Abstract: An oxygen storage material (OSM) that exhibits enhanced redox properties, developed mesoporosity, and a resistance to sintering. The oxygen storage material (OSM) has a high oxygen storage capacity (i.e., OSC>1.5 mmol H2/g) and enhanced reducibility (i.e., bimodal TPR-H2 profile with two Tmax in the temperature range from 150° C. to 550° C.). The OSM is suitable for use as a catalyst and a catalyst support. The method of making the oxygen storage material comprises the preparation of a solution containing zirconium, cerium, rare earth and transition metal salts, followed by the co-precipitation of all constituent metal hydroxides with a base.

Abstract: A method of making an oxygen storage material (OSM) with developed mesoporosity having a small fraction of pores <10 nm (fresh or aged), and resistance to thermal sintering is provided. This OSM is suitable for use as a catalyst and catalyst support. The method of making this oxygen storage material (OSM) includes the preparation of a solution containing pre-polymerized zirconium oligomers, cerium, rare earth and transition metal salts; the interaction of this solution with a complexing agent that has an affinity towards zirconium; the formation of a zirconium-based precursor; and the co-precipitation of all constituent metal hydroxide with abase.

Abstract: Mesoporous, zirconium-based mixed oxides and a method of making the same comprises: injecting a polyvalent metal-containing solution into an electrolyte solution to form a mother liquor; forming a precipitate; aging the precipitate in the mother liquor to form the mixed oxides; washing the mixed oxides with an aqueous medium; drying and collecting the mixed oxides. The pH of the electrolyte solution exceeds the isoelectric point for zirconium-based mixed oxides. The mixed oxides exhibit a single particle size distribution, improved Ce02 reducibility in the presence of Rhodium, a decrease in surface area after calcination (800-1100° C.) that is not more than 55%, and a tetragonal/cubic structure after calcination. After calcination at 1100° C. for 10 hours in air, the mixed oxides exhibit a surface area >25 m2/g, a pore volume >0.20 cm3/g, an average pore size >30 nm, and an average crystallite size between 8-15 nm.

Abstract: A crystalline, core-shell hybrid Chabazite (CHA) material for use as a catalyst has a core with a silicon to aluminum ratio (SAR) that is less than 25 and a shell that at least partially encapsulates the core, the shell having an SAR of about 25 or greater. The crystalline, core-shell hybrid Chabazite is prepared by forming a first chabazite (CHA) material having a silicon to aluminum ratio (SAR) that is less than 25, placing the first CHA material into an aqueous reaction mixture comprising one or more precursors capable of forming a second chabazite (CHA) material having an SAR that is 25 or greater, growing the second CHA material on the surface of the first CHA material, and collecting the core-shell hybrid CHA material.

Abstract: The present disclosure generally provides novel STT-type zeolite materials called PIDC-120501, PIDC-120502, and PIDC-120805/120806 or PIDC-type zeolites and a method of making these zeolites. The present disclosure also provides for the use of these zeolite materials as a catalyst and a method of preparing said catalyst. The PIDC-type zeolites or STT-type zeolite materials may be used as a catalyst, such as in Selective Catalytic Reduction (SCR) applications.

Abstract: Mesoporous, zirconium-based mixed oxides and a method of making the same comprises: injecting a polyvalent metal-containing solution into an electrolyte solution to form a mother liquor; forming a precipitate; aging the precipitate in the mother liquor to form the mixed oxides; washing the mixed oxides with an aqueous medium; drying and collecting the mixed oxides. The pH of the electrolyte solution exceeds the isoelectric point for zirconium-based mixed oxides. The mixed oxides exhibit a single particle size distribution, improved Ce02 reducibility in the presence of Rhodium, a decrease in surface area after calcination (800-1 100° C.) that is not more than 55%, and a tetragonal/cubic structure after calcination. After calcination at 1 100° C. for 10 hours in air, the mixed oxides exhibit a surface area >25 m2/g, a pore volume >0.20 cm3/g, an average pore size >30 nm, and an average crystallite size between 8-15 nm.

