Patents by Inventor Yoshiyuki Asahina
Yoshiyuki Asahina has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 8952120Abstract: An isocyanurate type polyisocyanate composition which is derived from an aliphatic diisocyanate monomer and an alcohol and satisfies all of the following requirements when it contains substantially no aliphatic diisocyanate monomer and substantially no solvent: 1) the viscosity at 25° C. is 500-1,500 mPa·s; 2) the isocyanurate trimer concentration is 60-95 mass %; 3) when the number of allophanate bonds is expressed as A and the number of isocyanurate bonds is expressed as B, the proportion of the allophanate bonds, a=(A/(A+B))×100, is 1-30%; and 4) when the number of urethodione bonds is expressed as D, the proportion of the urethodione bonds, d=(D/(B+D))×100, is less than 2%.Type: GrantFiled: September 21, 2006Date of Patent: February 10, 2015Assignee: Asahi Kasei Chemicals CorporationInventors: Yoshiyuki Asahina, Masakazu Yamauchi
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Patent number: 8940853Abstract: Blocked polyisocyanates, obtained by using a polyisocyanate derived from an aliphatic and/or an alicyclic diisocyanate monomer, as a precursor, and including both of a blocked isocyanate group blocked with a pyrazole compound and a cationic group neutralized with an anion, in one molecule thereof; methods for making and using such blocked polyisocyanates; and compositions of matter including such blocked polyisocyanates.Type: GrantFiled: March 16, 2011Date of Patent: January 27, 2015Assignee: Asahi Kasei Chemicals CorporationInventors: Yoshiyuki Asahina, Michiaki Sasahira
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Patent number: 8772434Abstract: Disclosed is a block polyisocyanate obtained by blocking at least a part of isocyanate groups of a polyisocyanate, which is derived from an aliphatic diisocyanate and a polyol and satisfies all of the conditions (1)-(5) shown below, with a pyrazole compound. (1) Average number of isocyanate groups: 3.0-20 (2) Diisocyanate monomer trimer concentration: 10-50% by mass (3) Isocyanate group concentration: 5-22% by mass (4) Polyol content concentration: 5-40% by mass (5) Diisocyanate monomer concentration: 3% by mass or less.Type: GrantFiled: December 12, 2008Date of Patent: July 8, 2014Assignee: Asahi Kasei Chemicals CorporationInventors: Yoshiyuki Asahina, Mio Minakawa
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Publication number: 20120238697Abstract: [Problem] There are provided a blocked polyisocyanate capable of imparting long-term water resistance and water repellency to a base material, and excellent in low-temperature curability and storage stability, and an aqueous composition containing the same. [Solution] The blocked polyisocyanate has both of a blocked isocyanate group blocked with a pyrazole compound and a cationic group neutralized with an anion, in one molecule thereof.Type: ApplicationFiled: March 16, 2011Publication date: September 20, 2012Applicant: ASAHI KASEI CHEMICALS CORPORATIONInventors: Yoshiyuki ASAHINA, Michiaki SASAHIRA
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Patent number: 8148488Abstract: Disclosed is a polyisocyanate composition which is excellent in both curability and drying characteristic. The polyisocyanate composition contains at least one compound selected from aliphatic diisocyanates, at least one compound selected from alicyclic diisocyanates and at least one compound selected from polyols, while satisfying all of the following conditions; i) the diisocyanate monomer concentration is not more than 3 mass %, ii) the polyol component concentration is 1-50 mass %; and iii) the glass transition temperature is from ?50° C. to 0° C.Type: GrantFiled: March 1, 2005Date of Patent: April 3, 2012Assignee: Asahi Kasei Chemicals CorporationInventors: Yoshiyuki Asahina, Masakazu Yamauchi, Hironori Katagawa
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Patent number: 7834103Abstract: Disclosed is a polyisocyanate composition derived from an aliphatic diisocyanate monomer and an alcohol, which satisfies all the conditions below in a state not containing the aliphatic diisocyanate monomer and a solvent. 1) Isocyanurate trimer concentration: 55-95 mass % 2) Number ratio of allophanate groups derived from the alcohol to isocyanurate groups: 1-20% 3) Urethodione dimmer concentration: 2-25 mass % 4) Viscosity at 25° C.: 150-800 mPa·s.Type: GrantFiled: October 19, 2006Date of Patent: November 16, 2010Assignee: Asahi Kasei Chemicals CorporationInventors: Yoshiyuki Asahina, Hironori Katagawa
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Publication number: 20100256324Abstract: Disclosed is a block polyisocyanate obtained by blocking at least a part of isocyanate groups of a polyisocyanate, which is derived from an aliphatic diisocyanate and a polyol and satisfies all of the conditions (1)-(5) shown below, with a pyrazole compound. (1) Average number of isocyanate groups: 3.0-20 (2) Diisocyanate monomer trimer concentration: 10-50% by mass (3) Isocyanate group concentration: 5-22% by mass (4) Polyol content concentration: 5-40% by mass (5) Diisocyanate monomer concentration: 3% by mass or less.Type: ApplicationFiled: December 12, 2008Publication date: October 7, 2010Applicant: ASAHI KASEI CHEMICALS CORPORATIONInventors: Yoshiyuki Asahina, Mio Minakawa
