Abstract: A nuclear magnetic resonance coil array and a decoupling method thereof, and a nuclear magnetic resonance detection device. The coil array includes: a coil resonant unit and a decoupling network unit, where the coil resonant unit includes multiple coil resonant circuits; the decoupling network unit includes multiple decoupling circuits; where a coil resonant circuit includes a coil and a resonant capacitor; the resonant capacitor in each coil resonant circuit is connected in parallel with the coil; the coils in each coil resonance circuit are equally spaced on a circumference; a decoupling circuit is provided between a positive terminal and a negative terminal of adjacent coils, respectively; each coil is connected to an antenna switching circuit of a nuclear magnetic resonance detection device at the same time.