Abstract: A catalyst support material (D-CZMLA) with oxygen storage capacity corresponds to the formula vD:x(Ce1-wZrwO2):yM:zL:(1-v-x-y-z)Al2O3, wherein w is a molar ratio between 0.1-0.8 and v, x, y, and z are weight ratios, such that v is between 0.005-0.15, x is between 0.05-0.80, and y and z are between 0.001-0.10. M is an interactive promoter for oxygen storage, L is a stabilizer (L) for the Al2O3 support; and D is an oxidizing dopant. The catalyst support material can be incorporated into a wash coat that combines platinum group metals (PGM), an adhesive, and a mixture of (?)RE-Ce—ZrO2+(?)CZMLA+(1????)RE-Al2O3, wherein RE-Ce—ZrO2 is a rare earth element stabilized ceria zirconia having a weight ratio (?) between 0-0.7; CZMLA is the doped catalyst support material having a weight ratio (?) between 0.2-1, such that (?+?)?1; and RE-Al2O3 is rare earth element stabilized alumina having a weight ratio equal to (1????).

Abstract: A method of preparing a crystalline STT-type zeolite that has a mole ratio greater than about 15:1 of a tetravalent element oxide to a trivalent element oxide is disclosed along with a gas treatment system that incorporates the STT-type zeolite and a process for treating a gas using the STT-type zeolite. The method generally comprises forming an aqueous mixture comprising a tetravalent element oxide source, a trivalent element oxide source, a source of alkali metal, and an organic structure directing agent; maintaining the mixture under conditions that crystallize crystals of a STT-type zeolite; and recovering the crystals The STT-type zeolite crystals exhibit x-ray diffraction 2-theta degree peaks at: 8.26, 8.58, 9.28, 9.54, 10.58, 14.52, 15.60, 16.43, 17.13, 17.74, 18.08, 18.46, 19.01, 19.70, 20.12, 20.38, 20.68, 21.10, 21.56, 22.20, 22.50, 22.78, 23.36, 23.76, 23.99, 24.54, 24.92, 25.16, 25.58, 25.80, 26.12, 26.94, 27.38, 27.92, 28.30, 28.60, 29.24, 29.48, 30.08, 30.64, 31.20, 31.46, 31.80, 32.02, 32.

Abstract: A catalyst support material and a catalyst system incorporating said support material along with a method of making the same is provided for use in applications in which the support material is exposed to sulfur-containing impurities. The catalyst support material generally comprises an inorganic oxide base material having a surface and pores of predetermined size; and a zirconium layer adapted to interact with the surface and sized to be received by the pores of the base material. The catalyst support material being prepared by applying a layer of a zirconium compound to the surface and pores of an inorganic oxide base material followed by calcination in order to convert the zirconium compound to a metal, a metal oxide, or a mixture thereof.

Abstract: A wash coat is formed by combining platinum group metals (PGM) and an adhesive with a mixture of catalyst support materials according to the relationship (?)RE-Ce—ZrO2+(?)CZMLA+(1????)RE-Al2O3. The RE-Ce—ZrO2 is a commercial material of rare earth elements stabilized ceria zirconia having a weight ratio (?) ranging from 0 to about 0.7; CZMLA is a catalyst support material comprising a core support powder coated with a solid solution and has a weight ratio (?) ranging from about 0.2 to about 1 such that (?+?)?1. RE-Al2O3 is rare earth element stabilized alumina having a weight ratio equal to (1????). The wash coat exhibits a lower activation temperature compared with traditional wash coat formulations by at least 50° C. This wash coat also requires less RE-Ce—ZrO2 oxide and/or less PGM in the formulation for use as an emission control catalyst for gasoline and diesel engines.