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Publication number: 20090239998Abstract: An isocyanurate type polyisocyanate composition which is derived from an aliphatic diisocyanate monomer and an alcohol and satisfies all of the following requirements when it contains substantially no aliphatic diisocyanate monomer and substantially no solvent: 1) the viscosity at 25° C. is 500-1,500 mPa·s; 2) the isocyanurate trimer concentration is 60-95 mass %; 3) when the number of allophanate bonds is expressed as A and the number of isocyanurate bonds is expressed as B, the proportion of the allophanate bonds, a=(A/(A+B))×100, is 1-30%; and 4) when the number of urethodione bonds is expressed as D, the proportion of the urethodione bonds, d=(D/(B+D))×100, is less than 2%.Type: ApplicationFiled: September 21, 2006Publication date: September 24, 2009Inventors: Yoshiyuki Asahina, Masakazu Yamauchi
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Publication number: 20090131603Abstract: Disclosed is a polyisocyanate composition derived from an aliphatic diisocyanate monomer and an alcohol, which satisfies all the conditions below in a state not containing the aliphatic diisocyanate monomer and a solvent. 1) Isocyanurate trimer concentration: 55-95 mass % 2) Number ratio of allophanate groups derived from the alcohol to isocyanurate groups: 1-20% 3) Urethodione dimmer concentration: 2-25 mass % 4) Viscosity at 25° C.Type: ApplicationFiled: October 19, 2006Publication date: May 21, 2009Inventors: Yoshiyuki Asahina, Hironori Katagawa
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Publication number: 20070218209Abstract: Disclosed is a polyisocyanate composition which is excellent in both curability and drying characteristic. The polyisocyanate composition contains at least one compound selected from aliphatic diisocyanates, at least one compound selected from alicyclic diisocyanates and at least one compound selected from polyols, while satisfying all of the following conditions; i) the diisocyanate monomer concentration is not more than 3 mass %, ii) the polyol component concentration is 1-50 mass %; and iii) the glass transition temperature is from ?50° C. to 0° C.Type: ApplicationFiled: March 1, 2005Publication date: September 20, 2007Inventors: Yoshiyuki Asahina, Masakazu Yamauchi, Hironori Katagawa
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Patent number: 7012115Abstract: The present invention provides an aqueous urethane polyol comprising a hydroxyl group, a urethane group and a hydrophilic groups in a molecule, wherein: an average number of hydroxyl group is 3 to 20; a hydroxyl value is 10 to 200 (mg KOH/g); an equivalent ratio of (urethane group)/(hydroxyl group+hydrophilic group) is 1 to 2; and a number average molecular weight is 1,000 to 20,000.Type: GrantFiled: July 30, 2003Date of Patent: March 14, 2006Assignee: Asahi Kasei Kabushiki KaishaInventors: Yoshiyuki Asahina, Hironori Katagawa
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Publication number: 20050027066Abstract: The present invention provides an aqueous urethane polyol comprising a hydroxyl group, a urethane group and a hydrophilic groups in a molecule, wherein: an average number of hydroxyl group is 3 to 20; a hydroxyl value is 10 to 200 (mg KOH/g); an equivalent ratio of (urethane group)/(hydroxyl group+hydrophilic group) is 1 to 2; and a number average molecular weight is 1,000 to 20,000.Type: ApplicationFiled: July 30, 2003Publication date: February 3, 2005Inventors: Yoshiyuki Asahina, Hironori Katagawa
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Patent number: 6777524Abstract: Disclosed is a polyether polyurethane comprising (A) at least one polyisocyanate having two or more isocyanate groups, which is selected from the group consisting of an aromatic polyisocyanate and an aliphatic polyisocyanate; (B) a polyoxytetramethylene glycol (PTMG) having a number average molecular weight of from 500 to 4,000, a molecular weight distribution (Mw/Mn) of 1.75 or less, and a content of high molecular weight PTMG molecules of 10% by weight or less; and (C) at least one chain extender selected from the group consisting of a C2-C10 polyol having two or more hydroxyl groups and a C2-C10 polyamine having two or more amino groups. Also disclosed is a urethane prepolymer which comprises the above-mentioned components (A) and (B) and which has terminal isocyanate groups.Type: GrantFiled: February 19, 2002Date of Patent: August 17, 2004Assignee: Asahi Kasei Kabushiki KaishaInventors: Atsushi Shimizu, Mutsuhisa Furukawa, Kiyoo Kato, Yoshiyuki Asahina
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Publication number: 20040049003Abstract: 1.Type: ApplicationFiled: May 27, 2003Publication date: March 11, 2004Inventors: Yoshiyuki Asahina, Kaoru Ueyanagi, Hironori Katagawa
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Patent number: 6469122Abstract: Disclosed is a novel polyisocyanate which is obtained by reacting at least one diisocyanate selected from the group consisting of an aliphatic diisocyanate and an alicyclic diisocyanate with a polyol having a number average molecular weight of from 3,000 to 30,000 and an average number of hydroxyl groups of from 2 to 3 and which has an allophanate linkage content of from 0.05 to 0.40, in terms of the ratio of the number of allophanate linkages in the polyisocyanate to the sum of the number of the allophanate linkages in the polyisodyanate and the number of urethane linkages in the polyisocyanate. The polyisocyanate of the present invention exhibits a high curing rate and a low viscosity. Further, the polyisocyanate, upon being cured, not only has no surface tack and exhibits a low modulus-in-tension property, but also exhibits a high tensile elongation property without a need for a plasticizer. Therefore, the polyisocyanate of the present invention can be advantageously used as a sealant.Type: GrantFiled: August 30, 2000Date of Patent: October 22, 2002Assignee: Asahi Kasei Kabushiki KaishaInventors: Yoshiyuki Asahina, Jun-ichi Kanemaru
