Abstract: The present invention provides a vinyl alcohol polymer having properties comparable to the properties of vinyl alcohol polymers of solely petroleum origin, and, in using the vinyl alcohol polymer (PVA), saves petroleum resources, and reduces carbon dioxide emissions in production processes. The present invention relates to a vinyl alcohol polymer (X) obtained through saponification after polymerization of a plant-derived vinyl ester monomer (A) and a petroleum-derived vinyl ester monomer (B), and having a mole ratio (A)/(B) of 5/95 to 100/0.

Abstract: A coating agent for paper comprises: an ethylene-vinyl alcohol copolymer, wherein the ethylene-vinyl alcohol copolymer has a content of ethylene units of 1 mol % or more and less than 20 mol % and a block character of the ethylene units from 0.90 to 0.99. Coated paper is obtained by coating paper with such a coating agent. The coating agent of the present invention is excellent in viscosity stability and also causes the resulting coated paper to be excellent in barrier properties and water resistance.

Abstract: The present invention provides an aqueous dispersion that enables production of a film having improved water resistance, tensile elastic modulus, and stress at break, and with which a decrease of strain at break can be reduced in the film. The present invention relates to an aqueous dispersion comprising an ethylene-vinyl alcohol copolymer (A) and a cellulose nanofiber, the ethylene unit content of the ethylene-vinyl alcohol copolymer (A) being 1 mol % or more and less than 20 mol %.

Abstract: A water-based adhesive for a paper straw, comprising: an ethylene-vinyl alcohol copolymer (A); and water, wherein the ethylene-vinyl alcohol copolymer (A) has a content of ethylene units of 1 mol % or more and less than 20 mol % and a block character of the ethylene units from 0.90 to 0.99. The water-based adhesive contains the ethylene-vinyl alcohol copolymer (A) having a specific structure, and is thus excellent in balance between the rapid coatability, the film strength, the initial adhesiveness, the dynamic water resistance, and the acid resistance, and particularly excellent in the rapid coatability, the film strength, and the acid resistance.

Abstract: The present invention provides a coating agent having a reduced methanol content, an adhesive including the coating agent and excellent in coating performance and adhesiveness, and a coated product including the coating agent and excellent in water resistance and alcohol resistance. The present invention relates to a coating agent comprising a modified vinyl alcohol polymer (A), the modified vinyl alcohol polymer (A) comprising a structural unit derived from a derivative (a) of an ethylenically unsaturated dicarboxylic acid in a content (X) of 0.05 mol % or more and 10 mol % or less, having a degree of saponification of 80.0 mol % or more and 99.9 mol % or less, having a methanol content of less than 3.0 mass % as measured by headspace gas chromatography, and having an amount of 0.1 ppm or more and less than 2,000 ppm of a component insoluble in a 90° C., 5 mass % aqueous solution.

Abstract: The present invention relates generally to a highly-hydrolyzed polyvinyl alcohol composition having increased cold-water solubility, a process for making such a polyvinyl alcohol composition, and various end uses thereof.

Abstract: The present invention relates generally to a highly-hydrolyzed polyvinyl alcohol composition having increased cold-water solubility, a process for making such a polyvinyl alcohol composition, and various end uses thereof.

Abstract: Provided is a vinyl alcohol polymer that provides a coating film having superior water resistance and binder performances, and has sufficient solubility in water and viscosity stability even in a neutral pH region. Further provided are an aqueous solution, a coating agent, an ink jet recording material, a thermal recording material and a base paper for a release paper that comprise the vinyl alcohol polymer, and a method for producing same, and the like. The vinyl alcohol polymer includes a monomer unit represented by the following formula (1), with the following inequality (I) being satisfied. Preferably, the following inequalities (II) and (III) are further satisfied according to the PVA: wherein, P represents the viscosity average degree of polymerization; and S represents the content (mol %) of the monomer unit.

Abstract: An alkyl-modified PVA solution is provided which has low viscosity at high temperatures leading to superior handleability, accompanied by rapidly increased viscosity upon lowering of the temperature, even in the case in which the concentration of the alkyl-modified PVA in a solution is increased. An alkyl-modified vinyl alcohol polymer solution containing an alkyl-modified vinyl alcohol polymer, a surfactant and water. The alkyl-modified vinyl alcohol polymer has a monomer unit that includes an alkyl group having 5 to 29 carbon atoms. The percentage content of the monomer unit is no less than 0.05 mol % and no greater than 5 mol %. The degree of saponification of the alkyl-modified vinyl alcohol polymer is no less than 20 mol % and no greater than 99.99 mol %. The surfactant is a compound represented by the following formula (I) having hydrophilic groups X1 and X2, and an alkyleneoxy group having 3 to 5 carbon atoms (—R1—O—).

Abstract: Provided is a composition comprising: a vinyl alcohol polymer (A) comprising a monomer unit having a group represented by a formula (1); and a compound (B) comprising a silicon atom, a titanium atom, a zirconium atom or a combination thereof, at a content of 0.01 parts by mass or greater and 900 parts by mass or less with respect to 100 parts by mass of the vinyl alcohol polymer (A), wherein an inequality (I) is satisfied: 370?P×S?6,000??(I) wherein, P represents a viscosity average degree of polymerization; and S represents a percentage content (mol %) of the monomer unit. Also provided are a coating agent containing the composition, and a coated article, a thermal recording material, an ink jet recording material and a base paper for a release paper that are produced using the coating agent, and a method for producing a coated article.

