Patents by Inventor Zhijun Xiao

Zhijun Xiao has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8316941
    Abstract: In a method of treating a sandstone-containing formation penetrated by a wellbore, a treatment fluid comprising an aqueous fluid containing a Bronsted acid, a hydrogen fluoride source and an organic acid or salt thereof that is substantially soluble in the aqueous fluid is formed. The treatment fluid contains less than about 2% of fluoride (F?) by weight of the fluid and from 2% or less of sodium (Na+) by weight of the fluid. The treatment fluid is introduced into the formation through the wellbore as a single-stage without introducing an acid-containing fluid preflush into the formation prior to introducing the treatment fluid.
    Type: Grant
    Filed: March 24, 2008
    Date of Patent: November 27, 2012
    Assignee: Schlumberger Technology Corporation
    Inventors: Wayne W. Frenier, Diankui Fu, Stephen Nigel Davies, Murtaza Ziauddin, Zhijun Xiao, Bruno Lecerf, Helene Bulte, Michael J. Fuller
  • Patent number: 8312929
    Abstract: In a method of treating a sandstone-containing formation penetrated by a wellbore, a treatment fluid comprising an aqueous fluid containing a Bronsted acid, a hydrogen fluoride source and an organic acid or salt thereof that is substantially soluble in the aqueous fluid is formed. The treatment fluid contains less than about 2% of fluoride (F?) by weight of the fluid and from 2% or less of sodium (Na+) by weight of the fluid. The treatment fluid is introduced into the formation through the wellbore as a single-stage without introducing an acid-containing fluid preflush into the formation prior to introducing the treatment fluid.
    Type: Grant
    Filed: January 24, 2008
    Date of Patent: November 20, 2012
    Assignee: Schlumberger Technology Corporation
    Inventors: Wayne W. Frenier, Diankui Fu, Stephen Nigel Davies, Murtaza Ziauddin, Zhijun Xiao, Bruno Lecerf, Helene Bulte
  • Patent number: 7950462
    Abstract: Methods are given for making scale inhibitors, that were previously incompatible with fluids containing fluoride ion, compatible with fluids containing fluoride ion. Examples of such scale inhibitors include phosphonates and phosphino-polycarboxylates. The method is replacing alkali metal and alkaline earth metal cations, present in salts or bases, or as counter ions of the scale inhibitors, with hydrogen or ammonium ions. Methods of inhibiting scale formation and of dissolving scales are also given.
    Type: Grant
    Filed: April 23, 2010
    Date of Patent: May 31, 2011
    Assignee: Schlumberger Technology Corporation
    Inventors: Zhijun Xiao, Marieliz Garcia-Lopez de Victoria, Francis Tuedor
  • Publication number: 20100200238
    Abstract: Methods are given for making scale inhibitors, that were previously incompatible with fluids containing fluoride ion, compatible with fluids containing fluoride ion. Examples of such scale inhibitors include phosphonates and phosphino-polycarboxylates. The method is replacing alkali metal and alkaline earth metal cations, present in salts or bases, or as counter ions of the scale inhibitors, with hydrogen or ammonium ions. Methods of inhibiting scale formation and of dissolving scales are also given.
    Type: Application
    Filed: April 23, 2010
    Publication date: August 12, 2010
    Inventors: Zhijun Xiao, Marieliz Garcia-Lopez de Victoria, Francis Tuedor
  • Patent number: 7703530
    Abstract: Methods are given for making scale inhibitors, that were previously incompatible with fluids containing fluoride ion, compatible with fluids containing fluoride ion. Examples of such scale inhibitors include phosphonates and phosphino-polycarboxylates. The method is replacing alkali metal and alkaline earth metal cations, present in salts or bases, or as counter ions of the scale inhibitors, with hydrogen or ammonium ions. Methods of inhibiting scale formation and of dissolving scales are also given.
    Type: Grant
    Filed: July 18, 2006
    Date of Patent: April 27, 2010
    Assignee: Schlumberger Technology Corporation
    Inventors: Zhijun Xiao, Marieliz Garcia-Lopez de Victoria, Francis Tuedor
  • Publication number: 20090192057
    Abstract: In a method of treating a sandstone-containing formation penetrated by a wellbore, a treatment fluid comprising an aqueous fluid containing a Bronsted acid, a hydrogen fluoride source and an organic acid or salt thereof that is substantially soluble in the aqueous fluid is formed. The treatment fluid contains less than about 2% of fluoride (F?) by weight of the fluid and from 2% or less of sodium (Na+) by weight of the fluid. The treatment fluid is introduced into the formation through the wellbore as a single-stage without introducing an acid-containing fluid preflush into the formation prior to introducing the treatment fluid.
