Patents by Inventor Yoshinori Nishiki
Yoshinori Nishiki has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11519082Abstract: An organic hydride production apparatus includes: an electrolyte membrane having proton conductivity; a cathode that includes a cathode catalyst layer used to hydrogenate a hydrogenation target substance using protons to produce an organic hydride and also includes a cathode chamber; an anode that includes an anode catalyst layer used to oxidize water to produce protons and also includes an anode chamber; and a gas introduction unit that introduces, into the anolyte at a certain position, a certain gas used to remove at least one of the hydrogenation target substance and the organic hydride that have passed through the electrolyte membrane and been mixed into the anolyte.Type: GrantFiled: May 15, 2019Date of Patent: December 6, 2022Assignees: NATIONAL UNIVERSITY CORPORATION YOKOHAMA NATIONAL UNIVERSITY, DE NORA PERMELEC LTD.Inventors: Shigenori Mitsushima, Kensaku Nagasawa, Yoshinori Nishiki, Akihiro Kato, Setsuro Ogata, Awaludin Zaenal, Akiyoshi Manabe, Koji Matsuoka, Yasushi Sato
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Publication number: 20220333257Abstract: An organic hydride production apparatus includes: an electrolyte membrane having proton conductivity; a cathode, provided on one side of the electrolyte membrane, that contains a cathode catalyst used to hydrogenate a hydrogenation target substance using protons to produce an organic hydride; an anode, provided opposite to the one side of the electrolyte membrane, that contains an anode catalyst used to oxidize water to produce protons; and an anode support, provided opposite to the electrolyte membrane side of the anode, that supports the anode. The anode support is formed of an elastic porous body of which the Young's modulus is greater than 0.1 N/mm2 and less than 43 N/mm2.Type: ApplicationFiled: July 6, 2022Publication date: October 20, 2022Applicants: National University Corporation YOKOHAMA National University, DE NORA PERMELEC LTDInventors: Shigenori MITSUSHIMA, Kensaku NAGASAWA, Yoshinori NISHIKI, Setsuro OGATA, Akihiro KATO, Awaludin ZAENAL, Koji MATSUOKA, Yasushi SATO
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Publication number: 20220242757Abstract: An apparatus (100) for producing an acidic aqueous solution includes: an electrodialyzer (110) that has a monovalent ion perm-selective ion-exchange membrane and separates wastewater containing chloride ions and alkali metal ions into electrodialysis concentrated water and electrodialysis diluted water by an electrodialysis treatment; an electrolyzer (120) includes an anode that that electrolyzes the electrodialysis concentrated water to produce an acidic aqueous solution; and a first circulator (13) that circulates at least some of the acidic aqueous solution to the wastewater supplied to the electrodialyzer (110), and that adjusts a pH of the wastewater supplied to the electrodialyzer to 3 to 9.Type: ApplicationFiled: September 4, 2020Publication date: August 4, 2022Applicant: DE NORA PERMELEC LTDInventors: Manabu OZAWA, Yoshinori NISHIKI, Masaaki KATO, Rie MORITA
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Patent number: 11236428Abstract: To provide an electrolysis cell for producing an organic chemical hydride capable of advancing a reduction reaction in a cathode of an organic compound having an unsaturated bond with high current efficiency and a small electric power consumption unit.Type: GrantFiled: September 18, 2015Date of Patent: February 1, 2022Assignees: NATIONAL UNIVERSITY CORPORATION YOKOHAMA NATIONAL UNIVERSITY, DE NORA PERMELEC LTD.Inventors: Shigenori Mitsushima, Yasutomo Takakuwa, Yoshinori Nishiki, Akihiro Kato, Akiyoshi Manabe
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Patent number: 11035045Abstract: An organic hydride production apparatus that enables the reduction reaction at the cathode of an organic compound having an unsaturated bond to proceed at high current efficiency and at a low electric power consumption rate, and a method for producing an organic hydride that uses this production apparatus.Type: GrantFiled: November 19, 2015Date of Patent: June 15, 2021Assignees: NATIONAL UNIVERSITY CORPORATION YOKOHAMA NATIONAL UNIVERSITY, DE NORA PERMELEC LTD.Inventors: Shigenori Mitsushima, Yasutomo Takakuwa, Yoshinori Nishiki, Akihiro Kato, Akiyoshi Manabe
