Abstract: In an apparatus, a gas containing CH4 and CO2 is supplied from a first supply unit to a synthetic gas production unit which generates a synthetic gas containing CO and H2 while heating a first catalytic structure; the synthetic gas is supplied to a gas production unit which generates a lower olefin-containing gas including propylene while heating a second catalytic structure; and a detection unit detects propylene discharged from the gas production unit. The first catalytic structure includes first supports having a porous structure and a first metal fine particle that is present in first channels of the first supports. The second catalyst structure includes second supports having a porous structure and a second metal fine particle in the second supports. The second supports have a second channels, a portion of which have an average inner diameter of 0.95 nm or less.

Abstract: A cubic boron nitride sintered body including cubic boron nitride and a binder phase, wherein a content of the cubic boron nitride is 40 volume % or more and 70 volume % or less; a content of the binder phase is 30 volume % or more and 60 volume % or less; an average particle size of the cubic boron nitride is 0.1 ?m or more and 3.0 ?m or less; the binder phase contains TiN and/or TiCN, and TiB2 and contains substantially no AIN and/or Al2O3, the binder phase has a TiB2 (101) plane that shows a maximum peak position (2?) in X-ray diffraction of 44.2° or more; and I2/I1 is 0.10 or more and 0.55 or less, where denotes an X-ray diffraction intensity of a (111) plane of the cubic boron nitride and I2 denotes an X-ray diffraction intensity of a (101) plane of TiB2 of the binder phase.

Abstract: A cubic boron nitride sintered body including cubic boron nitride and a binder phase, wherein a content of the cubic boron nitride is 40 volume % or more and 80 volume % or less; a content of the binder phase is 20 volume % or more and 60 volume % or less; an average particle size of the cubic boron nitride is 0.5 ?m or more and 4.0 ?m or less; the binder phase contains TiC and TiB2 and contains substantially no AlN and/or Al2O3; a (101) plane of TiB2 in the binder phase shows a maximum peak position (2?) in X-ray diffraction of 44.2° or more; and a (200) plane of TiC in the binder phase shows a maximum peak position (2?) in X-ray diffraction of less than 42.1°.

Abstract: A tool having a cutting edge that includes a sintered body containing cubic boron nitride. The sintered body integrally and inseparably includes an inner region and a binder phase enriched layer formed on at least part of a surface of the inner region. The inner region includes: 15-90 volume % of cubic boron nitride; and 10-85 volume % of a mixture of a binder phase and impurities. The binder phase enriched layer includes: 90-100 volume % of the binder phase and impurities mixture; and 0-10 volume % of cubic boron nitride; and the binder phase contains at least one kind selected from the group consisting of: at least one element selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Al, Co, Ni and Si; and a compound of the element and at least one element selected from the group consisting of C, N, O and B.

Abstract: A cutting edge tip of a cubic boron nitride sintered body has improved joint strength to a substrate of a cemented carbide. A cutting edge tip of a cubic boron nitride sintered body has improved crater wear resistance. A tool 10 of the present invention includes a substrate 12 of a cemented carbide and a cutting edge tip 14 of a cubic boron nitride sintered body joined to the substrate 12. The cutting edge tip 14 has a thickness covering an upper surface 12a to a lower surface 12b of the substrate 12. The cubic boron nitride sintered body contains 50 volume % or more and 95 volume % or less of cubic boron nitride and 5 volume % or more and 50 volume % or less of a binder phase. The cubic boron nitride has an average grain size of 1.0 ?m or more and 6.0 ?m or less.

Abstract: A tool having a cutting edge that includes a sintered body containing cubic boron nitride. The sintered body integrally and inseparably includes an inner region and a binder phase enriched layer formed on at least part of a surface of the inner region. The inner region includes: 15-90 volume % of cubic boron nitride; and 10-85 volume % of a mixture of a binder phase and impurities. The binder phase enriched layer includes: 90-100 volume % of the binder phase and impurities mixture; and 0-10 volume % of cubic boron nitride; and the binder phase contains at least one kind selected from the group consisting of: at least one element selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Al, Co, Ni and Si; and a compound of the element and at least one element selected from the group consisting of C, N, O and B.

Abstract: A cutting edge tip of a cubic boron nitride sintered body has improved joint strength to a substrate of a cemented carbide. A cutting edge tip of a cubic boron nitride sintered body has improved crater wear resistance. A tool 10 of the present invention includes a substrate 12 of a cemented carbide and a cutting edge tip 14 of a cubic boron nitride sintered body joined to the substrate 12. The cutting edge tip 14 has a thickness covering an upper surface 12a to a lower surface 12b of the substrate 12. The cubic boron nitride sintered body contains 50 volume % or more and 95 volume % or less of cubic boron nitride and 5 volume % or more and 50 volume % or less of a binder phase. The cubic boron nitride has an average grain size of 1.0 ?m or more and 6.0 ?m or less.

Abstract: A cubic boron nitride sintered body with excellent wear resistance and fracture resistance. The cubic boron nitride sintered body includes 85 to 95% by volume of cubic boron nitride, and 5 to 15% by volume of a binder phase and inevitable impurities. The binder phase has at least three compounds selected from carbides, nitrides, carbonitrides, oxides and mutual solid solutions thereof of Al, V, Cr, Mn, Co, Ni, Nb and Mo. An amount of an aluminum element contained in the cubic boron nitride sintered body is 0.5 to 5% by mass based on a total mass of the cubic boron nitride sintered body. The binder phase is essentially free of both pure metals and alloys consisting of pure metals.

Abstract: A cubic boron nitride sintered body with excellent wear resistance and fracture resistance. The cubic boron nitride sintered body includes 85 to 95% by volume of cubic boron nitride, and 5 to 15% by volume of a binder phase and inevitable impurities. The binder phase has at least three compounds selected from carbides, nitrides, carbonitrides, oxides and mutual solid solutions thereof of Al, V, Cr, Mn, Co, Ni, Nb and Mo. An amount of an aluminum element contained in the cubic boron nitride sintered body is 0.5 to 5% by mass based on a total mass of the cubic boron nitride sintered body. The binder phase is essentially free of both pure metals and alloys consisting of pure metals.

Abstract: A cubic boron nitride-containing sintered body has heightened fracture resistance and toughness without lowered wear resistance. The body has a binder phase containing titanium nitride and titanium carbonitride, cubic boron nitride and inevitable impurities. A distance between a Bragg angle 2? of a (200) plane diffraction line of titanium carbonitride and a Bragg angle 2? of a (200) plane diffraction line of titanium nitride in an X-ray diffraction measurement using a Cu—K? line is 0.30° or more and 0.60° or less, and a full width at half maximum intensity of the (200) plane diffraction line of titanium carbonitride is 0.30° or more and 0.50° or less.