Abstract: A chromate-free coated metal sheet according to the present invention includes: a metal sheet; and a coating film ? which contains an organic resin A as a film formation component and a flaky aluminum pigment C having a deactivation-treated surface on at least one surface of the metal sheet; wherein the thickness of the coating film ? is in a range of 1.5 to 10 ?m.

Abstract: A surface-treated steel sheet includes: a steel sheet; and a coated layer which is formed on one surface or both surfaces of the steel sheet and includes zinc and vanadium, wherein the coated layer has a vanadium content of 1% or higher and 20% or less and a coating weight of 3 g/m2 or higher and 40 g/m2 or less, and has a plurality of dendritic arms that are grown in a thickness direction of the steel sheet, and a ratio x/y of a content x of vanadium that is present outside the arms to a content y of vanadium that is present inside the arms is 1.1 or higher and 3.0 or less in terms of vanadium element.

Abstract: This surface-treated metal includes a metal, and a coated material on a surface of the metal, in which an outermost layer is a photocatalytic film that contains particles showing photocatalytic activity and an organic-inorganic composite resin, a volume ratio of the particles to the film is in a range from 0.5 to 50 vol %, the resin contains a siloxane bond and at least one group selected from the group consisting of an aryl group, a carboxyl group, an amino group, a hydroxyl group, and an alkyl group having 1 to 12 carbon atoms, the coated material has concaves on a surface thereof on the outermost layer side, an area of the outermost layer is 50% to 98% of an area of a surface of the metal, and a surface area of the outermost layer is 101% to 5000% of the area of the surface of the metal.

Abstract: A chromate-free coated metal sheet according to the present invention includes: a metal sheet; and a coating film ? which contains an organic resin A as a film formation component and a flaky aluminum pigment C having a deactivation-treated surface on at least one surface of the metal sheet; wherein the thickness of the coating film ? is in a range of 2 to 10 ?m.

Abstract: This surface-treated metal includes a metal, and a coated material that is formed on a surface of the metal, in which an outermost layer of the coated material is a photocatalytic film that contains particles showing photocatalytic activity and an organic-inorganic composite resin, a volume ratio of the particles showing photocatalytic activity to the photocatalytic film is in a range from 0.5 vol % to 50 vol %, the organic-inorganic composite resin contains a siloxane bond and at least one group selected from the group consisting of an aryl group, a carboxyl group, an amino group, a hydroxyl group, and an alkyl group having 1 to 12 carbon atoms, the coated material has concaves on a surface thereof on the outermost layer side, an area of the outermost layer is 50% to 98% of an area of a surface of the metal when the coated material is seen in a plan view, and a surface area of the outermost layer is 101% to 5000% of the area of the surface of the metal.

Abstract: A surface-treated metal material of the present invention has a composite film on the surface of a metal material. The composite film includes an organic silicon compound (W) having cyclic siloxane bonds, at least one metal compound (X) selected from a group consisting of a titanium compound and a zirconium compound, a phosphate compound (Y) and a fluorine compound (Z). In each of the components of the composite film, the ratio of XS/WS is from 0.06 to 0.16, where WS is a solid mass of Si derived from the organic silicon compound (W) and XS is a solid mass of at least one metal component selected from a group consisting of Ti and Zr included in the metal compound (X); the ratio of YS/WS is from 0.15 to 0.31, where WS is the solid mass of Si and YS is a solid mass of P derived from the phosphate compound (Y); and the ratio of ZS/WS is from 0.08 to 0.50, where WS is the solid mass of Si and ZS is a solid mass of F derived from the fluorine compound (Z).

Abstract: A surface-treated steel sheet includes: a steel sheet; and a coated layer which is formed on one surface or both surfaces of the steel sheet and includes zinc and vanadium, wherein the coated layer has a vanadium content of 1% or higher and 20% or less and a coating weight of 3 g/m2 or higher and 40 g/m2 or less, and has a plurality of dendritic arms that are grown in a thickness direction of the steel sheet, and a ratio x/y of a content x of vanadium that is present outside the arms to a content y of vanadium that is present inside the arms is 1.1 or higher and 3.0 or less in terms of vanadium element.

Abstract: The present invention provides a composite coated zinc-containing plated steel material different from the plated steel materials treated by conventional chromate replacement technologies and superior in all of corrosion resistance, blackening resistance, coating adhesion, and alkali resistance. The composite coated zinc-containing plated steel material of the present invention is characterized by having a composite coating formed by coating and drying on the surface of a plated steel material a treatment solution containing a basic zirconium compound, vanadyl (VO2+)-containing compound, phosphoric acid compound, cobalt compound, organic acid, and water and having a pH 7 to 14, the composite coating containing, with respect to the Zr element as 100 parts by mass, V in an amount of 10 to 45 parts by mass, P in 5 to 100 parts by mass, Co in 0.1 to 20 parts by mass, and an organic acid in 10 to 90 parts by mass.

Abstract: This surface-treated metal material includes a composite film obtained by applying a metal surface treatment agent on a surface of a metal material and drying the metal surface treatment agent, the metal surface treatment agent containing: an organic silicon compound (W) obtained by combining a silane coupling agent (A) containing one amino group in a molecule and one glycidyl group in a molecule, at a solid content mass ratio [(A)/(B)] of 0.7 to 1.7; at least one kind of fluorine compound (X) selected from titanium hydrofluoric acid and zirconium hydrofluoric acid; a phosphoric acid (Y); a vanadium compound (Z); and at least one kind of lubricant (J).

Abstract: This surface-treated metal material includes a composite film obtained by applying a metal surface treatment agent on a surface of a metal material and drying the metal surface treatment agent, the metal surface treatment agent containing: an organic silicon compound (W) obtained by combining a silane coupling agent (A) containing one amino group in a molecule and one glycidyl group in a molecule, at a solid content mass ratio [(A)/(B)] of 0.7 to 1.7; at least one kind of fluorine compound (X) selected from titanium hydrofluoric acid and zirconium hydrofluoric acid; a phosphoric acid (Y); a vanadium compound (Z); and at least one kind of lubricant (J).

Abstract: The present invention provides a composite coated zinc-containing plated steel material different from the plated steel materials treated by conventional chromate replacement technologies and superior in all of corrosion resistance, blackening resistance, coating adhesion, and alkali resistance. The composite coated zinc-containing plated steel material of the present invention is characterized by having a composite coating formed by coating and drying on the surface of a plated steel material a treatment solution containing a basic zirconium compound, vanadyl (VO2+)-containing compound, phosphoric acid compound, cobalt compound, organic acid, and water and having a pH7 to 14, the composite coating containing, with respect to the Zr element as 100 mass %, V in an amount of 10 to 45 mass %, P in 5 to 100 mass %, Co in 0.1 to 20 mass %, and an organic acid in 10 to 90 mass %.

Abstract: The present invention provides a metal material given a chrome-free surface treatment satisfying all of the requirements of corrosion resistance, heat resistance, fingermark resistance, conductivity, coatability, and blackening resistance at the time of working, which was difficult to achieve with conventional chromate-free technology. The chromate-free surface treated metal material of the present invention is comprised of a metal material on the surface of which is coated and dried an aqueous metal surface treatment agent comprising an organic silicon compound (W), obtained by blending a silane coupling agent (A) containing one amino group in its molecule and a silane coupling agent (B) containing one glycidyl group in its molecule in a solid weight ratio [(A)/(B)] of 0.5 to 1.7, at least one type of fluorocompound (X) selected from fluorotitanic acid or fluorozirconic acid, phosphoric acid (Y), and a vanadium compound (Z) so as to form a composite coating containing the different ingredients.