Abstract: A non-aqueous electrolyte secondary battery that has a low initial resistance and an increase in resistance after charging and discharging is suppressed. The secondary battery includes a positive electrode, a negative electrode, and a non-aqueous electrolyte. The positive electrode includes a positive electrode active substance layer, which contains a lithium composite oxide having a layered structure. The lithium composite oxide is a porous particle. A surface of the porous particle includes a layer having a rock salt type structure. A thickness of the layer is not less than 5 nm and not more than 80 nm. A void ratio of the porous particle is not less than 15% and not more than 48%. The porous particle contains two or more voids having diameters that are at least 10% of the particle diameter of the porous particle. The surface of the porous particle includes a coating of lithium tungstate.

Abstract: A non-aqueous electrolyte secondary battery is obtained using a lithium composite oxide having a layered structure in a positive electrode active substance. An increase in resistance following repeated charging and discharging is suppressed. The battery includes a positive electrode provided with a positive electrode active substance layer, a negative electrode and a non-aqueous electrolyte. The positive electrode active substance layer contains a porous particle lithium composite oxide having a layered structure. The average void ratio of the porous particle is not less than 12% but not more than 50%, and it contains two or more voids having diameters that are at least 8% of its particle diameter. The surface of the porous particle is provided with a coating of lithium tungstate. The coverage ratio of the surface of the porous particle by the lithium tungstate is not less than 10% but not more than 65%.

Abstract: The present disclosure provides a positive electrode active material having a spinel-type crystal structure that can reduce an increase in resistance and a decrease in capacity retention rate due to repeated charging and discharging of a non-aqueous electrolyte secondary battery. The positive electrode active material disclosed herein is configured of a lithium manganese composite oxide having a spinel-type crystal structure, wherein the lithium manganese composite oxide includes secondary particles in which a plurality of primary particles are aggregated, an average particle diameter of the secondary particles based on a SEM image is 10 ?m or more and 20 ?m or less, an average particle diameter of the primary particles based on a SEM image is 4 ?m or more and 8 ?m or less, and nickel atoms are provided in the surface layer portion of the secondary particles.

Abstract: A non-aqueous electrolyte secondary battery is obtained using a lithium composite oxide having a layered structure in a positive electrode active substance. An increase in resistance following repeated charging and discharging is suppressed. The battery includes a positive electrode provided with a positive electrode active substance layer, a negative electrode and a non-aqueous electrolyte. The positive electrode active substance layer contains a porous particle lithium composite oxide having a layered structure. The average void ratio of the porous particle is not less than 12% but not more than 50%, and it contains two or more voids having diameters that are at least 8% of its particle diameter. The surface of the porous particle is provided with a coating of lithium tungstate. The coverage ratio of the surface of the porous particle by the lithium tungstate is not less than 10% but not more than 65%.

Abstract: A non-aqueous electrolyte secondary battery which is obtained using a lithium composite oxide having a layered structure and coated with a tungsten-containing compound in a positive electrode active substance, and which has a low initial resistance, and in which an increase in resistance following repeated charging and discharging is suppressed. The non-aqueous electrolyte secondary battery includes a positive electrode, a negative electrode and a non-aqueous electrolyte. The positive electrode includes a positive electrode active substance layer containing a lithium composite oxide having a layered structure. The lithium composite oxide includes a porous particle having a void ratio of not less than 20% but not more than 50%. The porous particle contains two or more voids having diameters that are at least 10% of the particle diameter of the porous particle. The surface of the porous particle is provided with a coating containing tungsten oxide and lithium tungstate.

Abstract: A non-aqueous electrolyte secondary battery which is obtained using a lithium composite oxide having a layered structure and coated with a tungsten-containing compound in a positive electrode active substance, and which has a low initial resistance, and in which an increase in resistance following repeated charging and discharging is suppressed. The non-aqueous electrolyte secondary battery includes a positive electrode, a negative electrode and a non-aqueous electrolyte. The positive electrode includes a positive electrode active substance layer containing a lithium composite oxide having a layered structure. The lithium composite oxide includes a porous particle having a void ratio of not less than 20% but not more than 50%. The porous particle contains two or more voids having diameters that are at least 10% of the particle diameter of the porous particle. The surface of the porous particle is provided with a coating containing tungsten oxide and lithium tungstate.

