Abstract: The present invention relates to a polymer latex composition, to a method for the preparation of such polymer latex composition, to the use of said polymer latex composition, to a compounded latex composition comprising said polymer latex composition, to a method for making dip-molded articles, to a method for making elastomeric films and articles, to a method for repairing of reforming an elastomeric film or article and to articles made by using said polymer latex composition.

Abstract: A polymer latex is described for the preparation of an elastomeric film obtained by free-radical emulsion polymerization of a mixture of ethylenically unsaturated monomers comprising: a) 15 to 99 wt.-% of conjugated dienes; b) 0 to 80 wt.-% of ethylenically unsaturated nitrile compounds; c) 0 to 70 wt.-% of vinyl aromatic monomers; the sum of ethylenically unsaturated nitrile compounds b) and vinyl aromatic monomers c) being 0.95 to 84.95 wt.-% d) 0.05 to 10 wt.-% of ethylenically unsaturated acids wherein the ethylenically unsaturated acids comprise d1) an ethylenically unsaturated acid comprising an acid functional group; and a spacer group separating the ethylenically unsaturated group and the acid functional group by at least 4 atoms; and e) 0 to 65 wt.-% of co-polymerizable ethylenically unsaturated compounds, wherein monomers a) to e) are as defined.

Abstract: An aqueous polymer latex composition is described for the preparation of an elastomeric film comprising: (I) particles of a latex polymer obtained by free-radical emulsion polymerization of a mixture of ethylenically unsaturated monomers, the particles bearing functional groups (a); and (II) a cross-linking component selected from monomeric compounds and oligomeric or polymeric compounds that are not prepared be free-radical addition polymerization, the cross-linking component comprising functional groups (b) and (c) that are different from each other, wherein functional group (b) forms upon reaction with functional group (a) a thermally reversible linkage selected from one or more of (i) a linkage having the structural formula wherein X, n, R1 and R2 are as defined; and (ii) a beta-hydroxy ester linkage; and functional groups (c) on different molecules of component (II) are capable of reacting with each other to provide elastomeric films having self-healing properties that can be repair

Abstract: The present invention relates to methods for reprocessing elastomeric films or articles comprising an elastomer film wherein the elastomeric film is made from a polymer latex comprising: (a) particles of a carboxylated conjugated diene nitrile latex polymer (a) obtainable by free-radical emulsion polymerization of a mixture of ethylenically unsaturated monomers comprising conjugated dienes; monomers selected from ethylenically unsaturated nitrile compounds; ethylenically unsaturated carboxylic acids and/or salts thereof; optionally vinyl aromatic monomers; and optionally alkyl esters of ethylenically unsaturated acids, in combination or association with (b) particles of a latex polymer (b) comprising at least one oxirane-functional group; wherein the monomer composition of the latex polymer (a) is different from the monomer composition of the latex polymer (b) and to the use of the polymer latex to make an elastomeric film obtained from the polymer latex self-healing, repairable and/or recyclable.

Abstract: The present invention relates to method for the production of a continuous elastomeric film and to continuous elastomeric films and elastomeric articles obtained thereby, where the method comprises: B) providing an aqueous polymer latex composition comprising: (I) particles of a latex polymer obtained by free-radical emulsion polymerization of a mixture of ethylenically unsaturated monomers, the particles bearing a plurality of functional groups, and (II) a crosslinking component comprising a plurality of functional groups at least one thereof being reactive with the functional groups on the latex polymer particles; B) forming from the aqueous polymer latex composition a continuous polymer film; C) optionally drying the continuous polymer film obtained in step B); D) curing the continuous polymer film obtained in step B) or C) to form a continuous elastomeric film; and E) optionally rolling the continuous elastomeric film obtained in step D) into a roll.

Abstract: The present invention relates to methods for reprocessing elastomeric films or articles comprising an elastomer film wherein the elastomeric film is made from a polymer latex comprising: (a) particles of a carboxylated conjugated diene nitrile latex polymer (a) obtainable by free-radical emulsion polymerization of a mixture of ethylenically unsaturated monomers comprising conjugated dienes; monomers selected from ethylenically unsaturated nitrile compounds; ethylenically unsaturated carboxylic acids and/or salts thereof; optionally vinyl aromatic monomers; and optionally alkyl esters of ethylenically unsaturated acids, in combination or association with (b) particles of a latex polymer (b) comprising at least one oxirane-functional group; wherein the monomer composition of the latex polymer (a) is different from the monomer composition of the latex polymer (b) and to the use of the polymer latex to make an elastomeric film obtained from the polymer latex self-healing, repairable and/or recyclable.

Abstract: The present invention relates to a polymer latex composition, to a method for the preparation of such polymer latex composition, to a compounded latex composition comprising said polymer latex composition, to the use of said polymer latex composition, to a method for making dip-molded articles, to a method for the production of a continuous elastomeric film and for making an elastomeric article, to a method for repairing or reforming an elastomeric film or an article and to articles made by using said polymer latex composition.

