Patents by Inventor Yozo Nagai

Yozo Nagai has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 7482388
    Abstract: A polymer electrolyte membrane for a polymer electrolyte fuel cell, that overcomes disadvantages of the conventional polymer ion-exchange membranes including fluorine-based polymer electrolyte membranes and can maintain cell characteristics even in use over a long period of time (e.g., several thousand hours). The polymer electrolyte membrane comprises a fluorine polymer substrate having grafted thereon monomers having sulfone groups as a cation-exchange group, wherein a main chain of the graft chain comprises a hydrocarbon or a partially fluorinated hydrocarbon, and sulfone groups or substituents having sulfone groups are bonded as a side chain, and wherein in element compositional ratio by ESCA, at least one surface of the polymer electrolyte membrane has O/S value of 5.0 or higher, and a surface element proportion of S is 0.4-5.0%.
    Type: Grant
    Filed: September 6, 2005
    Date of Patent: January 27, 2009
    Assignee: Nitto Denko Corporation
    Inventors: Toshimitsu Tachibana, Soji Nishiyama, Yozo Nagai
  • Publication number: 20080044710
    Abstract: The present invention provides an electrolyte membrane that can maintain its properties even during long-term use in a solid polymer fuel cell. More specifically, the present invention provides an electrolyte membrane that exhibits excellent adhesion to the electrodes in a solid polymer fuel cell. The electrolyte membrane of the present invention is an electrolyte membrane for a solid polymer fuel cell, in which a graft chain containing a cation-exchange group has been added to a polymer substrate comprising an olefin-type polymer or fluoropolymer, wherein the penetration temperature of the electrolyte membrane, as measured by thermomechanical analysis, is no more than 200° C. This electrolyte membrane preferably has a dimensional variation ratio, upon immersion in a 40 weight % aqueous methanol solution, of no more than 40%. The polymer substrate preferably comprises polyvinylidene fluoride.
    Type: Application
    Filed: December 12, 2005
    Publication date: February 21, 2008
    Inventors: Toshimitsu Tachibana, Yozo Nagai, Soji Nishiyama
  • Publication number: 20070224480
    Abstract: By performing photograft polymerization of functional monomers such that grafted chains will be introduced from the surface of a polymer base film into its interior without deteriorating its inherent characteristics and also by creating a multiplex crosslinked structure between the grafted chains and the base film under such conditions as to cause preferential radiation-induced crosslinking reaction, there is produced a polymer electrolyte membrane having high enough oxidation resistance and proton conductivity to be suitable for use in fuel cells.
    Type: Application
    Filed: March 23, 2007
    Publication date: September 27, 2007
    Applicants: JAPAN ATOMIC ENERGY AGENCY, NITTO DENKO CORPORATION
    Inventors: Masaru Yoshida, Masaharu Asano, Jinhun Chen, Yasunari Maekawa, Toshimitsu Tachibana, Yozo Nagai, Soji Nishiyama
  • Publication number: 20070207359
    Abstract: A crosslinked nano-inorganic particle/polymer electrolyte membrane composed of a polymer film substrate, graft molecular chains bound to the backbone skeleton of the polymer film substrate and comprising a vinyl monomer graft-polymerized, sulfonic groups bound to the graft molecular chains, and an inorganic material as nano-scale particles uniformly dispersed within a crosslinked structure ascribed to the backbone skeleton of the polymer film substrate and the graft molecular chains, wherein the backbone skeleton of the polymer film substrate, the graft molecular chains, and the nano-inorganic particles mutually construct a crosslinked structure.
    Type: Application
    Filed: November 16, 2006
    Publication date: September 6, 2007
    Applicants: JAPAN ATOMIC ENERGY AGENCY, NITTO DENKO CORPORATION
    Inventors: Jinhun Chen, Masaru Yoshida, Masaharu Asano, Tetsuya Yamaki, Toshimitsu Tachibana, Soji Nishiyama, Yozo Nagai
  • Patent number: 7153565
    Abstract: Polytetrafluoroethylene porous film is laminated with an ultra high molecular weight polyolefin porous film to realize excellent formability, dust collecting ability, and permeability that could not be attained by these porous films used alone. The laminate, which can be formed to prescribed shape if desired, is used to make a container for holding an adsorbent.
    Type: Grant
    Filed: January 20, 2000
    Date of Patent: December 26, 2006
    Assignee: Nitto Denki Corporation
    Inventors: Norikane Nabata, Yozo Nagai, Eizo Kawano, Takuya Maeoka
  • Publication number: 20060281824
    Abstract: A polymer electrolyte membrane produced by a process in which a monofunctional vinyl monomer into which sulfonic acid groups can be introduced and a vinyl monomer having a halogen at a terminal are co-grafted into a polymer base film that has been exposed to an ionizing radiation, and the base film is exposed again to an ionizing radiation and/or heat treated so that the terminal halogen is eliminated to introduce a crosslinking structure in which the graft molecular chains are bound together.
    Type: Application
    Filed: June 8, 2006
    Publication date: December 14, 2006
    Applicants: JAPAN ATOMIC ENERGY AGENCY, NITTO DENKO CORPORATION
    Inventors: Masaharu Asano, Tetsuya Yamaki, Masaru Yoshida, Toshimitsu Tachibana, Soji Nishiyama, Yozo Nagai
  • Publication number: 20060223895
    Abstract: Polymer ion-exchange membranes having outstanding electrical conductivity, water retention and oxidation resistance are produced by the steps of uniformly mixing an organic high-molecular weight resin with functional inorganics having the abilities to promote graft polymerization of polymerizable monomers, adsorb water and conduct protons, irradiating the resulting functional inorganics/polymer membrane to initiate graft polymerization or graft copolymerization of polymerizable monomers having functional groups, and then introducing sulfonic acid groups into the graft chains.
