/or B, the M2 being one or more selected from the group consisting of In, Ti, Zn, Hf, and Zr, the M3 being one or more selected from the group consisting of Sn, Si, and Ge, the x1 and the x5 being more than 0, the x2, the x3, and the x4 being 0 or more, and the x5 when a sum of the x1, the x2, the x3, and the x4 is 2 being 3.0 or more and 3.
    Type: Application
    Filed: September 7, 2022
    Publication date: January 19, 2023
    Inventors: Kazushige Yamamoto, Naoyuki Nakagawa, Yukitami Mizuno, Soichiro Shibasaki, Yuya Honishi, Mutsuki Yamazaki, Yoshiko Hiraoka
  • Publication number: 20220077332
    Abstract: The solar cell of embodiments includes a transparent first electrode, a photoelectric conversion layer mainly containing cuprous oxide on the first electrode, an n-type layer on the photoelectric conversion layer, and a transparent second electrode on the n-type layer. A mixed region or/and a mixed layer are present on the n-type layer side of the photoelectric conversion layer, and the mixed region and the mixed layer contain elements belonging to a first group, a second group, and a third group. The first group is one or more elements selected from the group consisting of Zn and Sn, the second group is one or more elements selected from the group consisting of Y, Sc, V, Cr, Mn, Fe, Ni, Zr, B, Al, Ga, Nb, Mo, Ti, F, Cl, Br, and I, and the third group is one or more elements selected from the group consisting of Ge and Si.
    Type: Application
    Filed: November 15, 2021
    Publication date: March 10, 2022
    Inventors: Kazushige Yamamoto, Soichiro Shibasaki, Mutsuki Yamazaki, Naoyuki Nakagawa, Yuya Honishi, Sara Yoshio, Yoshiko Hiraoka
  • Publication number: 20210408315
    Abstract: A solar cell of an embodiment includes: a transparent substrate; a p-electrode on the substrate, the p-electrode including a first p-electrode containing an Sn-based metal oxide, a second p-electrode having an opening and consisting of a wiring containing a metal or graphene, and a third p-electrode containing an In-based metal oxide; a p-type light absorbing layer in direct contact with a surface of the first p-electrode on a side opposite to the second p-electrode side; an n-type layer provided on the p-type light absorbing layer; and an n-electrode provided on the n-type layer. The third p-electrode is provided to be present between the first p-electrode and the second p-electrode and to be in direct contact with an upper surface of the second p-electrode. An entire side surface of the second p-electrode is in direct contact with the first p-electrode.
    Type: Application
    Filed: September 9, 2021
    Publication date: December 30, 2021
    Inventors: Kazushige Yamamoto, Soichiro Shibasaki, Yuya Honishi, Naoyuki Nakagawa, Mutsuki Yamazaki, Yoshiko Hiraoka
  • Publication number: 20210391491
    Abstract: A process for manufacturing a multilayered thin film, includes: forming a photovoltaic conversion layer, comprising Cu2O as a main component, on a first transparent electrode; and placing, under a first atmosphere at an oxygen level of from 5.0×10?8 [g/L] to 5.0×10?5 [g/L] for 1 h to 1600 h, a member having the photovoltaic conversion layer formed on the first transparent electrode.
    Type: Application
    Filed: August 30, 2021
    Publication date: December 16, 2021
    Inventors: Yuya Honishi, Soichiro Shibasaki, Naoyuki Nakagawa, Mutsuki Yamazaki, Yoshiko Hiraoka, Kazushige Yamamoto
  • Patent number: 11171253
    Abstract: A solar cell of an embodiment includes: a first electrode; a second electrode; a light-absorbing layer interposed between the first electrode and the second electrode; a dot region interposed between the first electrode and the light-absorbing layer, the dot region including dots.