Abstract: The present invention relates to a polymer latex composition, to a method for the preparation of such a polymer latex composition, to the use of said polymer latex composition for the production of elastomeric articles, to a compounded latex composition comprising said polymer latex composition, to a method for making dip-molded articles, to a method for making elastomeric articles and to articles made by using said polymer latex composition.

Abstract: The present invention relates to method for the production of a continuous elastomeric film and to continuous elastomeric films and elastomeric articles obtained thereby, where the method comprises: B) providing an aqueous polymer latex composition comprising: (I) particles of a latex polymer obtained by free-radical emulsion polymerization of a mixture of ethylenically unsaturated monomers, the particles bearing a plurality of functional groups, and (II) a crosslinking component comprising a plurality of functional groups at least one thereof being reactive with the functional groups on the latex polymer particles; B) forming from the aqueous polymer latex composition a continuous polymer film; C) optionally drying the continuous polymer film obtained in step B); D) curing the continuous polymer film obtained in step B) or C) to form a continuous elastomeric film; and E) optionally rolling the continuous elastomeric film obtained in step D) into a roll.

Abstract: The present invention relates to a polymer latex comprising: (A) particles of a latex polymer (A) obtainable by free-radical emulsion polymerization of a mixture of ethylenically unsaturated monomers the latex polymer comprising a plurality of functional groups (x); and (B) a compound bearing a beta-hydroxy ester linkage and at least one additional functional group (y) reactive with the functional groups (x) on latex polymer (A), to a method for preparation of said polymer latex, to its use, to a method for dip-molding and to articles obtained from the latex.

Abstract: This invention relates to novel hydrogenation catalyst compositions obtainable from reacting metal-based complex hydrogenation catalysts with specific co-catalysts and to a process for selectively hydrogenating nitrile rubbers in the presence of such novel hydrogenation catalyst compositions.

Abstract: A polymer latex is described for the preparation of an elastomeric film obtained by free-radical emulsion polymerization of a mixture of ethylenically unsaturated monomers comprising: a) 15 to 99 wt.-% of conjugated dienes; b) 0 to 80 wt.-% of ethylenically unsaturated nitrile compounds; c) 0 to 70 wt.-% of vinyl aromatic monomers; the sum of ethylenically unsaturated nitrile compounds b) and vinyl aromatic monomers c) being 0.95 to 84.95 wt.-% d) 0.05 to 10 wt.-% of ethylenically unsaturated acids wherein the ethylenically unsaturated acids comprise d1) an ethylenically unsaturated acid comprising an acid functional group; and a spacer group separating the ethylenically unsaturated group and the acid functional group by at least 4 atoms; and e) 0 to 65 wt.-% of co-polymerizable ethylenically unsaturated compounds, wherein monomers a) to e) are as defined.

Abstract: An aqueous polymer latex composition is described for the preparation of an elastomeric film comprising: (I) particles of a latex polymer obtained by free-radical emulsion polymerization of a mixture of ethylenically unsaturated monomers, the particles bearing functional groups (a); and (II) a cross-linking component selected from monomeric compounds and oligomeric or polymeric compounds that are not prepared be free-radical addition polymerization, the cross-linking component comprising functional groups (b) and (c) that are different from each other, wherein functional group (b) forms upon reaction with functional group (a) a thermally reversible linkage selected from one or more of (i) a linkage having the structural formula ?wherein X, n, R1 and R2 are as defined; and (ii) a beta-hydroxy ester linkage; and functional groups (c) on different molecules of component (II) are capable of reacting with each other to provide elastomeric films having self-healing properties that can be repaired a

Abstract: The present invention relates to methods for reprocessing elastomeric films or articles comprising an elastomer film wherein the elastomeric film is made from a polymer latex comprising: (a) particles of a carboxylated conjugated diene nitrile latex polymer (a) obtainable by free-radical emulsion polymerization of a mixture of ethylenically unsaturated monomers comprising: 15 to 99 wt.-% of conjugated dienes; 1 to 80 wt.-% of monomers selected from ethylenically unsaturated nitrile compounds; 0.05 to 10 wt.-% of ethylenically unsaturated carboxylic acids and/or salts thereof; 0 to 50 wt.-% of vinyl aromatic monomers; and 0 to 65 wt.

Abstract: This invention relates to a novel process for selectively and efficiently hydrogenating nitrile rubber in the presence of specific complex catalysts system comprising an NHC-ligand comprising Ru-complex catalyst and a specific hydrogenation enhancer.

Abstract: This invention relates to a novel process for selectively and efficiently hydrogenating nitrile rubber in the presence of specific complex catalysts system comprising an NHC-ligand comprising Ru-complex catalyst and a specific hydrogenation enhancer.

Abstract: This invention relates to novel hydrogenation catalyst compositions obtainable from reacting metal-based complex hydrogenation catalysts with specific co-catalysts and to a process for selectively hydrogenating nitrile rubbers in the presence of such novel hydrogenation catalyst compositions.