Abstract: The invention provides novel high-energy density and low-cost flow electrochemical devices incorporating solid-flow electrodes, and further provides methods of using such electrochemical devices. Included are anode and cathode current collector foils that can be made to move during discharge or recharge of the device. Solid-flow devices according to the invention provide improved charging capability due to direct replacement of the conventional electrode stack, higher volumetric and gravimetric energy density, and reduced battery cost due to reduced dimensions of the ion-permeable layer.

Abstract: A flow battery system and methods are provided for eliminating crossover issues of active materials in redox flow batteries. A solid adsorbent with large specific surface area is disposed in an electrolyte of at least one half-cell, in contact with the electrolyte. During a charging process, the active material in a charged state is captured and stored on surfaces of the adsorbent, so that concentrations of the active material in the electrolyte in the charged state is reduced and the crossover is inhibited. During a discharging process, the active material is desorbed from the adsorbent to the electrolyte and pumped into the stack for reaction. The flow battery stack can have a microporous membrane separator. The electrolyte of the flow battery includes zinc iodide as active material and polyethylene glycol (PEG) as an additive.

Abstract: A flow battery system and methods are provided for eliminating crossover issues of active materials in redox flow batteries. A solid adsorbent with large specific surface area is disposed in an electrolyte of at least one half-cell, in contact with the electrolyte. During a charging process, the active material in a charged state is captured and stored on surfaces of the adsorbent, so that concentrations of the active material in the electrolyte in the charged state is reduced and the crossover is inhibited. During a discharging process, the active material is desorbed from the adsorbent to the electrolyte and pumped into the stack for reaction. The flow battery stack can have a microporous membrane separator. The electrolyte of the flow battery includes zinc iodide as active material and polyethylene glycol (PEG) as an additive.

Abstract: The disclosure relates to a complexed iodine-based electrolyte, a redox flow battery comprising the complexed iodine-based electrolyte, and a method for producing the redox flow battery.

Abstract: The disclosure relates to a complexed iodine-based electrolyte, a redox flow battery comprising the complexed iodine-based electrolyte, and a method for producing the redox flow battery.

Abstract: The invention provides novel high-energy density and low-cost flow electrochemical devices incorporating solid-flow electrodes, and further provides methods of using such electrochemical devices. Included are anode and cathode current collector foils that can be made to move during discharge or recharge of the device. Solid-flow devices according to the invention provide improved charging capability due to direct replacement of the conventional electrode stack, higher volumetric and gravimetric energy density, and reduced battery cost due to reduced dimensions of the ion-permeable layer.