Patent number: 10189867
Abstract: The present document discloses an organosilicon modified photoinitiator represented by the general formula (I): wherein, R1 and R2 are each independently selected from the group consisting of C1-C20 alkyl, C2-C8 alkenyl, C5-C8 cycloalkyl, aryl C1-C3 alkyl; one of R3, R4, R5, R6, and R7 is SIL1-X, and the others are each independently selected from the group consisting of hydrogen, C1-C20 alkyl, C2-C8 alkenyl, C5-C8 cycloalkyl, aryl C1-C3 alkyl, and halogen; X is a direct bond or C1-C12 alkylene; and SIL1 and SIL2 are each independently represented by the formula —SiR8R9R10 or (R?SiO3/2)a(R?2SiO2/2)b(R??3SiO1/2)c, wherein R8, R9 and R10 are each independently selected from the group consisting of C1-C20 alkyl, C2-C8 alkenyl, C5-C8 cycloalkyl, aryl, and aryl C1-C3 alkyl, R?, R? and R?? each independently selected from the group consisting of C1-C20 alkyl, C2-C8 alkenyl, C5-C8 cycloalkyl, and phenyl C1-C3 alkyl, and a, b, and c are numbers that satisfy a?0, b?0, c>0, the ratio of a to c is from 0 to 10
Type:
Grant
Filed:
February 27, 2017
Date of Patent:
January 29, 2019
Assignees:
Henkel IP & Holding GmbH, Henkel AG & Co. KGaA
Inventors:
Hao Wu, Zhiming Li, Jinyou Li, Yong Zhang, Xingang Zhang, Zhixiang Lu, Zheng Lu
Publication number: 20180312532
Abstract: Compounds represented by the following Formula I: wherein: R1, R2, R3, R4, and R5 are the same or different and are selected from the group consisting of SIL1-X, hydrogen, C1-C20 alkyl, C2-C8 alkenyl, C5-C8 cycloalkyl, phenyl C1-C3 alkyl, and fluorine; X is optional, and if present is C1-C12 alkyl; SIL1 has the general formula: (R7SiO3/2)a(R72SiO2/2)b(R73SiO1/2)c wherein: R7 is selected from the group consisting of C1-C20 alkyl, C2-C8 alkenyl, C5-C8 cycloalkyl, alkoxyl, phenyl, and phenyl C1-C3 alkyl; a is a positive number, b is 0 or a positive number, c is 0 or a positive number, b/a is from 0 to 100, and c/a is from 0 to 10, wherein at least one of R1, R2, R3, R4, and R5 is SIL1-X; and R6 is selected from the group consisting of C1-C20 alkyl, C2-C8 alkenyl, C5-C8 cycloalkyl, phenyl, phenyl C1-C3 alkyl, trimethylphenol, and fluorine, a method to produce these compounds, and the use thereof as a photoinitiator.
Type:
Application
Filed:
July 10, 2018
Publication date:
November 1, 2018
Inventors:
Wenjuan TAN, Zhixiang Lu, Hao Wu, Yong Zhang, Zheng Lu, Xuelong Hou
Publication number: 20170166594
Abstract: The present document discloses an organosilicon modified photoinitiator represented by the general formula (I): wherein, R1 and R2 are each independently selected from the group consisting of C1-C20 alkyl, C2-C8 alkenyl, C5-C8 cycloalkyl, aryl C1-C3 alkyl; one of R3, R4, R5, R6, and R7 is SIL1-X, and the others are each independently selected from the group consisting of hydrogen, C1-C20 alkyl, C2-C8 alkenyl, C5-C8 cycloalkyl, aryl C1-C3 alkyl, and halogen; X is a direct bond or C1-C12 alkylene; and SIL1 and SIL2 are each independently represented by the formula —SiR8R9R10 or (R?SiO3/2)a(R?2SiO2/2)b(R??3SiO1/2)c, wherein R8, R9 and R10 are each independently selected from the group consisting of C1-C20 alkyl, C2-C8 alkenyl, C5-C8 cycloalkyl, aryl, and aryl C1-C3 alkyl, R?, R? and R?? each independently selected from the group consisting of C1-C20 alkyl, C2-C8 alkenyl, C5-C8 cycloalkyl, and phenyl C1-C3 alkyl, and a, b, and c are numbers that satisfy a?0, b?0, c>0, the ratio of a to c is from 0 to 10
Type:
Application
Filed:
February 27, 2017
Publication date:
June 15, 2017
Inventors:
Hao Wu, Zhiming Li, Jinyou Li, Yong Zhang, Xingang Zhang, Zhixiang Lu, Zheng Lu