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Publication number: 20200407860Abstract: The present invention provides an electrode for electrolysis in which electrolysis performance is hard to deteriorate and excellent catalytic activity is kept stable over a long period of time even when electric power in which there is a large fluctuation in output, such as renewable energy, is used as a power source. The electrode for electrolysis is an electrode 10 for electrolysis provided with an electrically conductive substrate 2 at least the surface of which contains nickel or a nickel-based alloy, an intermediate layer 4 formed on the surface of the electrically conductive substrate 2 and containing a lithium-containing nickel oxide represented by composition formula LixNi2-xO2 (0.02?x?0.5), and a catalyst layer 6 of a nickel cobalt spinel oxide, an iridium oxide, or the like, the catalyst layer 6 formed on the surface of the intermediate layer 4.Type: ApplicationFiled: March 4, 2019Publication date: December 31, 2020Inventors: Shigenori MITSUSHIMA, Yoshiyuki KURODA, Ikuo NAGASHIMA, Tatsuya TANIGUCHI, Yoshinori NISHIKI, Akihiro KATO, Awaludin ZAENAL, Fumiya TSUJII, Takaaki NAKAI
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Patent number: 10676832Abstract: Provided is a method capable of producing, in a simple and low-cost manner, an electrolysis electrode which can be used in alkaline water electrolysis and has superior durability against output variation. The method for producing an anode for alkaline water electrolysis includes: a step of dissolving lithium nitrate and a nickel carboxylate in water to prepare an aqueous solution containing lithium ions and nickel ions, a step of applying the aqueous solution to the surface of a conductive substrate having at least the surface composed of nickel or a nickel-based alloy, and a step of subjecting the conductive substrate to which the aqueous solution has been applied to a heat treatment at a temperature within a range from at least 450° C. to not more than 600° C., thereby forming a catalyst layer composed of a lithium-containing nickel oxide on the conductive substrate.Type: GrantFiled: September 11, 2017Date of Patent: June 9, 2020Assignees: DE NORA PERMELEC LTD, NATIONAL UNIVERSITY CORPORATION YOKOHAMA NATIONAL UNIVERSITY, KAWASAKI JUKOGYO KABUSHIKI KAISHAInventors: Shigenori Mitsushima, Sho Fujita, Ikuo Nagashima, Yoshinori Nishiki, Akiyoshi Manabe, Akihiro Kato
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Publication number: 20200080212Abstract: An organic hydride production apparatus includes: an electrolyte membrane having proton conductivity; a cathode, provided on one side of the electrolyte membrane, that contains a cathode catalyst used to hydrogenate a hydrogenation target substance using protons to produce an organic hydride; an anode, provided opposite to the one side of the electrolyte membrane, that contains an anode catalyst used to oxidize water to produce protons; and an anode support, provided opposite to the electrolyte membrane side of the anode, that supports the anode. The anode support is formed of an elastic porous body of which the Young's modulus is greater than 0.1 N/mm2 and less than 43 N/mm2.Type: ApplicationFiled: November 18, 2019Publication date: March 12, 2020Applicants: National University Corporation YOKOHAMA National University, DE NORA PERMELEC LTDInventors: Shigenori MITSUSHIMA, Kensaku NAGASAWA, Yoshinori NISHIKI, Setsuro OGATA, Akihiro KATO, Awaludin ZAENAL, Koji MATSUOKA, Yasushi SATO
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Publication number: 20190352786Abstract: An organic hydride production apparatus includes: an electrolyte membrane having proton conductivity; a cathode that includes a cathode catalyst layer used to hydrogenate a hydrogenation target substance using protons to produce an organic hydride and also includes a cathode chamber; an anode that includes an anode catalyst layer used to oxidize water to produce protons and also includes an anode chamber; and a gas introduction unit that introduces, into the anolyte at a certain position, a certain gas used to remove at least one of the hydrogenation target substance and the organic hydride that have passed through the electrolyte membrane and been mixed into the anolyte.Type: ApplicationFiled: October 18, 2017Publication date: November 21, 2019Applicants: National University Corporation YOKOHAMA National University, DE NORA PERMELEC LTDInventors: Shigenori MITSUSHIMA, Kensaku NAGASAWA, Yoshinori NISHIKI, Akihiro KATO, Setsuro OGATA, Awaludin ZAENAL, Akiyoshi MANABE, Koji MATSUOKA, Yasushi SATO
