Abstract: A positive electrode active material includes: a composite particle that includes a particle containing a lithium transition metal composite oxide of Li and Co and a layer that is provided on a surface of the particle and includes an oxide of Li, Ni and Mn. Ni and Mn have a concentration distribution centered on the center from a surface of the composite particle, in a depth range in which a ratio d (%) satisfies 0.04%?d?0.20%, a mole fraction rn of Ni and a mole fraction rm of Mn are within ranges of 0.05?rn and 0.05?rm, respectively, and a ratio rn2/rn1 and a ratio rm2/rm1 are within ranges of 0.85?rn2/rn1?1.0 and 0.85?rm2/rm1?1.0, respectively.

Abstract: A cathode active material capable of obtaining a high capacity and capable of improving stability or low-temperature characteristics, a method of manufacturing the same, and a battery are provided. A cathode (21) includes a cathode active material including a lithium complex oxide including Li and at least one kind selected from the group consisting of Co, Ni and Mn, and P and at least one kind selected from the group consisting of Ni, Co, Mn, Fe, Al, Mg and Zn as coating elements on a surface of the lithium complex oxide. Preferably, the contents of the coating elements are higher on the surface of the cathode active material than those in the interior thereof, and decrease from the surface to the interior.

Abstract: A lithium ion secondary battery includes a positive electrode, a negative electrode, and an electrolytic solution. The positive electrode contains a lithium composite oxide. The negative electrode contains a material including at least one of silicon Si and tin Sn as a constituent element. The lithium composite oxide includes lithium Li having a composition ratio a, a first element having a composition ratio b, and a second element having a composition ratio c as a constituent element. The first element including two kinds or more selected from among manganese Mn, nickel Ni, and cobalt Co, and including at least manganese. The second element including at least one kind selected from among aluminum Al, titanium Ti, magnesium Mg, and boron B. The composition ratios a to c satisfy the relationships of 1.1<a<1.3, 0.7<b+c<1.1, 0<c<0.1, and a>b+c.

Abstract: A secondary battery includes: a cathode including a cathode active material layer on a cathode current collector; an anode; and an electrolytic solution. The cathode active material layer includes spherical active materials each being a secondary particle and planular active materials each being a secondary particle. The spherical active materials are each included in a region closer to the cathode current collector, and the planular active materials are each included in a region farther from the cathode current collector. Primary particles of the spherical active materials have an average particle diameter that is larger than an average particle diameter of primary particles of the planular active materials.

Abstract: A lithium ion secondary battery includes a positive electrode, a negative electrode, and an electrolytic solution. The positive electrode contains a lithium composite oxide. The negative electrode contains a material including at least one of silicon Si and tin Sn as a constituent element. The lithium composite oxide includes lithium Li having a composition ratio a, a first element having a composition ratio b, and a second element having a composition ratio c as a constituent element. The first element including two kinds or more selected from among manganese Mn, nickel Ni, and cobalt Co, and including at least manganese. The second element including at least one kind selected from among aluminum Al, titanium Ti, magnesium Mg, and boron B. The composition ratios a to c satisfy the relationships of 1.1<a<1.3, 0.7<b+c<1.1, 0<c<0.1, and a>b+c.

Abstract: A secondary battery includes: a cathode including an active material; an anode; and an electrolytic solution, and the active material includes a plurality of active material particles as primary particles and a carbon material. The active material particles contain a polyanion-based compound. The carbon material contains a first carbon material present on surfaces of the active material particles, and a second carbon material present between the active material particles provided with the first carbon material. A ratio B/A between a total carbon amount A and a surface carbon amount B of the active material satisfies 7<B/A<11.5. A ratio D/C between a specific surface area C of the active material, and an oil feed amount D of N-methyl-2-pyrrolidone satisfies 1.5<D/C?2.

Abstract: A secondary battery includes: a cathode; an anode; and an electrolytic solution. The cathode includes a lithium composite oxide, a first compound, and a second compound. The lithium composite oxide includes lithium (Li) and a transition metal element as constituent elements. The first compound includes a first metal element different from the transition metal element as a constituent element, the first compound existing on a surface and inside of the lithium composite oxide. The second compound includes a second metal element different from the first metal element as a constituent element, the second compound existing on the surface of the lithium composite oxide.

Abstract: A cathode active material capable of increasing a capacity and improving high temperature characteristics or cycle characteristics, a method of manufacturing it, a cathode using the cathode active material, and a battery using the cathode active material are provided. In a cathode active material contained in a cathode, a coating layer is provided on at least part of complex oxide particle containing at least lithium (Li) and cobalt (Co). The coating layer is an oxide which contains lithium (Li) and at least one of nickel (Ni) and manganese (Mn).

Abstract: A battery capable of improving the energy density and improving the battery characteristics such as cycle characteristics and high temperature storage characteristics. A cathode and an anode are oppositely arranged with a separator in between. The open circuit voltage in full charge is in the range from 4.25 V to 6.00 V. The separator has a base material layer and a surface layer. The surface layer opposed to the cathode is formed from at least one from the group consisting of polyvinylidene fluoride, polytetrafluoroethylene, polypropylene, and aramid.