    Type: Grant
    Filed: August 31, 2017
    Date of Patent: November 9, 2021
    Assignee: KABUSHIKI KAISHA TOSHIBA
    Inventors: Soichiro Shibasaki, Miyuki Shiokawa, Sara Yoshio, Naoyuki Nakagawa, Yukitami Mizuno, Kohei Nakayama, Mutsuki Yamazaki, Yoshiko Hiraoka, Kazushige Yamamoto, Yuya Honishi, Takeshi Niimoto
  • Publication number: 20210184066
    Abstract: A solar cell according to an embodiment includes a first electrode being transparent, a first semiconductor layer on the first electrode, a second semiconductor layer on the first semiconductor layer, and a second electrode being transparent on the second semiconductor layer, wherein grooves exist regularly on a surface of the first semiconductor layer facing a side of the second semiconductor layer.
    Type: Application
    Filed: February 25, 2021
    Publication date: June 17, 2021
    Inventors: Yuya Honishi, Soichiro Shibasaki, Naoyuki Nakagawa, Mutsuki Yamazaki, Yoshiko Hiraoka, Kazushige Yamamoto
  • Publication number: 20210184064
    Abstract: The photoelectric conversion layer of an embodiment is based on Cu2O, contains at least one p-type dopant selected from the group consisting of Ge, Ta, and In, and has a band gap of equal to or more than 2.10 eV and equal to or less than 2.30 eV.
    Type: Application
    Filed: February 26, 2021
    Publication date: June 17, 2021
    Inventors: Kazushige Yamamoto, Mutsuki Yamazaki, Soichiro Shibasaki, Yuya Honishi, Naoyuki Nakagawa, Yoshiko Hiraoka
  • Publication number: 20210013360
    Abstract: A method for manufacturing a stacked thin film, includes forming a photoelectric conversion layer on a first transparent electrode by sputtering using a target mainly composed of copper in an oxygen containing atmosphere. An oxygen partial pressure of the sputtering is in a range of 0.01 [Pa] or more and 4.8 [Pa] or less, and 0.24×d [Pa] or more and 2.4×d [Pa] or less when a deposition rate is d [?m/min], in formation of the photoelectric conversion layer. A sputtering temperature is 300° C. or more and 600° C. or less, in formation of the photoelectric conversion layer.
    Type: Application
    Filed: September 9, 2020
    Publication date: January 14, 2021
    Applicants: KABUSHIKI KAISHA TOSHIBA, TOSHIBA ENERGY SYSTEMS & SOLUTIONS CORPORATION
    Inventors: Soichiro SHIBASAKI, Yuya HONISHI, Mutsuki YAMAZAKI, Naoyuki NAKAGAWA, Sara YOSHIO, Yoshiko HIRAOKA, Kazushige YAMAMOTO
  • Publication number: 20180083150
    Abstract: A solar cell of an embodiment includes: a first electrode; a second electrode; a light-absorbing layer interposed between the first electrode and the second electrode; a dot region interposed between the first electrode and the light-absorbing layer, the dot region including dots.
    Type: Application
    Filed: August 31, 2017
    Publication date: March 22, 2018
    Inventors: Soichiro Shibasaki, Miyuki Shiokawa, Sara Yoshio, Naoyuki Nakagawa, Yukitami Mizuno, Kohei Nakayama, Mutsuki Yamazaki, Yoshiko Hiraoka, Kazushige Yamamoto, Yuya Honishi, Takeshi Niimoto
  • Patent number: 8741504
    Abstract: A solid catalyst having a close-packed structure has basic structural units present in the surface of the solid catalyst, the basic structural units including (i) a triangular lattice constituted of atoms of platinum, ruthenium, and at least one additional element which are disposed at the vertexes in the triangular lattice so that each atom of one of the elements adjoins atoms of the other elements or (ii) a rhombic lattice constituted of atoms of platinum, ruthenium, and at least one additional element which are disposed at the vertexes in the rhombic lattice in an atomic ratio of 1:2:1 so that each ruthenium atom directly adjoins a platinum atom and an atom of the additional element; and a fuel cell includes either of the solid catalyst as an anode-side electrode catalyst.