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Publication number: 20190264340Abstract: An organic hydride production apparatus includes: an electrolyte membrane having proton conductivity; a cathode that includes a cathode catalyst layer used to hydrogenate a hydrogenation target substance using protons to produce an organic hydride and also includes a cathode chamber; an anode that includes an anode catalyst layer used to oxidize water to produce protons and also includes an anode chamber; and a gas introduction unit that introduces, into the anolyte at a certain position, a certain gas used to remove at least one of the hydrogenation target substance and the organic hydride that have passed through the electrolyte membrane and been mixed into the anolyte.Type: ApplicationFiled: May 15, 2019Publication date: August 29, 2019Applicants: National University Corporation YOKOHAMA National University, DE NORA PERMELEC LTDInventors: Shigenori MITSUSHIMA, Kensaku NAGASAWA, Yoshinori NISHIKI, Akihiro KATO, Setsuro OGATA, Awaludin ZAENAL, Akiyoshi MANABE, Koji MATSUOKA, Yasushi SATO
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Publication number: 20190226102Abstract: Provided is a method capable of producing, in a simple and low-cost manner, an electrolysis electrode which can be used in alkaline water electrolysis and has superior durability against output variation. The method for producing an anode for alkaline water electrolysis includes: a step of dissolving lithium nitrate and a nickel carboxylate in water to prepare an aqueous solution containing lithium ions and nickel ions, a step of applying the aqueous solution to the surface of a conductive substrate having at least the surface composed of nickel or a nickel-based alloy, and a step of subjecting the conductive substrate to which the aqueous solution has been applied to a heat treatment at a temperature within a range from at least 450° C. to not more than 600° C., thereby forming a catalyst layer composed of a lithium-containing nickel oxide on the conductive substrate.Type: ApplicationFiled: September 11, 2017Publication date: July 25, 2019Inventors: Shigenori MITSUSHIMA, Sho FUJITA, Ikuo NAGASHIMA, Yoshinori NISHIKI, Akiyoshi MANABE, Akihiro KATO
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Patent number: 10202698Abstract: A device for producing an organic hydride 10 of an aspect of the present invention has an electrochemical cell provided with an anode 12 on a surface of an electrolyte membrane 11 and a cathode including a cathode catalyst layer 13 and a cathode diffusion layer 14 on another surface of the electrolyte membrane 11. A gap is provided between the anode 12 and the electrolyte membrane 11. The anode 12 has a network structure with an aperture ratio of 30 to 70%, and has an electrical supply supporting material formed of an electronic conductor and the electrode catalyst held by the electrical supply supporting material.Type: GrantFiled: March 24, 2015Date of Patent: February 12, 2019Assignees: Yokohama National University, DE NORA PERMELEC LTDInventors: Shigenori Mitsushima, Yasutomo Takakuwa, Yoshinori Nishiki, Akihiro Kato, Akiyoshi Manabe, Yasushi Sato, Kota Miyoshi, Kojiro Nakagawa, Shinji Oshima
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Patent number: 9896774Abstract: A three-compartment cell for production of oxidising disinfectant solutions is provided. The intermediate compartment of the cell is separated from the anodic compartment by a fibrous diaphragm in intimate contact with an anion-exchange membrane.Type: GrantFiled: September 15, 2014Date of Patent: February 20, 2018Assignee: INDUSTRIE DE NORA S.P.A.Inventors: Mariachiara Benedetto, Yoshinori Nishiki
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Patent number: 9890062Abstract: An electrolytic enrichment method for heavy water includes enriching heavy water by electrolysis using an alkaline water electrolysis cell including an anode chamber that holds an anode, a cathode chamber that holds a cathode, and a diaphragm.Type: GrantFiled: July 24, 2014Date of Patent: February 13, 2018Assignee: INDUSTRIE DE NORA S.P.A.Inventors: Akiyoshi Manabe, Yoshinori Nishiki, Akira Kunimatsu