Abstract: Provided is a nonaqueous electrolyte secondary battery with a positive electrode active material that contains an excess of Li and has a layered structure, the nonaqueous electrolyte secondary battery having a high output and enabling prevention of gelation of the positive electrode active material layer-forming paste during production. The herein disclosed nonaqueous electrolyte secondary battery includes a positive electrode, a negative electrode, and a nonaqueous electrolyte. The positive electrode includes a positive electrode active material layer. The positive electrode active material layer contains a lithium composite oxide having a layered structure as a positive electrode active material. The compositional ratio of the lithium atom to the metal atom other than a lithium atom contained in the lithium composite oxide is greater than 1. The lithium composite oxide is in the form of porous particles.

Abstract: A nonaqueous electrolyte secondary battery is provided which is suppressed in capacity deterioration upon repeating charging and discharging irrespective of cracks being formed in a lithium manganese oxide particle having a spinel type crystal structure. The nonaqueous electrolyte secondary battery herein disclosed includes a positive electrode, a negative electrode, and a nonaqueous electrolyte. The positive electrode includes a positive electrode active material layer. The positive electrode active material layer includes lithium manganese oxide particles having a spinel type crystal structure as the positive electrode active material. At least a part of the lithium manganese oxide particles has a cracked part. The lithium manganese oxide particles have a coating film on the particle surface including the surface of the cracked part. The coating film contains a P component including a LiMnPO4 component, and a F component.

Abstract: The present disclosure provides a positive electrode active material having a spinel-type crystal structure that can reduce an increase in resistance and a decrease in capacity retention rate due to repeated charging and discharging of a non-aqueous electrolyte secondary battery. The positive electrode active material disclosed herein is configured of a lithium manganese composite oxide having a spinel-type crystal structure, wherein the lithium manganese composite oxide includes secondary particles in which a plurality of primary particles are aggregated, an average particle diameter of the secondary particles based on a SEM image is 10 ?m or more and 20 ?m or less, an average particle diameter of the primary particles based on a SEM image is 4 ?m or more and 8 ?m or less, and nickel atoms are provided in the surface layer portion of the secondary particles.

Abstract: A positive electrode active material contains at least: fluorine in an amount not lower than 0.08 mass %; carbon in an amount not lower than 0.02 mass %; and lithium-metal composite oxide particles making up the remainder. The lithium-metal composite oxide particles contain nickel in an amount not lower than 60 mol % of the total amount of metallic elements. At least a partial amount of each of the fluorine and the carbon is present on surfaces of the lithium-metal composite oxide particles.

Abstract: When spinel-type lithiated cobalt oxide is employed for a cathode active material for a lithium ion battery, a sufficient discharge capacity is not always obtained. Thus, spinel-type lithiated cobalt oxide is doped with at least chromium, and specifically, a cathode active material for a lithium ion battery includes a spinel-type crystal phase including lithium, cobalt, chromium and oxygen, and the cathode active material has a composition represented by LiCoxCryMzO2±? where M is at least one selected from Al and Mn, and 0.85?x<1, 0<y?0.15, 0?z, and 0.85<x+y+z?1.2.

Abstract: The present disclosure can bring excellent output characteristics to a nonaqueous electrolyte secondary battery that uses a cathode active material containing tungsten while desired durability is secured. The battery of the present disclosure includes a cathode, an anode, and a nonaqueous electrolyte. The cathode includes a cathode active material layer that contains a granular cathode active material. The cathode active material includes a core part that contains a lithium-transition metal composite oxide of a layered structure; a tungsten-concentrated layer that is formed over a surface of the core part and has a higher tungsten concentration than in the core part; and a lithium-tungsten compound particle that adheres to at least part of a surface of the tungsten-concentrated layer and contains tungsten and lithium. In the battery of the present disclosure, the tungsten-concentrated layer has an amorphous structure. This can bring excellent output characteristics while desired durability is secured.

Abstract: A non-aqueous electrolyte secondary battery which is obtained using a lithium composite oxide having a layered structure and coated with a tungsten-containing compound in a positive electrode active substance, and which has a low initial resistance, and in which an increase in resistance following repeated charging and discharging is suppressed. The non-aqueous electrolyte secondary battery includes a positive electrode, a negative electrode and a non-aqueous electrolyte. The positive electrode includes a positive electrode active substance layer containing a lithium composite oxide having a layered structure. The lithium composite oxide includes a porous particle having a void ratio of not less than 20% but not more than 50%. The porous particle contains two or more voids having diameters that are at least 10% of the particle diameter of the porous particle. The surface of the porous particle is provided with a coating containing tungsten oxide and lithium tungstate.