Abstract: An object of the invention is to provide a novel alkyl-modified PVA capable of exerting superior thickening properties while maintaining high water solubility, and also capable of having high water resistance in a state being hardened without using an especial crosslinking agent. In addition, another object is to provide a composition, a thickener, a coating material for papers, a coated paper, an adhesive and a film containing the alkyl-modified PVA. Provided is an alkyl-modified vinyl alcohol polymer containing (a) a monomer unit represented by the following general formula (I): wherein, R1 represents a linear or branched alkyl group having 8 to 29 carbon atoms; and R2 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, and has a viscosity average degree of polymerization of no less than 200 and no greater than 5,000, a degree of saponification of no less than 20 mol % and no greater than 99.99 mol %, and a content of the monomer unit (a) of no less than 0.

Abstract: An alkyl-modified PVA solution is provided which has low viscosity at high temperatures leading to superior handleability, accompanied by rapidly increased viscosity upon lowering of the temperature, even in the case in which the concentration of the alkyl-modified PVA in a solution is increased. An alkyl-modified vinyl alcohol polymer solution containing an alkyl-modified vinyl alcohol polymer, a surfactant and water. The alkyl-modified vinyl alcohol polymer has a monomer unit that includes an alkyl group having 5 to 29 carbon atoms. The percentage content of the monomer unit is no less than 0.05 mol % and no greater than 5 mol %. The degree of saponification of the alkyl-modified vinyl alcohol polymer is no less than 20 mol % and no greater than 99.99 mol %. The surfactant is a compound represented by the following formula (I) having hydrophilic groups X1 and X2, and an alkyleneoxy group having 3 to 5 carbon atoms (—R1—O—).

Abstract: Provided is a composition comprising: a vinyl alcohol polymer (A) comprising a monomer unit having a group represented by a formula (1); and a compound (B) comprising a silicon atom, a titanium atom, a zirconium atom or a combination thereof, at a content of 0.01 parts by mass or greater and 900 parts by mass or less with respect to 100 parts by mass of the vinyl alcohol polymer (A), wherein an inequality (I) is satisfied: 370?P×S?6,000??(I) wherein, P represents a viscosity average degree of polymerization; and S represents a percentage content (mol %) of the monomer unit. Also provided are a coating agent containing the composition, and a coated article, a thermal recording material, an ink jet recording material and a base paper for a release paper that are produced using the coating agent, and a method for producing a coated article.

Abstract: Provided is a vinyl alcohol polymer that provides a coating film having superior water resistance and binder performances, and has sufficient solubility in water and viscosity stability even in a neutral pH region. Further provided are an aqueous solution, a coating agent, an ink jet recording material, a thermal recording material and a base paper for a release paper that comprise the vinyl alcohol polymer, and a method for producing same, and the like. The vinyl alcohol polymer includes a monomer unit represented by the following formula (1), with the following inequality (I) being satisfied. Preferably, the following inequalities (II) and (III) are further satisfied according to the PVA: wherein, P represents the viscosity average degree of polymerization; and S represents the content (mol %) of the monomer unit.

Abstract: An object of the present invention is to provide a modified PVA solution that enables physical properties such as viscosity to be adjusted even when a concentration of the modified PVA having high hydrophobicity is increased, and to provide a method for producing the modified PVA solution. The modified vinyl alcohol polymer solution of the present invention comprises: a modified vinyl alcohol polymer; an organic solvent; and water, the modified vinyl alcohol polymer: comprising a monomer unit having an alkyl group having a carbon number of 2 or greater and 29 or less;, and having a percentage content of the monomer unit being no less than 0.05 mol % and no greater than 5 mol %, and a degree of saponification of the modified vinyl alcohol polymer being no less than 20 mol % and no greater than 99.99 mol %, and in terms of Hansen solubility parameters of the organic solvent, ?d being no less than 13 MPa0.5 and no greater than 18 MPa0.5, ?p being no less than 4 MPa0.5 and no greater than 9 MPa0.

Abstract: The present invention provides a polyvinyl alcohol polymer having excellent water solubility, compared to conventional polyvinyl alcohol polymers, and having a high cloud point even when the polyvinyl alcohol polymer is partially saponified. The present invention is a polyvinyl alcohol polymer having, at its end, a group represented by the general formula (I) and/or having, in its main chain, a group represented by the general formula (II). In the formulae, R denotes a hydrogen atom or an OM group, and M denotes a hydrogen atom, an alkali metal atom, a 1/2 alkaline earth metal atom, or an ammonium group.

Abstract: An object of the invention is to provide a novel alkyl-modified PVA capable of exerting superior thickening properties while maintaining high water solubility, and also capable of having high water resistance in a state being hardened without using an especial crosslinking agent. In addition, another object is to provide a composition, a thickener, a coating material for papers, a coated paper, an adhesive and a film containing the alkyl-modified PVA. Provided is an alkyl-modified vinyl alcohol polymer containing (a) a monomer unit represented by the following general formula (I): wherein, R1 represents a linear or branched alkyl group having 8 to 29 carbon atoms; and R2 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, and has a viscosity average degree of polymerization of no less than 200 and no greater than 5,000, a degree of saponification of no less than 20 mol % and no greater than 99.99 mol %, and a content of the monomer unit (a) of no less than 0.

Abstract: The present invention provides a polyvinyl alcohol polymer having excellent water solubility, compared to conventional polyvinyl alcohol polymers, and having a high cloud point even when the polyvinyl alcohol polymer is partially saponified. The present invention is a polyvinyl alcohol polymer having, at its end, a group represented by the general formula (I) and/or having, in its main chain, a group represented by the general formula (II). In the formulae, R denotes a hydrogen atom or an OM group, and M denotes a hydrogen atom, an alkali metal atom, a 1/2 alkaline earth metal atom, or an ammonium group.