Abstract: A vehicular propulsion system, a vehicular fuel system and a method of producing fuel for an internal combustion engine. A separation unit that makes up a part of the fuel system includes one or more adsorbent-based reaction chambers to selectively receive and separate at least a portion of onboard fuel into octane-enhanced and cetane-enhanced components. Regeneration of an adsorbate takes place through interaction with a solvent, while subsequent separation allows the solvent to be reused. A controller may be used to determine a particular operational condition of the internal combustion engine such that the onboard fuel can be sent to one or more combustion chambers within the internal combustion engine without first passing through the separation unit, or instead to the separation unit in situations where the internal combustion engine may require an octane-rich or cetane-rich mixture.

Abstract: A vehicular propulsion system, a vehicular fuel system and a method of operating an internal combustion engine. A separation unit that makes up a part of the fuel system includes one or more adsorbent-based chambers such that the separation unit may selectively receive and separate at least a portion of onboard fuel into octane-enhanced and cetane-enhanced fuel components. A supply tank includes three compartments where the first contains the onboard fuel, the second receives a vaporized adsorbate from the separation unit and condenses at least a part of it into one of an octane-rich fuel component or a cetane-rich fuel component, while the third may either store the condensed and enriched fuel component or help condense more of the vaporized adsorbate. The condensing takes place through heat exchange between the onboard fuel and the vaporized adsorbate that are present within the various compartments of the supply tank.

Abstract: A vehicular propulsion system, a vehicular fuel system and a method of operating an internal combustion engine. A separation unit that makes up a part of the fuel system includes one or more adsorbent-based chambers such that the separation unit may selectively receive and separate at least a portion of onboard fuel into octane-enhanced and cetane-enhanced components. Regeneration of an adsorbate takes place through a heat exchange relation with existing system infrastructure.

Abstract: A vehicular propulsion system, a vehicular fuel system and a method of operating an internal combustion engine. A separation unit that makes up a part of the fuel system includes one or more adsorbent-based chambers such that the separation unit may selectively receive and separate at least a portion of onboard fuel into octane-enhanced and cetane-enhanced fuel components. A supply tank includes three compartments where the first contains the onboard fuel, the second receives a vaporized adsorbate from the separation unit and condenses at least a part of it into one of an octane-rich fuel component or a cetane-rich fuel component, while the third may either store the condensed and enriched fuel component or help condense more of the vaporized adsorbate. The condensing takes place through heat exchange between the onboard fuel and the vaporized adsorbate that are present within the various compartments of the supply tank.

Abstract: A method and apparatus for the oxy-combustion of fuel in an internal combustion engine (ICE) used to power a vehicle includes one or more air separation devices that separate oxygen from the atmospheric air to mix with the fuel and return the nitrogen to the atmosphere and converts the free energy available in the form of waste heat from the engine exhaust gas stream and coolant system on board the vehicle into electrical and/or mechanical energy, which energy is used to separate oxygen from air to eliminate or significantly reduce the volume of nitrogen entering the ICE's combustion chamber, and thereby reduce NOx pollutants released into the atmosphere and increase the concentration of CO2 in the engine exhaust stream for capture using an integrated system to compress and increase the density of the captured CO2 for temporary on-board storage until it is discharged at a recovery station, e.g., during vehicle refueling.

Abstract: A whole crude oil desulfurization system and process includes a combination of an adsorption zone and a hydroprocessing zone. This combined process and system reduces the requisite throughput for the hydroprocessing unit, conventionally a very costly and process both in terms of energy expenditures and catalyst depletion. By first contacting the whole crude oil feedstock with an adsorbent for the sulfur-containing compounds, the adsorption effluent having a relatively lower sulfur content can be collected and provided to refiners without further treatment. The adsorbates, including adsorbed organosulfur compounds, are solvent desorbed resulting in a stream containing high levels of organosulfur compounds and a solvent. Following recovery of the solvent, the volume of the sulfur-containing feedstream that remains to be desulfurized in the hydroprocessing zone is substantially less than the original amount of whole crude oil feedstock.