    Type: Grant
    Filed: November 25, 2008
    Date of Patent: June 3, 2014
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Takashi Yoshida, Fumihiko Aiga, Satoshi Itoh, Yoshiko Hiraoka, Reiko Yoshimura, Tsukasa Tada
  • Patent number: 7709413
    Abstract: A solid catalyst has a close-packed structure and has a first surface layer and a second surface layer, wherein the first surface layer includes platinum as a main component and the second surface layer contains PtaXb (wherein X is one element selected from the group consisting of Zr, Hf, Nb, Ta, Mo, and W; a+b=100; and 25?b?50); and a fuel cell includes the solid catalyst as an anode-side electrode catalyst.
    Type: Grant
    Filed: November 26, 2008
    Date of Patent: May 4, 2010
    Assignee: Kabuhsiki Kaisha Toshiba
    Inventors: Takashi Yoshida, Satoshi Itoh, Fumihiko Aiga, Yoshiko Hiraoka, Reiko Yoshimura, Tsukasa Tada, Yasutaka Nishida
  • Publication number: 20090257931
    Abstract: A recovering method is provided, which includes contacting a solid component containing Ru with an aqueous solution to create a Ru compound, and causing the Ru compound to selectively elute in the aqueous solution. The aqueous solution is formed of at least one selected from the group consisting of aqueous solutions A, B, C, D, and E. The aqueous solution A comprises an acid and formic acid, alcohols, aldehydes, a compound having a hemiacetal structure or a compound having an acetal structure. The aqueous solution B comprises an acid and a compound which creates, in the coexistence thereof with the acid, formic acid, alcohols, aldehydes, a compound having a hemiacetal structure or a compound having an acetal structure. The aqueous solution C comprises an acid and sugars. The aqueous solution D comprises formic acid, and the aqueous solution E comprises oxalic acid.
    Type: Application
    Filed: June 24, 2009
    Publication date: October 15, 2009
    Inventors: Yoshihiko Nakano, Jun Tamura, Kazuhiro Yasuda, Mutsuki Yamazaki, Itsuko Mizutani, Yoshiko Hiraoka
  • Publication number: 20090137388
    Abstract: A solid catalyst has a close-packed structure and has a first surface layer and a second surface layer, wherein the first surface layer includes platinum as a main component and the second surface layer contains PtaXb (wherein X is one element selected from the group consisting of Zr, Hf, Nb, Ta, Mo, and W; a+b=100; and 25?b?50); and a fuel cell includes the solid catalyst as an anode-side electrode catalyst.
    Type: Application
    Filed: November 26, 2008
    Publication date: May 28, 2009
    Inventors: Takashi Yoshida, Satoshi Itoh, Fumihiko Aiga, Yoshiko Hiraoka, Reiko Yoshimura, Tsukasa Tada, Yasutaka Nishida
  • Publication number: 20090136826
    Abstract: A solid catalyst having a close-packed structure has basic structural units present in the surface of the solid catalyst, the basic structural units including (i) a triangular lattice constituted of atoms of platinum, ruthenium, and at least one additional element which are disposed at the vertexes in the triangular lattice so that each atom of one of the elements adjoins atoms of the other elements or (ii) a rhombic lattice constituted of atoms of platinum, ruthenium, and at least one additional element which are disposed at the vertexes in the rhombic lattice in an atomic ratio of 1:2:1 so that each ruthenium atom directly adjoins a platinum atom and an atom of the additional element; and a fuel cell includes either of the solid catalyst as an anode-side electrode catalyst.
    Type: Application
    Filed: November 25, 2008
    Publication date: May 28, 2009
    Inventors: Takashi Yoshida, Fumihiko Aiga, Satoshi Itoh, Yoshiko Hiraoka, Reiko Yoshimura, Tsukasa Tada