Abstract: A rare earth ion doped silicate luminescence glass and preparation method thereof are provided. The luminescence glass is the material with the following formula: aM2O.bM?2O3.cSiO2.dRE2O3, wherein M is at least one of Na, K and Li, M? is at least one of Y, Gd, La, Sc and Lu, RE is at least one of Ce, Tm, Tb, Ho, Dy, Er, Nd, Sm, Eu and Pr. The preparation method is: grinding the raw material until mixed uniformly, calcining the raw material at 1200-1500° C. for 1-5 h, cooling to room temperature, annealing at 600-1100° C. for 0.5-24 h, cooling to room temperature again, molding then getting the product. The performance of the product is stable. The product is homogenous, and the luminescence performance is good. The light transmittance is high. The process of the preparation method is simple and with low cost.

Abstract: Blue light emitting glass and the preparation method thereof are provided. The blue light emitting glass has the following composition: aCaO.bAl2O3.cSiO2.xCeO2, wherein a, b, c and x are, by mol part, 15-55, 15-35, 20-60 and 0.01-5 respectively. The preparation method comprises: weighing the raw materials according to the composition of the blue light emitting glass; mixing the raw materials uniformly and melting the raw materials to obtain glass melt; molding the glass melt to obtain transparent glass; thermally treating the transparent glass under reducing atmosphere, and thereafter obtaining the finished product. The blue light emitting glass obtained has intense broadband excitation spectrum in ultraviolet region and emits intense blue light under the excitation of ultraviolet light. It is suitable for using as luminescent medium material.

Abstract: The present invention relates to ZnO green luminescent material and its preparation. The ZnO green luminescent material is prepared by doping a trivalent rare earth ion compound and a Li compound into zinc oxide material. The method comprises the following steps: (1) weighing raw material in the stoichiometric ratio of formula ZnO: xA, yLi, (2) grinding the raw material, sintering it at 800-1200° C. for 2-8 h, cooling to the room temperature, and then obtaining the ZnO green luminescent material. The present ZnO green luminescent material doped with trivalent rare earth ion compound and Li compound has high stability and luminous intensity, and has higher low-voltage cathode ray luminescence efficiency. The method can easily be operated and can be used widely.

Abstract: Bismuth ion sensitized rare earth germanate luminescence materials and preparation methods are disclosed. The luminescence materials are the compounds of the following general formula (Y1-x-y-zAxBiyLnz)2GeO5. The preparation methods comprise: using oxides, carbonates, oxalates, acetates, nitrates or halides of Y, A, Bi, Ln and Ge as raw materials, wherein A is one of Gd, Lu, Sc and La, and Ln is at least one of Tm, Ho, Sm, Tb, Eu and Dy, homogeneously grinding the raw materials, sintering at 1300-1500° C. for 6-24 h, and then cooling them to room temperature to obtain the bismuth ion sensitized rare earth germanate luminescence materials.

Abstract: The present invention relates to oxide luminescent materials activated by trivalent thulium and their preparations. The luminescent materials are the compounds with the following general formula: (RE1-xTmx)2O3, wherein a range of x is 0<x?0.05 and RE is one or two selected from Y, Gd, La, Lu and Sc. These materials are prepared by Sol-Gel method or high temperature solid phase method using metal oxide of Tm3+, chloride of Tm3+, nitrate of Tm3+, carbonate of Tm3+ or oxalate of Tm3+, and one or two of oxide Y3+, Gd3+, La3+, Lu3+ or Sc3+, chloride Y3+, Gd3+, La3+, Lu3+ or Sc3+, nitrate Y3+, Gd3+, La3+, Lu3+ or Sc3+, carbonate Y3+, Gd3+, La3+, Lu3+ or Sc3+ and oxalate of Y3+, Gd3+, La3+, Lu3+ or Sc3+ as raw material. The present oxide luminescent materials activated by trivalent thulium have high stability, color purity and luminous efficiency, and the methods can easily be operated.

Abstract: A kind of germanate luminescence material and its preparation. The germanate luminescence material is a compound of following formula: (Y1-xLnx)2GeO5, or Y in the said formula is partly or entirely substituted by at least one of Gd, Lu, Sc and La, and x is 0<x?0.3, and Ln is one of Ce, Tm, Ho, Sm, Tb, Eu and Dy. The preparation is grinding the raw material, and then sintering at 1300-1500° C. for 6-24 h, and cooling the sintered product to room temperature, and obtaining the germanate luminescence material.