Abstract: This invention relates to a method for preparing a bimetallic titania-based catalyst for use in hydrodesulfurization reactions.

Abstract: Embodiments of a molten metal anode solid oxide fuel cell (MMA-SOFC) system comprise a first MMA-SOFC and a second MMA-SOFC, a fuel contactor integral with the first MMA-SOFC or in fluid communication with the first MMA-SOFC, a molten metal conduit configured to deliver molten metal from a first molten metal anode to a second molten metal anode, and one or more external electric circuits, wherein a first molten metal anode is configured to oxidize molten metal to produce metal oxides and electrons, the fuel contactor is configured to reduce the metal oxides and produce metals and metal sulfides in the molten metal upon reaction with sulfur-containing fuel. The second molten metal anode is configured to oxidize the metal sulfides in the metal sulfides-containing molten metal to produce metals and electrons, and the external electric circuits are configured to generate power from the electrons produced in the first and second MMA-SOFCs.

Abstract: A process for reducing the amount of CO2 released into the atmosphere with the exhaust gas stream produced by the combustion of a hydrocarbon fuel in an internal combustion engine (ICE) used to power a vehicle by capturing at least a portion of the CO2 in a liquid sorbent on board the vehicle, recovering the CO2 from the sorbent and compressing the CO2 for temporary storage on board the vehicle, where the process is operated as a semi-closed system in which the liquid sorbent that captures the CO2 serves as a working fluid and retains the CO2 during the power generation cycle to produce mechanical energy or work, after which the CO2 is desorbed for densification and recovery as an essentially pure gas stream and the working fluid is recycled for use in the process.

Abstract: A method and apparatus for the oxy-combustion of fuel in an internal combustion engine (ICE) used to power a vehicle includes one or more air separation devices that separate oxygen from the atmospheric air to mix with the fuel and return the nitrogen to the atmosphere and converts the free energy available in the form of waste heat from the engine exhaust gas stream and coolant system on board the vehicle into electrical and/or mechanical energy, which energy is used to separate oxygen from air to eliminate or significantly reduce the volume of nitrogen entering the ICE's combustion chamber, and thereby reduce NOx pollutants released into the atmosphere and increase the concentration of CO2 in the engine exhaust stream for capture using an integrated system to compress and increase the density of the captured CO2 for temporary on-board storage until it is discharged at a recovery station, e.g., during vehicle refueling.

Abstract: A method and system for on-board treatment of an exhaust stream containing CO2 emitted by an internal combustion engine in order to reduce the amount of CO2 discharged into the atmosphere which include: a. a treatment zone, preferably operating in swing mode with at least two subsystems, on board the vehicle containing a capture agent having a predetermined capacity for extracting CO2 from the exhaust stream, each subsystem having a heat exchanger with an inlet for admitting the hot exhaust gas stream for passage in heat relation with the capture agent to release CO2 and regenerate the capture agent, an outlet for passage of a treated, cooled exhaust stream having a reduced CO2 content, and an outlet for CO2 released from the regenerated capture agent; b. a compression zone for reducing the volume of the CO2; and c. a storage zone for the temporary storage of compressed CO2.

Abstract: The invention relates to a mixed salt composition which is useful as a CO2 sorbent. The mixed salt composition comprises a Mg salt, and at least one Group IA element salt, where the Mg and Group IA element are present at a molar ratio of from 3:1 to 8:1. The resulting composition can adsorb about 20% or more of CO2 in a gas. Via varying the molar ratios of the components, and the Group IA element, one can develop compositions which show optional functionality at different conditions. The composition is especially useful in the adsorptive capture of CO2 on mobile sources, such as transportation vehicles, where it can be recovered during regeneration of the adsorbent composition and the CO2 used as a coolant gas, as a reactant in manufacture of fuel, and so forth.