    Type: Application
    Filed: April 5, 2006
    Publication date: October 5, 2006
    Applicants: JAPAN ATOMIC ENERGY AGENCY, NITTO DENKO CORPORATION
    Inventors: Masaru Yoshida, Tetsuya Yamaki, Masaharu Asano, Yousuke Morita, Soji Nishiyama, Toshimitsu Tachibana, Yozo Nagai
  • Publication number: 20060105216
    Abstract: The improved electrolyte membrane which is produced by grafting a styrenic monomer and bis(vinylphenyl)ethane as monomers to a polymer substrate and then introducing sulfonic acid groups into the graft side chains formed has improved oxidation resistance and good adhesion to electrodes. The polymer substrate is preferably made of a fluorocarbon polymer or an olefinic polymer. The styrenic monomer is preferably one or more species selected from the group consisting of styrene, ?-methylstyrene, vinyltoluene, and trifluorostyrene.
    Type: Application
    Filed: November 7, 2005
    Publication date: May 18, 2006
    Applicants: Japan Atomic Energy Agency, Nitto Denko Corporation
    Inventors: Yozo Nagai, Toshimitsu Tachibana, Soji Nishiyama, Tetsuya Yamaki, Masaharu Asano, Masaru Yoshida
  • Publication number: 20060051647
    Abstract: A polymer electrolyte membrane for a polymer electrolyte fuel cell, that overcomes disadvantages of the conventional polymer ion-exchange membranes including fluorine-based polymer electrolyte membranes and can maintain cell characteristics even in use over a long period of time (e.g., several thousand hours). The polymer electrolyte membrane comprises a fluorine polymer substrate having grafted thereon monomers having sulfone groups as a cation-exchange group, wherein a main chain of the graft chain comprises a hydrocarbon or a partially fluorinated hydrocarbon, and sulfone groups or substituents having sulfone groups are bonded as a side chain, and wherein in element compositional ratio by ESCA, at least one surface of the polymer electrolyte membrane has O/S value of 5.0 or higher, and a surface element proportion of S is 0.4-5.0%.
    Type: Application
    Filed: September 6, 2005
    Publication date: March 9, 2006
    Inventors: Toshimitsu Tachibana, Soji Nishiyama, Yozo Nagai
  • Patent number: 6448312
    Abstract: A colored resin composition for water pipes which comprises (A) a polyethylene resin and (B) specific amounts of (i) a cobalt blue pigment, (ii) at least one selected from phthalocyanine pigments having no metals and metal phthalocyanine pigments having no chlorine atoms or one chlorine atom in a molecule, (iii) a dioxazine pigment and (iv) a titanium dioxide pigment and a colored water pipe which comprises the colored polyethylene resin composition and has a color tone within a specific color solid expressed by the values of the Munsell standard color table before and after the test of resistance to chlorine water for 500 hours. The composition and the water pipe are colored in a bluish color and exhibits an excellent hiding property, excellent fastness of the color tone of the coloring component to water containing chlorine and an excellent property for preventing formation of blisters in water containing chlorine.
    Type: Grant
    Filed: October 11, 2001
    Date of Patent: September 10, 2002
    Assignees: High Tech Chem Co., Ltd., Japan Polyolefins Co., Ltd.
    Inventors: Kotaro Oshima, Tohru Matsuoka, Yozo Nagai, Mitsuo Nakamura
  • Patent number: 6302934
    Abstract: A filter medium for filters wherein the evolution of organic gases and dusting from a reinforcing member are depressed and thus the excellent characteristics inherent to a porous polytetrafluoroethylene membrane as a collection layer are fully achieved. The filter medium (1) for filters comprises a porous polytetrafluoroethylene membrane (2) and a porous ultrahigh-molecular weight polyolefin membrane (3) as a reinforcing member for the filter medium.
    Type: Grant
    Filed: November 9, 1999
    Date of Patent: October 16, 2001
    Assignee: Nitto Denko Corporation
    Inventors: Norikane Nabata, Yozo Nagai, Eizo Kawano, Takuya Maeoka
  • Patent number: 4735988
    Abstract: A propylene polymer composition comprising (A) a modified propylene polymer obtained by treating: (1) 100 parts by weight of a propylene polymer or a mixture of a propylene homopolymer and a ethylene-propylene copolymer rubber, with (2) 0.1 to 50 parts by weight of an organic compound having at least one unsaturated bond in the molecule and a hydroxyl group and (3) 0.01 to 20 parts by weight of an organic peroxide; and (B) a propylene polymer, wherein content of the component (A) in the composition is 5 to 50% by weight. This composition may further contain one or more of (C) an amorphous ethylene-propylene copolymer having a propylene content of 20% to 50% by weight and a Mooney viscosity ML.sub.1+4 at 100.degree. C. of 20 to 100, (D) a high-density ethylene copolymer having a density of 0.935 g/cm.sup.3 or more, (E) a linear low-density ethylene copolymer having a density of not less than 0.900 g/cm.sup.3 but less than 0.935 g/cm.sup.2, a melting point of 106.degree. C. to 130 C., a melt flow rate of 0.
    Type: Grant
    Filed: May 28, 1986
    Date of Patent: April 5, 1988
    Assignee: Showa Denko Kabushiki Kaisha
    Inventors: Tomio Takada, Tsutomu Suda, Mitsunobu Machida, Yozo Nagai, Minoru Takaishi, Noboru Takagi