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Patent number: 6111048Abstract: Disclosed is a novel blocked polyisocyanate obtained by blocking the terminal isocyanate groups of a non-blocked polyisocyanate with a thermally dissociative blocking agent, wherein the non-blocked polyisocyanate is obtained by reacting at least one diisocyanate selected from the group consisting of an aliphatic diisocyanate and an alicyclic diisocyanate with a polyhydroxy compound having an average number of hydroxyl groups as many as 4.5 to 10, and removing substantially all unreacted diisocyanate monomers. A coating composition comprising the blocked polyisocyanate of the present invention as a curing agent and a polyol as a main agent not only has excellent curability even under low temperature conditions, but is also capable of forming a coating which has excellent impact resistance.Type: GrantFiled: May 27, 1998Date of Patent: August 29, 2000Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Yoshiyuki Asahina, Taketoshi Usui
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Patent number: 5849855Abstract: Disclosed is a blocked polyisocyanate composition comprising: a blocked polyisocyanate obtained by blocking the terminal isocyanate groups of a two or more terminal isocyanate groups-containing polyisocyanate derived from at least one diisocyanate selected from an aliphatic diisocyanate and an alicyclic diisocyanate with a blocking agent comprising at least one active methylene compound selected from a malonic diester and an acetoacetic ester; and a salt of a basic compound with an acidic compound, or a mixture of the salt with the basic compound or the acidic compound, the composition having a pH value of from 1 to 8.5. The blocked polyisocyanate composition of the present invention not only exhibits high stability even under high temperature conditions, but also is capable of maintaining such high stability for a prolonged period of time.Type: GrantFiled: August 19, 1996Date of Patent: December 15, 1998Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Taketoshi Usui, Yoshiyuki Asahina
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Patent number: 5817732Abstract: A thermally dissociative blocked polyisocyanate, wherein an isocyanate group of the polyisocyanate is protected with a thermally dissociative blocking agent, which polyisocyanate is a urethane-modified isocyanurate polyisocyanate,(1) that is obtained by a cyclic-trimerization of at least one aliphatic or alicyclic diisocyanate either after its reaction with or in the presence of a polyhydric alcohol having a valence of at least 3,(2) of which the average number of isocyanate functional groups in said polyisocyanate is in the range of 4.5 to 10, and(3) the viscosity of which measured at 25.degree. C. substantially in the absence of the aliphatic or alicyclic diisocyanate monomer and a solvent thereof is in the range of 5,000 to 100,000 mPa.multidot.s;a thermosetting hardener composition; anda thermosetting one-pack coating composition comprising the blocked polyisocyanate.Type: GrantFiled: October 8, 1996Date of Patent: October 6, 1998Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Yoshiyuki Asahina, Taketoshi Usui
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Patent number: 5623286Abstract: A power source control apparatus controls a power source of a display unit of a system which includes an input device and a computer body. The power source control apparatus includes a first part for detecting an input signal which is output from the input device and for turning ON the power source of the display unit based on the detection of the input signal in a state where the power source is OFF, a second part for turning OFF the power source of the display unit if the first part detects no input signal for a predetermined time, and a third part for transmitting to the computer body second and subsequent input signals detected by the first part, so that the power source of the display unit is automatically turned ON in response to the input signal from the input device, but only the second and subsequent input signals are transmitted to the main body.Type: GrantFiled: July 5, 1994Date of Patent: April 22, 1997Assignee: Fujitsu LimitedInventors: Masayuki Morimoto, Yoshiyuki Asahina, Takehiko Tanaka, Mikita Matsuo
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Patent number: 4801663Abstract: A novel isocyanurate polyisocyanate is disclosed containing N,N',N"-tris(6-isocyanatohexyl)-isocyanurate in an extremely high proportion and having an extremely low viscosity. The novel isocyanurate polyisocyanate is excellent not only in compatibility with a polyol having a low polarity but also in solubility in a solvent having a low polarity as well as in a polar solvent. The novel isocyanurate polyisocyanate is very useful as a curing agent for a two-component polyurethane composition, especially a two-component polyurethane coating composition. The two-component polyurethane coating composition of the present invention is capable of providing a coat film having extremely excellent properties.Type: GrantFiled: March 29, 1988Date of Patent: January 31, 1989Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Kaoru Ueyanagi, Norio Oyabu, Yoshiyuki Asahina