Abstract: The present invention discloses a method for preparing high-performance anisotropic rare-earth-free permanent magnets, comprising the steps of: forming alloy ingots by melting according to a nominal composition of MnxBi100-x, (45?×?55); then coarsely crushing the alloy ingots and passing the crushed material through a 100-mesh sieve to obtain coarse powder; putting an appropriate amount of MnxBi100-x alloy coarse powder obtained into a ball-milling tank together with non-magnetic steel balls, with a ratio of ball to powder of 10:1; adding an appropriate amount of ethanol as solvent, and then adding a non-ionic surfactant polyvinylpyrrolidone (PVP) accounting for 5-15% of the power mass to assist in low-energy ball milling; washing the slurry obtained in anhydrous ethyl alcohol, and orientating and curing the washed magnetic powder in a magnetic field after adding binder to obtain high-performance anisotropic Mn—Bi alloy magnets finally.