Abstract: A method of preparing a crystalline STT-type zeolite that has a mole ratio greater than about 15:1 of a tetravalent element oxide to a trivalent element oxide is disclosed along with a gas treatment system that incorporates the STT-type zeolite and a process for treating a gas using the STT-type zeolite. The method generally comprises forming an aqueous mixture comprising a tetravalent element oxide source, a trivalent element oxide source, a source of alkali metal, and an organic structure directing agent; maintaining the mixture under conditions that crystallize crystals of a STT-type zeolite; and recovering the crystals The STT-type zeolite crystals exhibit x-ray diffraction 2-theta degree peaks at: 8.26, 8.58, 9.28, 9.54, 10.58, 14.52, 15.60, 16.43, 17.13, 17.74, 18.08, 18.46, 19.01, 19.70, 20.12, 20.38, 20.68, 21.10, 21.56, 22.20, 22.50, 22.78, 23.36, 23.76, 23.99, 24.54, 24.92, 25.16, 25.58, 25.80, 26.12, 26.94, 27.38, 27.92, 28.30, 28.60, 29.24, 29.48, 30.08, 30.64, 31.20, 31.46, 31.80, 32.02, 32.

Abstract: A wash coat is formed by combining platinum group metals (PGM) and an adhesive with a mixture of catalyst support materials according to the relationship (?)RE-Ce—ZrO2+(?)CZMLA+(1????)RE-Al2O3. The RE-Ce—ZrO2 is a commercial material of rare earth elements stabilized ceria zirconia having a weight ratio (?) ranging from 0 to about 0.7; CZMLA is a catalyst support material comprising a core support powder coated with a solid solution and has a weight ratio (?) ranging from about 0.2 to about 1 such that (?+?)?1. RE-Al2O3 is rare earth element stabilized alumina having a weight ratio equal to (1????). The wash coat exhibits a lower activation temperature compared with traditional wash coat formulations by at least 50° C. This wash coat also requires less RE-Ce—ZrO2 oxide and/or less PGM in the formulation for use as an emission control catalyst for gasoline and diesel engines.

Abstract: A catalyst support material (D-CZMLA) with oxygen storage capacity corresponds to the formula vD:x(Ce1-wZrwO2):yM:zL:(1?v?x?y?z)Al2O3, wherein w is a molar ratio between 0.1-0.8 and v, x, y, and z are weight ratios, such that v is between 0.005-0.15, x is between 0.05-0.80, and y and z are between 0.001-0.10. M is an interactive promoter for oxygen storage, L is a stabilizer (L) for the Al2O3 support; and D is an oxidizing dopant. The catalyst support material can be incorporated into a wash coat that combines platinum group metals (PGM), an adhesive, and a mixture of (?)RE-Ce—ZrO2+(?)CZMLA+(1????)RE-Al2O3, wherein RE-Ce—ZrO2 is a rare earth element stabilized ceria zirconia having a weight ratio (?) between 0-0.7; CZMLA is the doped catalyst support material having a weight ratio (?) between 0.2-1, such that (?+?)?1; and RE-Al2O3 is rare earth element stabilized alumina having a weight ratio equal to (1????).

Abstract: A new type of catalyst support with oxygen storage capacity (OSC) and methods of making the same are disclosed. The composition ratio is x(Ce1?wZrwO2):yM:zL:(1?x?y?z)Al2O3, where Ce1?wZrwO2 is the oxygen storage composition with stabilizer Zr02, molar ratio (w) in the range of 0 to about 0.8, and a weight ratio (x) of about 0.05 to about 0.8; M is an interactive promoter for oxygen storage capacity with a weight ratio (y) of 0 to about 0.10; and L is a stabilizer for the support Al2O3 with weight ratio (z) of from 0 to about 0.10. In some cases, M or L can act as both OSC promoter and thermal stabilizer. The weight percentage range of ceria-zirconia and other metal and rare earth oxides (x+y+z) is from about 5 to about 80% relative to total oxides.

Abstract: The present disclosure generally provides novel STT-type zeolite materials called PIDC-120501, PIDC-120502, and PIDC-120805/120806 or PIDC-type zeolites and a method of making these zeolites. The present disclosure also provides for the use of these zeolite materials as a catalyst and a method of preparing said catalyst. The PIDC-type zeolites or STT-type zeolite materials may be used as a catalyst, such as in Selective Catalytic Reduction (SCR) applications.

