Abstract: A process for recovering nitric acid or salts thereof, comprising: contacting, in the presence of water, an water-immiscible ionic liquid of the formula [A+][X?], wherein [A+] represents a phosphonium or ammonium cation and [X?] represents a counter anion which is NO3?, an halide anion displaceable by NO3?, or both, with a fluid which contains HNO3 and at least one more mineral acid, or precursors of said acids, and partition, under mixing, said acids between aqueous and organic phases and form nitrate-loaded ionic liquid of the formula [A+][NO3?]z>0.25 where Z indicates a molar amount of nitrate held in the ionic liquid beyond the positions occupied by the nitrate counter ions; separating the so-formed mixture into an organic phase comprising a nitrate-loaded ionic liquid of the formula [A+][NO3?]z>0.

Abstract: Method and systems are disclosed for selectively removing naturally-occurring sugars in beverages in an effective, affordable and scalable manner.

Abstract: A process for recovering nitric acid or salts thereof, comprising: contacting, in the presence of water, an water-immiscible ionic liquid of the formula [A+][X?], wherein [A+] represents a phosphonium or ammonium cation and [X?] represents a counter anion which is NO3?, an halide anion displaceable by NO3?, or both, with a fluid which contains HNO3 and at least one more mineral acid, or precursors of said acids, and partition, under mixing, said acids between aqueous and organic phases and form nitrate-loaded ionic liquid of the formula [A+][NO3?]z>0.25 where Z indicates a molar amount of nitrate held in the ionic liquid beyond the positions occupied by the nitrate counter ions; separating the so-formed mixture into an organic phase comprising a nitrate-loaded ionic liquid of the formula [A+][NO3?]z>0.

Abstract: Provided herein a process for purification of an ionic liquid from heavy metals, comprising combining heavy metal-containing ionic liquid and a sulfide source to form heavy metal sulfide, and separating said heavy metal sulfide from the ionic liquid.

Abstract: Provided herein a process for purification of an ionic liquid from heavy metals, comprising combining heavy metal-containing ionic liquid and a sulfide source to form heavy metal sulfide, and separating said heavy metal sulfide from the ionic liquid.

Abstract: A process for removing impurities from a flue gas, comprising treating the flue gas with a liquid absorbent comprising (i) a precursor of chlorine dioxide and (ii) an organic ionic liquid, and releasing a purified flue gas into the atmosphere. The process is useful for removing Hg, SO2 and NOx.

Abstract: Methods and systems are disclosed for selectively removing naturally-occurring sugars in beverages in an effective, affordable and scalable manner.

Abstract: Disclosed is an agrochemical delivery unit comprising an impermeable cell which is a cell made of material that is impermeable to water; an agrochemical within the impermeable cell; and a wick comprising a hydrogel, said wick having a portion located within the impermeable cell and a portion located outside of the impermeable cell. Also disclosed is an agrochemical delivery unit comprising (a) a cell comprising two or more cell wall segments wherein at least one segment is impermeable to water and at least one segment is permeable to water; and (ii) an agrochemical within the cell. The invention provides methods of making and using the units.

Abstract: A process for removing impurities from a flue gas, comprising treating the flue gas with a liquid absorbent comprising (i) a precursor of chlorine dioxide and (ii) an organic ionic liquid, and releasing a purified flue gas into the atmosphere. The process is useful for removing Hg, SO2 and NOx.

Abstract: Process for treating a medium by the removal or destruction of one or more undesired substances present in said medium, comprising combining hydrogen peroxide and alkali hydroxide in an aqueous solution to form superoxide, and bringing the resultant superoxide-containing solution into contact with said medium. The process is useful for the destruction of halogenated organic pollutants and also for carbon dioxide removal from flue gases. The process can also be applied for soil remediation.