Abstract: A process for reducing the amount of CO2 released into the atmosphere with the exhaust gas stream produced by the combustion of a hydrocarbon fuel in an internal combustion engine (ICE) used to power a vehicle by capturing at least a portion of the CO2 in a liquid sorbent on board the vehicle, recovering the CO2 from the sorbent and compressing the CO2 for temporary storage on board the vehicle, where the process is operated as a semi-closed system in which the liquid sorbent that captures the CO2 serves as a working fluid and retains the CO2 during the power generation cycle to produce mechanical energy or work, after which the CO2 is desorbed for densification and recovery as an essentially pure gas stream and the working fluid is recycled for use in the process.

Abstract: The invention relates to a method and a system for on board production of hydrocarbon fuels. Electrochemistry is used to combine CO2 produced by an internal combustion engine with hydrogen and optionally, water, to produce syngas and other fuels.

Abstract: A method and apparatus for the oxy-combustion of fuel in an internal combustion engine (ICE) used to power a vehicle converts the free energy available onboard the vehicle in the form of waste heat from the engine exhaust gas stream and coolant system into electrical and/or mechanical energy which energy is used to separate oxygen from air to eliminate or significantly reduce the volume of nitrogen entering the ICE's combustion chamber, and thereby reduce NOx pollutants released into the atmosphere and increase the concentration of CO2 in the engine exhaust stream for capture using an integrated system to compress and increase the density of the captured CO2 for temporary on-board storage until it is discharged at a recovery station, e.g., during vehicle refueling.

Abstract: A method and system are described for on-board treatment of an exhaust stream containing CO2 emitted by a hydrocarbon-fueled internal combustion engine (ICE) used to power a vehicle in order to reduce the amount of CO2 discharged into the atmosphere which include: a.

Abstract: The present invention provides selective extraction of sulfoxides, or sulfoxides in combination with sulfones, from hydrocarbon mixtures containing these compounds. A significant advantage of the invention is that oxidation products resulting from oxidative desulfurization of hydrocarbon feedstocks are selectively extracted with minimum co-extraction of non-oxidized products such as valuable hydrocarbon fuel components.

Abstract: A method and system are described for on-board treatment of an exhaust stream containing CO2 emitted by a hydrocarbon-fueled internal combustion engine (ICE) used to power a vehicle in order to reduce the amount of CO2 discharged into the atmosphere which include: a. a first waste heat recovery zone on board the vehicle for receiving the high temperature exhaust gas stream, at least one heat exchanger having an inlet for receiving the hot exhaust gas stream from the ICE for passage in heat exchange relation and a discharge outlet for discharging the exhaust stream at a lower temperature, the heat recovery zone further including at least one heat recovery device for converting the waste heat from the exhaust gas to electrical and/or mechanical energy; b.

Abstract: A method and system are described for on-board treatment of an exhaust stream containing CO2 emitted by a hydrocarbon-fueled internal combustion engine (ICE) used to power a vehicle in order to reduce the amount of CO2 discharged into the atmosphere which include: a. a first waste heat recovery zone on board the vehicle for receiving the high temperature exhaust gas stream in heat exchange relation and discharging the exhaust stream at a lower temperature, the waste heat recovery zone further including at least one heat exchanger and/or heat recovery device with an inlet for receiving the hot exhaust gas stream from the ICE for passage in heat exchange relation and an outlet for the cooled exhaust gas stream, the heat exchanger further including an inlet for receiving a heat exchange fluid at a first temperature and an outlet for discharging the fluid at a second higher temperature, the heat recovery device including power transmission means; b.

Abstract: A method and system are described for on-board treatment of an exhaust stream containing CO2 emitted by a hydrocarbon-fueled internal combustion engine (ICE) used to power a vehicle in order to reduce the amount of CO2 discharged into the atmosphere which include: a.