Abstract: A green light-emitting glass and the method of preparing the same are provided. The components with parts by mole of the green light-emitting glass are alkali oxide 25-40, Y2O3 0.01-15, SiO2 40-70, Tb2O3 0.01-15. The method of preparing the glass includes mixing alkali salt with Y2O3, SiO2 and Tb4O7, firing the mixture at 1200° C.-1500° C. for 1-5 hours, cooling the precursor to the room temperature and annealing the precursor in a reducing atmosphere at 600° C.-1200° C. for 1-20 hours. A green light-emitting glass with good transparence, high uniformity, easily being made into big bulk and high stability is provided. The process of capsulation of parts by using the glass is simple. And a method of preparing the glass with simple process and low cost is provided.

Abstract: A full-color light-emitting material and preparation method thereof are provided. A light-emitting material is following general formula compound (Y1-x-y-zAxByCz)2GeO5, wherein 0<x?0.05, 0<y?0.15, 0<z?0.15, x:y:z=1:1˜10:1˜10, A is one of Tm and Ce, B is one of Tb, Ho, Er and Dy, C is one of Eu, Pr and Sm. Preparation method is: grinding the raw material uniformly, then sintering the material at 1300˜1500 ° C. for 6˜24 h, cooling down the material to room temperature then getting the product. A full-color light-emitting material which can emit red-green-blue full-color light directly and be adapted for light-emitting device excited in ultraviolet zone without other doped material is provided. And a preparation method having simple process, stable product quality for full-color light-emitting materials is provided.

Abstract: The present invention relates to a white light luminescent device based on purple light LED. The white light luminescent device includes a housing, a support plate, at least one purple light LED semiconductor light source, and a piece of high silica luminescent glass. The support plate is received in the housing. The at least one purple light LED semiconductor light source is positioned on the support plate. The piece of high silica luminescent glass doped with Eu ions is opposite to the purple light LED semiconductor light source. One surface of the high silica luminescent glass away from the purple light LED semiconductor light source is coated with a phosphor layer formed with a selection from a mixture of yellow phosphor and red phosphor, a mixture of green phosphor and red phosphor, and yellow phosphor.

Abstract: Bismuth ion sensitized rare earth germanate luminescence materials and preparation methods are disclosed. The luminescence materials are the compounds of the following general formula (Y1-x-y-zAxBiyLnz)2GeO5. The preparation methods comprise: using oxides, carbonates, oxalates, acetates, nitrates or halides of Y, A, Bi, Ln and Ge as raw materials, wherein A is one of Gd, Lu, Sc and La, and Ln is at least one of Tm, Ho, Sm, Tb, Eu and Dy, homogeneously grinding the raw materials, sintering at 1300-1500° C. for 6-24 h, and then cooling them to room temperature to obtain the bismuth ion sensitized rare earth germanate luminescence materials.

Abstract: The present invention relates to ZnO green luminescent material and its preparation. The ZnO green luminescent material is prepared by doping a trivalent rare earth ion compound and a Li compound into zinc oxide material. The method comprises the following steps: (1) weighing raw material in the stoichiometric ratio of formula ZnO: xA, yLi, (2) grinding the raw material, sintering it at 800-1200° C. for 2-8 h, cooling to the room temperature, and then obtaining the ZnO green luminescent material. The present ZnO green luminescent material doped with trivalent rare earth ion compound and Li compound has high stability and luminous intensity, and has higher low-voltage cathode ray luminescence efficiency. The method can easily be operated and can be used widely.

Abstract: A green luminescent glass for ultraviolet LED and a preparation method for glass are disclosed. The preparation method includes: weighing raw materials of CaCO3, Al2O3, SiO2, CeO2 and Tb4O7 respectively and mixing the raw materials evenly; melting the raw materials at 1500˜1700 for 0.5˜3 hours and then molding to form a glass; annealing the formed glass in reducing atmosphere with temperature of 650˜1050 for 3˜20 hours; and cooling the glass to room temperature to obtain the green luminescent glass for ultraviolet LED. The green luminescent glass for ultraviolet LED prepared according to the preparation method of the disclosure has advantages of high luminous intensity, uniformity and stability.