Abstract: A cathode active material is a lithium-rich lithium-containing compound having a bedded salt-type crystal structure. A product SD of a specific surface area S in square meters per gram and a crystallite diameter D in micrometer is equal to or more than about 1.4×10?6 cubic meters per gram.

Abstract: A lithium ion secondary battery includes: a positive electrode; a negative electrode; and an electrolytic solution, at least one of the positive electrode and the negative electrode being capable of storing and releasing lithium ions, and containing an active material that satisfies predetermined conditions.

Abstract: Disclosed herein is a positive electrode active material wherein at least one metallic element M1 different from a principal transition metal element A is present at least at part of a surface of a lithium-containing transition metal oxide containing the principal transition metal element A, and, further, a compound of a metallic element M2 different from the metallic element M1 is present in a coating manner or in the vicinity of the lithium-containing transition metal oxide.

Abstract: A cathode active material capable of obtaining a high capacity and capable of improving stability or low-temperature characteristics, a method of manufacturing the same, and a battery are provided. A cathode (21) includes a cathode active material including a lithium complex oxide including Li and at least one kind selected from the group consisting of Co, Ni and Mn, and P and at least one kind selected from the group consisting of Ni, Co, Mn, Fe, Al, Mg and Zn as coating elements on a surface of the lithium complex oxide. Preferably, the contents of the coating elements are higher on the surface of the cathode active material than those in the interior thereof, and decrease from the surface to the interior.

Abstract: A cathode includes a lithium transition metal complex compound including lithium, one, or two or more transition metals, magnesium, and oxygen as constituent elements. In a standardized X-ray absorption spectrum of the lithium transition metal complex compound measured by an X-ray absorption spectroscopic method, a first absorption edge having absorption edge energy E1 in X-ray absorption intensity of about 0.5 exits in a range where X-ray energy is from about 1303 eV to about 1313 eV both inclusive, in a discharged state in which a discharge voltage is about 3.0 V, and a second absorption edge having absorption edge energy E2 in X-ray absorption intensity of about 0.5 exits, in a charged state in which a charge voltage V is from about 4.3 V to about 4.5 V both inclusive. The absorption edge energies E1 and E2 and the charge voltage V satisfy a relation of E2?E1?(V?4.25)×4.

Abstract: A secondary battery capable of obtaining superior battery characteristics is provided. The cathode according to the technology includes a lithium-containing compound. The lithium-containing compound is a compound obtained by inserting an element M2 different from an element M1 in a crystal structure of a surface layer region of a composite oxide represented by a general formula of Li1+a(MnbCocNi1?b?c)1?aM1dO2?c (the element M2 is Mg or the like). A mole fraction R1 represented by [R1 (percent)=(a substance amount of the element M2/sum of substance amounts of Mn, Co, Ni, and the element M2)×100] on a central side of the lithium-containing compound is smaller than the mole fraction R1 on a surface layer side of the lithium-containing compound.

Abstract: A lithium ion secondary battery capable of improving the lithium ion input-output characteristics. An active material capable of storing and releasing lithium ions is a Li complex oxide or a Li complex oxoacid salt. A plurality of primary particles have a particle size distribution with 1 nm<D10<65 nm, 5 nm<D50<75 nm, and 50 nm<D90<100 nm. The maximum peak pore size A in a pore size distribution as measured by a mercury intrusion technique is 10 nm?A?75 nm. The ratio B/A of the maximum peak pore size A and the crystallite size B is 0.5<B/A?1.

Abstract: A cathode active material has: a composite oxide particle containing at least lithium and one or a plurality of transition metals; and a coating layer provided on at least a part of the composite oxide particle. The coating layer contains at least one kind of element M differing from a main transition metal element A forming the composite oxide particle and selected from Groups 2 to 16 of the periodic table and a halogen element X. In the coating layer, the element M and the halogen element X exhibit different distribution states.

Abstract: A positive electrode for a nonaqueous electrolyte battery includes a collector, and a positive electrode active material layer. The positive electrode active material layer includes a positive electrode active material, and also includes a heteropoly acid and/or heteropoly acid compound and phosphorous acid as additives.

Abstract: Disclosed herein is a positive electrode active material prepared by mixing a lithium-containing compound, a compound containing a transition metal to be put into a solid solution, and a compound containing a metallic element M2 different from the transition metal, and firing the mixture to form composite oxide particles, depositing a compound containing at least one element selected from among sulfur (S), phosphorus (P) and fluorine (F) on surfaces of the particles, and firing the particles, whereby each of the particles is provided with a concentration gradient such that the concentration of the metallic element M2 increases from the center toward the surface of the particle, and at least one element selected from among (S), (P) and (F) is made present in the form of being aggregated at the surfaces of the composite oxide particles.

Abstract: A positive electrode active material includes a lithium complex oxide particle, and a coating layer formed on at least a part of the surface of the lithium complex oxide particle. The lithium complex oxide particle is a lithium complex oxide particle composed mainly of nickel. The coating layer contains an oxo acid and/or an oxo acid compound, an acidity of the surface of the lithium complex oxide particle composed mainly of nickel is increased by the coating layer. The acidity is determined based on a pH of a supernatant of water in a state where after 1.0 part by weight of the lithium complex oxide particle composed mainly of nickel and having a coating layer formed thereon is dispersed in 50 parts by weight of water. The lithium complex oxide particle sediments, and the pH is less than 8.0.