Abstract: A nonaqueous electrolyte secondary battery uses, as a positive electrode active material, a lithium composite oxide having a layered structure and coated with lithium tungstate, and has a low resistance. The nonaqueous electrolyte secondary battery includes positive and negative electrodes and a nonaqueous electrolyte. The positive electrode includes a positive electrode active material layer containing a lithium composite oxide having a layered structure as a positive electrode active material. The lithium composite oxide is in the form of porous particles, each having at least two voids each having a percentage of a void area with respect to the area occupied by each of the particles in its cross-sectional view of at least 1%. Each porous particle has a void connecting the particle interior to the surface and having an opening with a diameter of at least 100 nm. Each porous particle has a lithium tungstate coating on its surface.

Abstract: A non-aqueous electrolyte secondary battery is obtained using a lithium composite oxide having a layered structure in a positive electrode active substance. An increase in resistance following repeated charging and discharging is suppressed. The battery includes a positive electrode provided with a positive electrode active substance layer, a negative electrode and a non-aqueous electrolyte. The positive electrode active substance layer contains a porous particle lithium composite oxide having a layered structure. The average void ratio of the porous particle is not less than 12% but not more than 50%, and it contains two or more voids having diameters that are at least 8% of its particle diameter. The surface of the porous particle is provided with a coating of lithium tungstate. The coverage ratio of the surface of the porous particle by the lithium tungstate is not less than 10% but not more than 65%.

Abstract: A non-aqueous electrolyte secondary battery that has a low initial resistance and an increase in resistance after charging and discharging is suppressed. The secondary battery includes a positive electrode, a negative electrode, and a non-aqueous electrolyte. The positive electrode includes a positive electrode active substance layer, which contains a lithium composite oxide having a layered structure. The lithium composite oxide is a porous particle. A surface of the porous particle includes a layer having a rock salt type structure. A thickness of the layer is not less than 5 nm and not more than 80 nm. A void ratio of the porous particle is not less than 15% and not more than 48%. The porous particle contains two or more voids having diameters that are at least 10% of the particle diameter of the porous particle. The surface of the porous particle includes a coating of lithium tungstate.

Abstract: Provided is a nonaqueous electrolyte secondary battery with a positive electrode active material that contains an excess of Li and has a layered structure, the nonaqueous electrolyte secondary battery having a high output and enabling prevention of gelation of the positive electrode active material layer-forming paste during production. The herein disclosed nonaqueous electrolyte secondary battery includes a positive electrode, a negative electrode, and a nonaqueous electrolyte. The positive electrode includes a positive electrode active material layer. The positive electrode active material layer contains a lithium composite oxide having a layered structure as a positive electrode active material. The compositional ratio of the lithium atom to the metal atom other than a lithium atom contained in the lithium composite oxide is greater than 1. The lithium composite oxide is in the form of porous particles.

Abstract: A negative electrode active substance material used for an electricity storage device of the present disclosure includes a silicon phase and a silicide phase represented by a basic composition formula MSi2, where M is one or more of Cr, Ti, Zr, Nb, Mo, and Hf. The negative electrode active substance material may have a structure in which the silicide phase is dispersed in the silicon phase.

Abstract: When spinel-type lithiated cobalt oxide is employed for a cathode active material for a lithium ion battery, a sufficient discharge capacity is not always obtained. Thus, spinel-type lithiated cobalt oxide is doped with at least chromium, and specifically, a cathode active material for a lithium ion battery includes a spinel-type crystal phase including lithium, cobalt, chromium and oxygen, and the cathode active material has a composition represented by LiCoxCryMzO2±? where M is at least one selected from Al and Mn, and 0.85?x<1, 0<y?0.15, 0?z, and 0.85<x+y+z?1.

Abstract: A positive electrode active material contains at least: fluorine in an amount not lower than 0.08 mass %; carbon in an amount not lower than 0.02 mass %; and lithium-metal composite oxide particles making up the remainder. The lithium-metal composite oxide particles contain nickel in an amount not lower than 60 mol % of the total amount of metallic elements. At least a partial amount of each of the fluorine and the carbon is present on surfaces of the lithium-metal composite oxide particles.