Abstract: The present invention relates to oxide luminescent materials activated by trivalent thulium and their preparations. The luminescent materials are the compounds with the following general formula: (RE1-xTmx)2O3, wherein a range of x is 0<x?0.05 and RE is one or two selected from Y, Gd, La, Lu and Sc. These materials are Prepared by Sol-Gel Method or high temperature solid phase method using metal oxide of Tm3+, chloride of Tm3+, nitrate of Tm3+, carbonate of Tm3+ or oxalate of Tm3+, and one or two of oxide Y3+, Gd3+, La3+, Lu3+ or Sc3+, chloride Y3+, Gd3+, La3+, Lu3+ or Sc3+, nitrate Y3+, Gd3+, La3+, Lu3+ or Sc3+, carbonate Y3+, Gd3+, La3+, Lu3+ or Sc3+ and oxalate of Y3+, Gd3+, La3+, Lu3+ or Sc3+ as raw material. The present oxide luminescent materials activated by trivalent thulium have high stability, color purity and luminous efficiency, and the methods can easily be operated.

Abstract: Blue light emitting glass and the preparation method thereof are provided. The blue light emitting glass has the following composition: aCaO.bAl2O3.cSiO2.xCeO2, wherein a, b, c and x are, by mol part, 15-55, 15-35, 20-60 and 0.01-5 respectively. The preparation method comprises: weighing the raw materials according to the composition of the blue light emitting glass; mixing the raw materials uniformly and melting the raw materials to obtain glass melt; moulding the glass melt to obtain transparent glass; thermally treating the transparent glass under reducing atmosphere, and thereafter obtaining the finished product. The blue light emitting glass obtained has intense broadband excitation spectrum in ultraviolet region and emits intense blue light under the excitation of ultraviolet light. It is suitable for using as luminescent medium material.

Abstract: A rare earth ion doped silicate luminescence glass and preparation method thereof are provided. The luminescence glass is the material with the following formula: aM2O.bM?2O3.cSiO2.dRE2O3, wherein M is at least one of Na, K and Li, M? is at least one of Y, Gd, La, Sc and Lu, RE is at least one of Ce, Tm, Tb, Ho, Dy, Er, Nd, Sm, Eu and Pr. The preparation method is: grinding the raw material until mixed uniformly, calcining the raw material at 1200-1500° C. for 1-5 h, cooling to room temperature, annealing at 600-1100° C. for 0.5-24 h, cooling to room temperature again, molding then getting the product. The performance of the product is stable. The product is homogenous, and the luminescence performance is good. The light transmittance is high. The process of the preparation method is simple and with low cost.

Abstract: A full-color light-emitting material and preparation method thereof are provided. A light-emitting material is following general formula compound (Y1-x-y-zAxByCz)2GeO5, wherein 0<x?0.05, 0<y?0.15, 0<z?0.15, x:y:z=1:1˜10:1˜10, A is one of Tm and Ce, B is one of Tb, Ho, Er and Dy, C is one of Eu, Pr and Sm. Preparation method is: grinding the raw material uniformly, then sintering the material at 1300˜1500 ° C. for 6˜24 h, cooling down the material to room temperature then getting the product. A full-color light-emitting material which can emit red-green-blue full-color light directly and be adapted for light-emitting device excited in ultraviolet zone without other doped material is provided. And a preparation method having simple process, stable product quality for full-color light-emitting materials is provided.

Abstract: A kind of germanate luminescence material and its preparation. The germanate luminescence material is a compound of following formula: (Y1-xLnm)2GeO5, or Y in the said formula is partly or entirely substituted by at least one of Gd, Lu, Sc and La, and x is 0<x?0.3, and Ln is one of Ce, Tm, Ho, Sm, Tb, Eu and Dy. The preparation is grinding the raw material, and then sintering at 1300-1500° C. for 6-24 h, and cooling the sintered product to room temperature, and obtaining the germanate luminescence material.

Abstract: A green light-emitting glass and the method of preparing the same are provided. The components with parts by mole of the green light-emitting glass are alkali oxide 25-40, Y2O3 0.01-15, SiO2 40-70, Tb2O3 0.01-15. The method of preparing the glass includes mixing alkali salt with Y2O3, SiO2 and Tb4O7, firing the mixture at 1200° C-1500° C. for 1-5 hours, cooling the precursor to the room temperature and annealing the precursor in a reducing atmosphere at 600° C-1200° C. for 1-20 hours. A green light-emitting glass with good transparence, high uniformity, easily being made into big bulk and high stability is provided. The process of capsulation of parts by using the glass is simple. And a method of preparing the glass with simple process and low cost is provided.