    Type: Application
    Filed: March 24, 2008
    Publication date: July 30, 2009
    Inventors: Wayne W. Frenier, Diankui Fu, Stephen Nigel Davies, Murtaza Ziauddin, Zhijun Xiao, Bruno Lecerf, Helene Bulte, Michael Fuller
  • Publication number: 20090192054
    Abstract: In a method of treating a sandstone-containing formation penetrated by a wellbore, a treatment fluid comprising an aqueous fluid containing a Bronsted acid, a hydrogen fluoride source and an organic acid or salt thereof that is substantially soluble in the aqueous fluid is formed. The treatment fluid contains less than about 2% of fluoride (F?) by weight of the fluid and from 2% or less of sodium (Na+) by weight of the fluid. The treatment fluid is introduced into the formation through the wellbore as a single-stage without introducing an acid-containing fluid preflush into the formation prior to introducing the treatment fluid.
    Type: Application
    Filed: January 24, 2008
    Publication date: July 30, 2009
    Inventors: Wayne W. Frenier, Diankui Fu, Stephen Nigel Davies, Murtaza Ziauddin, Zhijun Xiao, Bruno Lecerf, Helene Bulte
  • Patent number: 7540328
    Abstract: A dry solid composition is disclosed that, when added to an aqueous liquid, provides a slurry that can be used in sandstone acid fracturing. The slurry generates hydrofluoric acid downhole to etch the sandstone fracture faces created. The chemical and physical properties of the composition result in very uneven etching of the fracture faces, enhancing the fluid conductivity of the final fracture. Optionally, inert masking materials may be included in the dry composition, or added to the slurry, to increase the inhomogeneity of the etching and further increase the fluid conductivity.
    Type: Grant
    Filed: September 20, 2007
    Date of Patent: June 2, 2009
    Assignee: Schlumberger Technology Corporation
    Inventors: J. Ernest Brown, John W. Still, Diankui Fu, Zhijun Xiao, Wayne Frenier
  • Publication number: 20080006409
    Abstract: A dry solid composition is disclosed that, when added to an aqueous liquid, provides a slurry that can be used in sandstone acid fracturing. The slurry generates hydrofluoric acid downhole to etch the sandstone fracture faces created. The chemical and physical properties of the composition result in very uneven etching of the fracture faces, enhancing the fluid conductivity of the final fracture. Optionally, inert masking materials may be included in the dry composition, or added to the slurry, to increase the inhomogeneity of the etching and further increase the fluid conductivity.
    Type: Application
    Filed: September 20, 2007
    Publication date: January 10, 2008
    Inventors: J. Ernest Brown, John Still, Diankui Fu, Zhijun Xiao, Wayne Frenier
  • Patent number: 7299870
    Abstract: A method is described for treating a subterranean formation with a low viscosity fluid system that contains a surfactant or mixture of surfactants that does not divert fluid flow in the formation, but that develops the ability to divert flow as the fluid flows through the formation. The fluid optionally contains a formation-dissolving agent. The fluid is used in matrix acidizing, acid fracturing, and diversion.
    Type: Grant
    Filed: December 1, 2005
    Date of Patent: November 27, 2007
    Assignee: Schlumberger Technology Corporation
    Inventors: Marieliz Garcia-Lopez De Victoria, Yenny Christanti, Golchehreh Salamat, Zhijun Xiao, Bernhard Lungwitz
  • Publication number: 20070158067
    Abstract: Methods are given for making scale inhibitors, that were previously incompatible with fluids containing fluoride ion, compatible with fluids containing fluoride ion. Examples of such scale inhibitors include phosphonates and phosphino-polycarboxylates. The method is replacing alkali metal and alkaline earth metal cations, present in salts or bases, or as counter ions of the scale inhibitors, with hydrogen or ammonium ions. Methods of inhibiting scale formation and of dissolving scales are also given.
    Type: Application
    Filed: July 18, 2006
    Publication date: July 12, 2007
    Inventors: Zhijun Xiao, Marieliz Garcia-Lopez de Victoria, Francis Tuedor
  • Patent number: 7207388
    Abstract: A fluid-loss pill that includes a brine solution and an effective amount of a viscoelastic surfactant is disclosed. The viscoelastic surfactant preferably includes at least one compound selected from the family of compounds described by where R1, R2, R3, R4 and R5 are carbon atom or carbon chains, saturated or unsaturated, single or multiple unsaturation, straight chain, branched chain or cyclic including aromatic or alicyclic groups, and R1 contains 16–26 carbon atoms, R2 contains 2–10 carbon atoms, R3, R4 and R5 contains 1–6 carbon atoms. Methods of treating a well that include injecting fluid-loss pill into a well to control lost-circulation or to kill a well.