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Patent number: 9818496Abstract: The present invention relates to a method for treating tritium water-containing raw water, the method including supplying a part of raw water containing tritium water and alkali water to a circulation tank, mixing the raw water with alkali water in the circulation tank to obtain an electrolyte adjusted so as to have a desired alkali concentration, and continuously electrolyzing the electrolyte while circulating the electrolyte, thereby subjecting the raw water stored in the storage tank to alkali water electrolysis and thus gasifying the raw water. According to the invention, by gasifying tritium water-containing raw water by alkali water electrolysis, the tritium concentration in a tritium-containing hydrogen gas is diluted to 1/1,244 and the tritium water-containing raw water can be reduced in volume.Type: GrantFiled: January 28, 2015Date of Patent: November 14, 2017Assignee: DE NORA PERMELEC LTDInventors: Akiyoshi Manabe, Masahiro Ohara, Yoshinori Nishiki, Akira Kunimatsu
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Publication number: 20170314145Abstract: An organic hydride production apparatus that enables the reduction reaction at the cathode of an organic compound having an unsaturated bond to proceed at high current efficiency and at a low electric power consumption rate, and a method for producing an organic hydride that uses this production apparatus.Type: ApplicationFiled: November 19, 2015Publication date: November 2, 2017Applicants: NATIONAL UNIVERSITY CORPORATION YOKOHAMA NATIONAL UNIVERSITY, DE NORA PERMELEC LTD.Inventors: Shigenori MITSUSHIMA, Yasutomo TAKAKUWA, Yoshinori NISHIKI, Akihiro KATO, Akiyoshi MANABE
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Publication number: 20170292198Abstract: To provide an electrolysis cell for producing an organic chemical hydride capable of advancing a reduction reaction in a cathode of an organic compound having an unsaturated bond with high current efficiency and a small electric power consumption unit.Type: ApplicationFiled: September 18, 2015Publication date: October 12, 2017Applicants: NATIONAL UNIVERSITY CORPORATION YOKOHAMA NATIONAL UNIVERSITY, De Nora Permelec Ltd.Inventors: Shigenori MITSUSHIMA, Yasutomo TAKAKUWA, Yoshinori NISHIKI, Akihiro KATO, Akiyoshi MANABE
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Publication number: 20170206991Abstract: The present invention relates to a method for treating tritium water-containing raw water, the method including supplying a part of raw water containing tritium water and alkali water to a circulation tank, mixing the raw water with alkali water in the circulation tank to obtain an electrolyte adjusted so as to have a desired alkali concentration, and continuously electrolyzing the electrolyte while circulating the electrolyte, thereby subjecting the raw water stored in the storage tank to alkali water electrolysis and thus gasifying the raw water. According to the invention, by gasifying tritium water-containing raw water by alkali water electrolysis, the tritium concentration in a tritium-containing hydrogen gas is diluted to 1/1,244 and the tritium water-containing raw water can be reduced in volume.Type: ApplicationFiled: January 28, 2015Publication date: July 20, 2017Applicant: De Nora Permelec Ltd.Inventors: Akiyoshi MANABE, Masahiro OHARA, Yoshinori NISHIKI, Akira KUNIMATSU
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Publication number: 20170130344Abstract: A device for producing an organic hydride 10 of an aspect of the present invention has an electrochemical cell provided with an anode 12 on a surface of an electrolyte membrane 11 and a cathode including a cathode catalyst layer 13 and a cathode diffusion layer 14 on another surface of the electrolyte membrane 11. A gap is provided between the anode 12 and the electrolyte membrane 11. The anode 12 has a network structure with an aperture ratio of 30 to 70%, and has an electrical supply supporting material formed of an electronic conductor and the electrode catalyst held by the electrical supply supporting material.Type: ApplicationFiled: March 24, 2015Publication date: May 11, 2017Inventors: Shigenori MITSUSHIMA, Yasutomo TAKAKUWA, Yoshinori NISHIKI, Akihiro KATO, Akiyoshi MANABE, Yasushi SATO, Kota MIYOSHI, Kojiro NAKAGAWA, Shinji OSHIMA
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Publication number: 20160368789Abstract: An electrolytic enrichment method for heavy water includes enriching heavy water by electrolysis using an alkaline water electrolysis cell including an anode chamber that holds an anode, a cathode chamber that holds a cathode, and a diaphragm.Type: ApplicationFiled: July 24, 2014Publication date: December 22, 2016Inventors: Akiyoshi MANABE, Yoshinori NISHIKI, Akira KUNIMATSU