Abstract: A method of preparing a crystalline STT-type zeolite that has a mole ratio greater than about 15:1 of a tetravalent element oxide to a trivalent element oxide is disclosed along with a gas treatment system that incorporates the STT-type zeolite and a process for treating a gas using the STT-type zeolite. The method generally comprises forming an aqueous mixture comprising a tetravalent element oxide source, a trivalent element oxide source, a source of alkali metal, and an organic structure directing agent; maintaining the mixture under conditions that crystallize crystals of a STT-type zeolite; and recovering the crystals The STT-type zeolite crystals exhibit x-ray diffraction 2-theta degree peaks at: 8.26, 8.58, 9.28, 9.54, 10.58, 14.52, 15.60, 16.43, 17.13, 17.74, 18.08, 18.46, 19.01, 19.70, 20.12, 20.38, 20.68, 21.10, 21.56, 22.20, 22.50, 22.78, 23.36, 23.76, 23.99, 24.54, 24.92, 25.16, 25.58, 25.80, 26.12, 26.94, 27.38, 27.92, 28.30, 28.60, 29.24, 29.48, 30.08, 30.64, 31.20, 31.46, 31.80, 32.02, 32.

Abstract: A rare earth alumina particulate composition manufacturing method and application are disclosed. The rare earth alumina of the invention is a particulate of porous structure with a molecular formula (REx,Al1-x)2O3, phase ? or ?+? characterized by a particle size distribution ranging from 1 to 80 ?m with a D50 of 5 to 15 ?m, a pore size distribution ranging from 0.4-200 nm with an average pore diameter of 8 to 30 nm, a pore volume (PV) raging from 0.5 to 1.2 cc/g and a fresh specific surface area (SA) ranging from 130 to 250 m2/g after calcination at 500-900° C. for 5 to 10 hours. The rare earth alumina retains a SA of greater than 60 m2/g after calcination at 1200° C. for 4 hours and greater than 40 m2/g after calcination at 1200° C. for 50 hours. There is no presence of the ? phase or other impurity phases in the long-term aged samples. The rare earth alumina of the invention has a high thermal stability and is a fine three-way catalyst support material.

Abstract: A new type of catalyst support with oxygen storage capacity (OSC) and methods of making the same are disclosed. The composition ratio is x(Ce1-wZrw02):yM:zL:(1-x-y-z)AI203, where Ce1-wZrw02 is the oxygen storage composition with stabilizer Zr02, molar ratio (w) in the range of 0 to about 0.8, and a weight ratio (x) of about 0.05 to about 0.8; M is an interactive promoter for oxygen storage capacity with a weight ratio (y) of 0 to about 0.10; and L is a stabilizer for the support Al203 with weight ratio (z) of from 0 to about 0.10. In some cases, M or L can act as both OSC promoter and thermal stabilizer. The weight percentage range of ceria-zirconia and other metal and rare earth oxides (x+y+z) is from about 5 to about 80% relative to total oxides.

Abstract: A rare earth alumina particulate composition manufacturing method and application are disclosed. The rare earth alumina of the invention is a particulate of porous structure with a molecular formula (RExAl1-x)2O3, phase ? or ?+? characterized by a particle size distribution ranging from 1 to 80 ?m with a D50 of 5 to 15 ?m, a pore size distribution ranging from 0.4-200 nm with an average pore diameter of 8 to 30 nm, a pore volume (PV) raging from 0.5 to 1.2 cc/g and a fresh specific surface area (SA) ranging from 130 to 250 m2/g after calcination at 500-900° C. for 5 to 10 hours. The rare earth alumina retains a SA of greater than 60 m2/g after calcination at 1200° C. for 4 hours and greater than 40 m2/g after calcination at 1200° C. for 50 hours. There is no presence of the ? phase or other impurity phases in the long-term aged samples. The rare earth alumina of the invention has a high thermal stability and is a fine three-way catalyst support material.