Abstract: A negative electrode active material formed from a Si-containing alloy having a composition represented by Chemical Formula (1): SixSnyMzAaLib, wherein M represents one or two or more transition metal elements, A represents an inevitable impurity, and x, y, z, a, and b represent values of mass %, wherein 0<x<100, 0?y<100, 0<z<100, 0.2?b?1.5, a represents the balance, and x+y+z+a+b=100, is used in an electric device. The negative electrode active material improves cycle durability of an electric device such as a lithium ion secondary battery.

Abstract: A negative electrode active material containing a Si-containing alloy having a composition to be represented by Chemical Formula (1): SixSnyMzAlwAa (in Chemical Formula (1) above, M is one or two or more transition metal elements, A is an unavoidable impurity, and x, y, z, w, and a represent values of percentage by mass, where y, z, and w are 2?y?10, 25?z?35, and 0.3?w?3, respectively, and x and a are remainder) is used in an electrical device, providing a means capable of improving the cycle durability of the electrical device such as a lithium ion secondary battery.

Abstract: A negative electrode active material including a silicon-containing alloy having a ternary alloy composition expressed by Si—Sn—Ti and including a structure in which an a-Si phase containing amorphous or low-crystalline silicon formed by dissolving tin in a crystal structure of silicon is dispersed in a parent phase of a silicide phase including TiSi2, wherein when a peak intensity of a Si—O bond peak that is observed at a position where an interatomic distance in a radial wave function observed by XAFS is 0.13 nm is S(1) and a peak intensity of a Si—Si bond peak that is observed at a position where the interatomic distance is 0.2 nm is S(2), a relation of S(2)>S(1) is satisfied is used for an electrical device. When used, the negative electrode active material achieves both cycle durability and charging-discharging efficiency for an electrical device such as a lithium ion secondary battery.

Abstract: A negative electrode active material including a silicon-containing alloy having a ternary alloy composition expressed by Si—Sn—Ti and including a structure in which an a-Si phase containing amorphous or low-crystalline silicon formed by dissolving tin in a crystal structure of silicon is dispersed in a parent phase of a silicide phase including TiSi2, wherein when a peak intensity of a Si—O bond peak that is observed at a position where an interatomic distance in a radial wave function observed by XAFS is 0.13 nm is S(1) and a peak intensity of a Si—Si bond peak that is observed at a position where the interatomic distance is 0.2 nm is S(2), a relation of S(2)>S(1) is satisfied is used for an electrical device. When used, the negative electrode active material achieves both cycle durability and charging-discharging efficiency for an electrical device such as a lithium ion secondary battery.

Abstract: A negative electrode active material which has a ternary alloy composition represented by Si—Sn-M (M is one or two or more transition metal elements) and has a microstructure which has a first phase (silicide phase) having a silicide of a transition metal as a main component and a second phase partially containing Sn and having amorphous or low crystalline silicon as a main component, and further has partially a plurality of independent first phases and partially a eutectic structure of the first phase and the second phase is used for an electric device. The negative electrode active material improves cycle durability of an electric device such as a lithium ion secondary battery.

Abstract: To provide a means capable of improving the cycle durability of an electric device such as a lithium ion secondary battery. A negative electrode active material containing a silicon-containing alloy having ternary alloy composition represented by Si—Sn-M (M is one or two or more transition metal elements) or quaternary alloy composition represented by Si—Sn-M-Al (M is one or two or more transition metal elements) and having a structure wherein an a-Si phase containing amorphous or low crystalline silicon containing tin in a silicon crystal structure in form of a solid solution is dispersed in a silicide phase containing a silicide of a transition metal as a main component is used in an electric device. The negative electrode active material improves the cycle durability of an electric device such as a lithium ion secondary battery.

Abstract: A negative electrode active material containing a Si-containing alloy having a composition to be represented by Chemical Formula (1): SixSnyMzAlwAa (in Chemical Formula (1) above, M is one or two or more transition metal elements, A is an unavoidable impurity, and x, y, z, w, and a represent values of percentage by mass, where y, z, and w are 2?y?10, 25?z?35, and 0.3?w?3, respectively, and x and a are remainder) is used in an electrical device, providing a means capable of improving the cycle durability of the electrical device such as a lithium ion secondary battery.

Abstract: In an electric device the negative electrode active material layer includes a silicide phase containing a silicide of a transition metal is dispersed in a parent phase containing amorphous or low crystalline silicon as a main component, a predetermined composition, and a ratio value (B/A) of a diffraction peak intensity B of a silicide of a transition metal in a range of 2?=37 to 45° to a diffraction peak intensity A of a (111) plane of Si in a range of 2?=24 to 33° in a predetermined range in an X-ray diffraction measurement using a CuK?1 ray is used as a Si-containing alloy. A solid solution or an oxide-coated solid solution in which a coating layer containing an oxide in a predetermined amount is formed on the particle surface of the solid solution and is used in the positive electrode active material layer.

Abstract: To provide a means capable of improving the cycle durability of an electric device such as a lithium ion secondary battery. A negative electrode active material containing a silicon-containing alloy having ternary alloy composition represented by Si—Sn-M (M is one or two or more transition metal elements) or quaternary alloy composition represented by Si—Sn-M-Al (M is one or two or more transition metal elements) and having a structure wherein an a-Si phase containing amorphous or low crystalline silicon containing tin in a silicon crystal structure in form of a solid solution is dispersed in a silicide phase containing a silicide of a transition metal as a main component is used in an electric device. The negative electrode active material improves the cycle durability of an electric device such as a lithium ion secondary battery.

Abstract: A negative electrode active material which has a ternary alloy composition represented by Si—Sn-M (M is one or two or more transition metal elements) and has a microstructure which has a first phase (silicide phase) having a silicide of a transition metal as a main component and a second phase partially containing Sn and having amorphous or low crystalline silicon as a main component, and further has partially a plurality of independent first phases and partially a eutectic structure of the first phase and the second phase is used for an electric device. The negative electrode active material improves cycle durability of an electric device such as a lithium ion secondary battery.

Abstract: A negative electrode active material including a silicon-containing alloy having a predetermined composition is used in an electric device. A ratio value (B/A) of a diffraction peak intensity B of a (001) plane of Sn to a diffraction peak intensity A of a (111) plane of Si is 0.3 or more and 3.7 or less in an X-ray diffraction measurement of the silicon-containing alloy using a CuK?1 ray. Here, the diffraction peak of the (111) plane of Si is present in a range of 2?=24 to 33° and the diffraction peak of the (001) plane of Sn is present in a range of 2?=26 to 35°.

Abstract: In an electric device the negative electrode active material layer includes a silicide phase containing a silicide of a transition metal is dispersed in a parent phase containing amorphous or low crystalline silicon as a main component, a predetermined composition, and a ratio value (B/A) of a diffraction peak intensity B of a silicide of a transition metal in a range of 2?=37 to 45° to a diffraction peak intensity A of a (111) plane of Si in a range of 2?=24 to 33° in a predetermined range in an X-ray diffraction measurement using a CuK?1 ray is used as a Si-containing alloy. A solid solution or an oxide-coated solid solution in which a coating layer containing an oxide in a predetermined amount is formed on the particle surface of the solid solution and is used in the positive electrode active material layer.