Abstract: Disclosed is an agrochemical delivery unit comprising an impermeable cell which is a cell made of material that is impermeable to water; an agrochemical within the impermeable cell; and a wick comprising a hydrogel, said wick having a portion located within the impermeable cell and a portion located outside of the impermeable cell. Also disclosed is an agrochemical delivery unit comprising (a) a cell comprising two or more cell wall segments wherein at least one segment is impermeable to water and at least one segment is permeable to water; and (ii) an agrochemical within the cell. The invention provides methods of making and using the units.

Abstract: The invention is a process for absorbing sulfur dioxide from a gaseous stream with the aid of an ionic liquid, followed by the release of sulfur dioxide from the ionic liquid on addition of a polar solvent and the regeneration of the ionic liquid.

Abstract: The invention is a process for absorbing sulfur dioxide from a gaseous stream with the aid of an ionic liquid, followed by the release of sulfur dioxide from the ionic liquid on addition of a polar solvent and the regeneration of the ionic liquid.

Abstract: Provided is a process for controlling heavy metal (e.g., mercury) emission in SO2-containing flue gas, comprising passing a stream of the flue gas (2) through a wet scrubber (1) where it is brought into contact with a liquid absorbent (8) comprising an ionic liquid, an oxidizer (11) and polar protic organic solvent, wherein the amount of said organic solvent is adjusted such that the SO2 absorption is minimized while operating said wet scrubber at a temperature lower than the normal working temperature that would be used in the absence of said solvent. The process may be preceded by an initial stage where a fluoride-containing liquid is used for reducing the amount of sulfur dioxide in the flue gas stream; the sulfur dioxide can be subsequently desorbed from the fluoride-containing liquid upon the addition of a polar solvent.

Abstract: The invention relates to processes for preparing aqueous nitric oxide solutions, by means of introducing a nitric oxide gas stream into an acidic, halide-containing aqueous solution, or by means of nitrite reduction in an acidic environment in the presence of halide ion. The resultant solutions are stable and can be used for treating surfaces prone to the formation of biofilm, or having biofilm thereon.

Abstract: Provided is a process for controlling heavy metal (e.g., mercury) emission in S02-containing flue gas, comprising passing a stream of the flue gas (2) through a wet scrubber (1) where it is brought into contact with a liquid absorbent (8) comprising an ionic liquid, an oxidizer (11) and polar protic organic solvent, wherein the amount of said organic solvent is adjusted such that the SO2 absorption is minimized while operating said wet scrubber at a temperature lower than the normal working temperature that would be used in the absence of said solvent. The process may be preceded by an initial stage where a fluoride-containing liquid is used for reducing the amount of sulfur dioxide in the flue gas stream; the sulfur dioxide can be subsequently desorbed from the fluoride-containing liquid upon the addition of a polar solvent.

Abstract: Process for treating a medium by the removal or destruction of one or more undesired substances present in said medium, comprising combining hydrogen peroxide and alkali hydroxide in an aqueous solution to form superoxide, and bringing the resultant superoxide-containing solution into contact with said medium. The process is useful for the destruction of halogenated organic pollutants and also for carbon dioxide removal from flue gases. The process can also be applied for soil remediation.

Abstract: A wet scrubber for absorbing elemental heavy metal from a gas stream, a liquor for a wet scrubber, and a power-plant comprising a wet scrubber are described. The wet scrubber includes a vessel having a gas inlet and outlet. In the vessel is a liquor including a oxidizer capable of oxidizing the elemental heavy metal and an ionic liquid. The liquor is substantially free of any ligand capable of bonding an ion of the heavy metal.

Abstract: A wet scrubber for absorbing a heavy metal from a gas stream, a liquor for said wet scrubber, and a power-plant comprising said wet scrubber are described. The wet scrubber has a liquor containing an oxidizer in ionic liquid. Optionally, the oxidizer has, in pure state, high vapor pressure, and in the ionic liquid, the oxidizer forms a complex that has a much lower vapor pressure. In a preferred embodiment, the liquor is substantially free of any ligand that binds to the metal to be absorbed by the liquor.

Abstract: A wet scrubber, a liquor for a wet scrubber, and a power-plant comprising a wet scrubber are described.