Publication number: 20170101486
Abstract: A magnesium halide adduct represented by the formula (I): MgX2.mROH.nE.pH2O, in which X is chlorine, bromine, a C1-C12 alkoxy, a C3-C10 cycloalkoxy or a C6-C10 aryloxy, with the proviso that at least one X is chlorine or bromine; R is a C1-C12 alkyl, a C3-C10 cycloalkyl or a C6-C10 aryl; E is an o-alkoxybenzoate compound represented by the formula (II): in which R1 and R2 groups are independently a C1-C12 linear or branched alkyl, a C3-C10 cycloalkyl, a C6-C10 aryl, a C7-C10 alkaryl or an C7-C10 aralkyl, the R1 and R2 groups are identical to or different from the R group; m is in a range of from 1.0 to 5.0; n is in a range of from 0.001to 0.5; and p is in a range of from 0 to 0.8, is disclosed. A catalyst component useful in olefin polymerization, which comprises a reaction product of (1) the magnesium halide adduct, (2) a titanium compound, and optionally (3) an electron donor compound, is also disclosed.
Type:
Application
Filed:
October 13, 2016
Publication date:
April 13, 2017
Applicants:
CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
Inventors:
Xianzhi XIA, Yuexiang LIU, Jigui ZHANG, Xinsheng WANG, Ping GAO, Suzhen QIAO, Maoping YIN, Weili LI, Tianyi ZHANG, Renqi PENG, Ying CHEN, Zhihui ZHANG
Publication number: 20170044280
Abstract: The present invention discloses a catalyst component for propene polymerization, comprising titanium, magnesium, halogen, and internal electron donor A, wherein said internal electron donor A is selected from the compounds as shown in Formula I, in Formula I, R is selected from hydrogen, hydroxyl, and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen, hydroxyl, and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C6-C30 heteroaryl, C7-C30 alkylaryl and C7-C30 arylalkyl; R1 and R2 may be identical to or different from each other, and are selected from hydrogen and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C7-C30 alkylaryl and C7-C30 arylalkyl. According to the present invention, by using the compound as shown in Formula I as internal electron donor compound for propene polymerization, the catalyst has a higher activity, and a slow rate of delay of activity.
Type:
Application
Filed:
April 24, 2015
Publication date:
February 16, 2017
Applicants:
China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry China Petroleum & Chemical Corporation
Inventors:
Jun WANG, Mingzhi GAO, Haitao LIU, Jing MA, Jianhua CHEN, Xiaoxia CAI, Jixing MA, Changxiu LI, Jianjun HU, Xiaofan ZHANG, Xianzhong LI, Zhihui ZHANG, Ruilin DUAN, Linna YANG, Changyou MA