Abstract: A mobile power supply with a data backup function and a data recovery method thereof are introduced. The mobile power supply supplies power to a portable electronic device installed with an Android operating system via a USB port. The mobile power supply copies a predetermined datum from the portable electronic device to a memory unit in the mobile power supply in conjunction with a control unit to perform first-stage data backup. Then, the USB port is electrically connected to a computer apparatus, such that the computer apparatus copies the predetermined datum from the memory unit to the computer apparatus while recharging the mobile power supply to perform second-stage data backup. Accordingly, the portable electronic device or the mobile power supply performs a data backup operation easily and quickly while being recharged.