Abstract: The present disclosure relates to quantum dots with a core of III-V material, a first layer of II-VI material and an external shell of II-VI material to be used, for example, in downconverters. The external shell is preferably made of an alloy of Zn and Cd with Se or S. Introducing a small amount of Cd in the external shell provides excellent absorbance performance in blue, violet and UV wavelengths. The amount of Cd needed for this increase in absorbance can be very low. Further, the emitted light can be nearly monochromatic, which is especially interesting in electronic applications.

Abstract: The invention relates to a method to prepare pockets comprising encapsulated material. The pockets are formed by first forming one or more bases B of barrier material on a substrate, by subsequently applying core material on at least part of the bases B and by forming a lid L on bases B provided with core material. The core material comprises at least one photoemissive particle or photoemissive compound such as quantum dots. The invention also relates to a pocket or a plurality of pockets comprising encapsulated material obtained by such method, to a device comprising at least one pocket of encapsulating material and to a process to transfer such a pocket of encapsulated material from one substrate to another substrate.

Abstract: A method to modify the surface of III-V quantum dots. III-V quantum dots provided with X type ligands and L type ligands at their outer surface are dispersed in a solvent include an additional compound. The additional compound has an organic acid of formula RYH or an organic salt of formula RYH+Z? and has at least one acidic proton H+ having a pKa in water equal to or lower than 16. During dispersion the acidic proton H+ protonates at least part of the L type ligands and at least part of the X type ligands are replaced. Surface modified quantum dots, dispersions having such surface modified quantum dots and to the use of such dispersions are disclosed.

Abstract: An integrated optoelectronic device includes a substrate which supports a passive waveguide for index-confining, in two transverse directions, and guiding, along a longitudinal direction, at least one optical mode. The devices further include a first charge transport layer for transporting charge carriers of a first conductivity type, a second charge transport layer for transporting charge carriers of a second conductivity type, opposite to the first conductivity type, and an active layer comprising a particulate film of solution-processable semiconductor nanocrystals. The active layer is arranged relative to the charge transport layers to form a diode junction. The active layer and the first and the second charge transport layer are further formed on the substrate such that they each overlap at least a portion of the waveguide in a cross-section perpendicular to the longitudinal direction. The active layer is evanescently coupled to the waveguide.

Abstract: The invention relates to a method to form copper nanoparticles. The method comprises heating a solution comprising a copper precursor comprising at least one neat copper carboxylate in a concentration of at least 0.2 M, a stabilizer comprising an amine in a concentration equal or larger than the concentration of the copper precursor and optionally a solvent to a temperature T1 to form metallic copper. The solution is then heated to a temperature T2, with the temperature T2 being at least 10° C. higher than the temperature T1. The solution is heated from temperature T1 to temperature T2 with an average rate of at least 2 degrees per minute. The invention further relates to copper nanoparticles obtainable by such method and to formulations comprising such nanoparticles.

Abstract: The disclosure relates to a method to prepare surface stabilized quantum dots by dispersing quantum dots having at least a first type of ligands bonded to their surface in a solvent having at least one multifunctional compound. The multifunctional compound includes at least a first functional group and at least a second functional group. The first functional group of the multifunctional compound is able to bind to the outer surface of the quantum dots and the second functional group of the multifunctional compound is able to interact with a first functional group of the first type of ligands provided on the outer surface of the quantum dots. The disclosure further relates to surface stabilized quantum dots obtainable by this method, to articles including such quantum dots and to the use of such quantum dots for use in on-chip color conversion applications.

Abstract: The present disclosure relates to quantum dots with a core of III-V material, a first layer of II-VI material and an external shell of II-VI material to be used, for example, in downconverters. The external shell is preferably made of an alloy of Zn and Cd with Se or S. Introducing a small amount of Cd in the external shell provides excellent absorbance performance in blue, violet and UV wavelengths. The amount of Cd needed for this increase in absorbance can be very low. Further, the emitted light can be nearly monochromatic, which is especially interesting in electronic applications.

Abstract: This disclosure relates to quantum dots with a core of III-V material, a first layer of II-VI material and an external shell of II-VI material to be used, for example, in downconverters. The external shell is preferably made of an alloy of Zn and Cd with Se or S. The inventors have demonstrated that introducing a small amount of Cd in the external shell provides excellent absorbance performance in blue, violet and UV wavelengths. The amount of Cd needed for this increase in absorbance can be very low. The inventors have shown that the emitted light can be nearly monochromatic, which is especially interesting in electronic applications.

Abstract: A method for synthesizing nanoparticles with a predetermined size at high or full yield comprises mixing a first precursor material comprising a first compound comprising a halide moiety and a metal or a metalloid, a second precursor material comprising a second compound comprising a polyatomic nonmetal, and a solvent. The method further comprises heating the mixture to colloidally form nanoparticles comprising the polyatomic nonmetal and the metal or metalloid. The halide moiety is selected such as to colloidally form the nanoparticles in a predetermined size range that is at least partially determined by this halide moiety.

Abstract: This disclosure relates to quantum dots with a core of III-V material, a first layer of II-VI material and an external shell of II-VI material to be used, for example, in downconverters. The external shell is preferably made of an alloy of Zn and Cd with Se or S. The inventors have demonstrated that introducing a small amount of Cd in the external shell provides excellent absorbance performance in blue, violet and UV wavelengths. The amount of Cd needed for this increase in absorbance can be very low. The inventors have shown that the emitted light can be nearly monochromatic, which is especially interesting in electronic applications.

Abstract: A method for synthesizing nanoparticles with a predetermined size at high or full yield comprises mixing a first precursor material comprising a first compound comprising a halide moiety and a metal or a metalloid, a second precursor material comprising a second compound comprising a polyatomic nonmetal, and a solvent. The method further comprises heating the mixture to colloidally form nanoparticles comprising the polyatomic nonmetal and the metal or metalloid. The halide moiety is selected such as to colloidally form the nanoparticles in a predetermined size range that is at least partially determined by this halide moiety.

Abstract: A method is disclosed for synthesis of nanoparticles of metal selenide, metal selenide alloys, metal chalcogenide comprising at least selenium or metal chalcogenide alloys comprising at least selenium. The method comprises obtaining a heterogeneous dispersion of powder at least selenium in a first solvent at a first temperature, the first temperature being such that the heterogeneous dispersion comprises at least a fraction of undissolved powder in the solvent. The method also comprises introducing the heterogeneous dispersion into a second solvent containing a metal cation precursor, the second solvent being at a second temperature higher than said first temperature allowing, upon introduction of the heterogeneous dispersion, dissolution of at least the fraction of the power resulting in nucleation of the nanoparticles. The method results in efficient and easy production of nanoparticles.

Abstract: A method is disclosed for synthesis of nanoparticles of metal selenide, metal selenide alloys, metal chalcogenide comprising at least selenium or metal chalcogenide alloys comprising at least selenium. The method comprises obtaining a heterogeneous dispersion of powder at least selenium in a first solvent at a first temperature, the first temperature being such that the heterogeneous dispersion comprises at least a fraction of undissolved powder in the solvent. The method also comprises introducing the heterogeneous dispersion into a second solvent containing a metal cation precursor, the second solvent being at a second temperature higher than said first temperature allowing, upon introduction of the heterogeneous dispersion, dissolution of at least the fraction of the power resulting in nucleation of the nanoparticles. The method results in efficient and easy production of nanoparticles.