Abstract: The present invention discloses a method for rapidly preparing a Prussian blue analogue with a monoclinic crystal structure. The Prussian blue analogue with a monoclinic crystal structure has a chemical formula of NaxM[Fe(CN)6]y·zH2O, where M=Mn or Fe, 1.5<×<2, and 0.5<y<1. In this method, a mixture of sodium ferrocyanide and sodium chloride is adopted as a solution A, and a solution of manganese salt or iron salt in water is adopted as a solution B; the solutions A and B are continuously and rapidly mixed by a micromixer, and the precipitation reaction is conducted to obtain a nano-precursor slurry; and the nano-precursor slurry is aged at 80° C. to 160° C. for 3 min to 2 h to obtain a Prussian blue analogue with a monoclinic crystal structure that has a particle diameter of 200 nm to 2,000 nm.

Abstract: The present invention discloses a method for rapidly preparing a Prussian blue analogue with a monoclinic crystal structure. The Prussian blue analogue with a monoclinic crystal structure has a chemical formula of NaxM[Fe(CN)6]y·zH2O, where M=Mn or Fe, 1.5 <×<2, and 0.5<y<1. In this method, a mixture of sodium ferrocyanide and sodium chloride is adopted as a solution A, and a solution of manganese salt or iron salt in water is adopted as a solution B; the solutions A and B are continuously and rapidly mixed by a micromixer, and the precipitation reaction is conducted to obtain a nano-precursor slurry; and the nano-precursor slurry is aged at 80° C. to 160° C. for 3 min to 2 h to obtain a Prussian blue analogue with a monoclinic crystal structure that has a particle diameter of 200 nm to 2,000 nm.