    Type: Grant
    Filed: June 7, 2006
    Date of Patent: April 24, 2007
    Assignee: Schlumberger Technology Corporation
    Inventors: Mathew Samuel, Richard Marcinew, Zhijun Xiao
  • Patent number: 7148185
    Abstract: A viscous aqueous high density well treatment fluid composition stable at high temperature containing a surfactant and inorganic salts is described. Methods of preparing the fluid and increasing the stability and viscosity of the fluid are given. The fluid is useful for wellbore cleanout, hydraulic fracturing, gravel packing, completion, acid diversion, lost circulation reduction, well killing, cementing, selective water shutoff, and fracture fluid diversion.
    Type: Grant
    Filed: May 9, 2003
    Date of Patent: December 12, 2006
    Assignee: Schlumberger Technology Corporation
    Inventors: Diankui Fu, Yiyan Chen, Zhijun Xiao, Mathew Samuel, Sylvie Daniel
  • Publication number: 20060254771
    Abstract: A fluid-loss pill that includes a brine solution and an effective amount of a viscoelastic surfactant is disclosed. The viscoelastic surfactant preferably includes at least one compound selected from the family of compounds described by where R1, R2, R3, R4 and R5 are carbon atom or carbon chains, saturated or unsaturated, single or multiple unsaturation, straight chain, branched chain or cyclic including aromatic or alicyclic groups, and R1 contains 16-26 carbon atoms, R2 contains 2-10 carbon atoms, R3, R4 and R5 contains 1-6 carbon atoms. Methods of treating a well that include injecting fluid-loss pill into a well to control lost-circulation or to kill a well.
    Type: Application
    Filed: June 7, 2006
    Publication date: November 16, 2006
    Inventors: Mathew Samuel, Richard Marcinew, Zhijun Xiao
  • Publication number: 20060131017
    Abstract: A method is described for treating a subterranean formation with a low viscosity fluid system that contains a surfactant or mixture of surfactants that does not divert fluid flow in the formation, but that develops the ability to divert flow as the fluid flows through the formation. The fluid optionally contains a formation-dissolving agent. The fluid is used in matrix acidizing, acid fracturing, and diversion.
    Type: Application
    Filed: December 1, 2005
    Publication date: June 22, 2006
    Inventors: Marieliz Garcia-Lopez De Victoria, Yenny Christanti, Golchehreh Salamat, Zhijun Xiao
  • Publication number: 20060054325
    Abstract: A dry solid composition is disclosed that, when added to an aqueous liquid, provides a slurry that can be used in sandstone acid fracturing. The slurry generates hydrofluoric acid downhole to etch the sandstone fracture faces created. The chemical and physical properties of the composition result in very uneven etching of the fracture faces, enhancing the fluid conductivity of the final fracture. Optionally, inert masking materials may be included in the dry composition, or added to the slurry, to increase the inhomogeneity of the etching and further increase the fluid conductivity.
    Type: Application
    Filed: September 15, 2004
    Publication date: March 16, 2006
    Inventors: J. Brown, John Still, Diankui Fu, Zhijun Xiao, Wayne Frenier
  • Publication number: 20050113263
    Abstract: A method for fracturing a subterranean formation is provided in which inert masking material particles are injected into the formation with a dissolution agent so that the masking material inhibits dissolution where it contacts a portion of one or both fracture faces. The undissolved regions provide support to keep the fracture open after the treatment and the dissolved regions provide a conductive pathway for flow of fluid to or from the wellbore.
    Type: Application
    Filed: September 15, 2004
    Publication date: May 26, 2005
    Inventors: J. Brown, John Still, Diankui Fu, Zhijun Xiao
  • Publication number: 20050003965
    Abstract: The invention relates to a method of fracturing a subterranean formation at reduced surface pressure including injecting into a wellbore an energized fracturing fluid based on a liquid medium having a density higher than 1.2 g/cm3.
    Type: Application
    Filed: July 1, 2003
    Publication date: January 6, 2005
    Inventors: Zhijun Xiao, Mathew Samuel, Raymond Tibbles, Omar Moussa
  • Publication number: 20030236174
    Abstract: A viscous aqueous high density well treatment fluid composition stable at high temperature containing a surfactant and inorganic salts is described. Methods of preparing the fluid and increasing the stability and viscosity of the fluid are given. The fluid is useful for wellbore cleanout, hydraulic fracturing, gravel packing, completion, acid diversion, lost circulation reduction, well killing, cementing, selective water shutoff, and fracture fluid diversion.
    Type: Application
    Filed: May 9, 2003
    Publication date: December 25, 2003
    Applicant: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Diankui Fu, Yiyan Chen, Zhijun Xiao, Mathew Samuel, Sylvie Daniel
  • Publication number: 20030166471
    Abstract: A fluid-loss pill that includes a brine solution and an effective amount of a viscoelastic surfactant is disclosed.
    Type: Application
    Filed: December 3, 2002
    Publication date: September 4, 2003
    Inventors: Mathew Samuel, Richard Marcinew, Zhijun Xiao