Publication number: 20150104708
Abstract: Provided are a high energy density oxide anode material for lithium ion battery, preparation process and use thereof. Said anode material includes a main part of the anode material and a covering layer. Said main part includes a shell and a core inside the shell. The material of said core is Li1+x[Ni1?y?zCoyMnz]O2 wherein ?0.1?x?0.2, 0?y?0.5, 0?z?0.5 and 0?y+z?0.7. The material of said shell is Li1+a[Co1?bXb]O2, wherein ?0.1?a?0.2, 0?b?0.5, and X is selected from Al, Mg, Cu, Zr, Ti, Cr, V, Fe, Mn, Ni, or combination thereof. Otherwise, The material of said main part is a mixture of Li1+x[Ni1?y?zCoyMnz]O2 and LiCoO2, wherein ?0.1?x?0.2, 0?y?0.5, 0<z?0.5 and 0?y+z?0.7. The material of said covering layer is selected from Al2O3, ZrO2, MgO, SiO2, ZnO2, TiO2, Y2O3, LiAlO2, or combination thereof. Said anode material has the advantages of high capacity, good cycle performance, low surface activity, high voltage resistance and fine safety.
Type:
Application
Filed:
December 22, 2014
Publication date:
April 16, 2015
Inventors:
Yujing BI, Deyu WANG, Jun LI